A Search for Water Ice at the Lunar Poles with Clementine Images

Optical and near-IR signatures of water ice on the Moon's surface were sought in the permanently shadowed regions near its poles. Significant amounts of multiply-scattered radiation partly illuminate primary shadows cast by craters and other features. If there is water ice in the permanently shadowed regions of the Moon's surface, its spectral signature should appear in this multiply-scattered light. This investigation can be done most effectively with observations obtained by spacecraft, because most selenocentric positions occupied by the Earth will also be occupied by the Sun at some point in time, and because the lunar poles are seen only obliquely to a terrestrial observer. Images obtained by Clementine are particularly well-suited to this task, because the spacecraft's polar orbit allowed images of the poles to be acquired on nearly every orbit, resulting in literally thousands of images taken within a few degrees of each pole, and because the filters on the ultraviolet-visual camera (UVVIS) and the near infrared camera (NIR) occur at major absorption bands or within important continuum features of water ice. Approximately 5800 images obtained by the UVVIS camera and 1800 images obtained by the NIR camera were calibrated and combined into coadded mosaics to create multispectral maps of the lunar poles with the highest possible signal-to-noise. Unfortunately, analysis of our UVVIS mosaics indicates that any possible signal from multiply-scattered light in primary shadows was overwhelmed by instrumental stray light. For the NIR camera, we were able to determine the normalized reflectance of several regions that were identified by Margot et al. (1999, Science284, 1658-1660) as permanent shadows. We have identified one permanently shadowed crater with a 1.5-μm band spectral signature indicative of between 2.5 and 21% fractional coverage of H₂O frost. However, the same region shows a 2.0 μm spectral signature that is inconsistent with the presence of any water.     

Sequential Separation of Uranium,Hafnium and Neodymium from Natural Waters Concentrated by Iron Coprecipitation

A new ion exchange chromatography method is presented for the isolation of high field‐strength elements (HFSE) from freshwater and seawater samples that have undergone iron coprecipitation. Large volumes of water can be condensed through the application of iron coprecipitation, but clean separation of elements from the precipitate proves difficult. The technique described is a five‐column process designed to separate the HFSE, including rare earth elements such as neodymium and hafnium, before removing the iron and isolating uranium. Subsequent isolation of Nd and Hf was achieved using established ion exchange chromatography methods. The efficacy of our chemistry was verified by measurements of analytical reference materials – both reference solutions and seawater samples – subjected to the chemical separation methods described. Elution results indicate high yields (> 90%) determined by concentration measurements of a known reference material added to each column. Measurement results for isotopic compositions of seawater (U, Nd) and reference solutions (NIST SRM 960, U) were identical within uncertainty to previously published values. Compositions were identical between solutions (Spex CLMS3, Spex PLND2) that underwent different iron coprecipitation procedures. Isotopic determinations for reference materials JNdi‐1 and NIST SRM 960 measured with the mass spectrometers used in this study were in agreement with universally accepted values for these materials, and indicate high precision.     

Modeling Environmental Concern for Urban Tree Protection Using Biophysical and Social Psychological Indicators

Urban forest management is being increasingly recognized as a viable policy vehicle for improving community health, sustainable development, and well-being for city dwellers. To improve our understanding of public concern for the local urban forest, a theoretical framework employing concepts traditionally explored in social–psychological and environmental concern studies was tested using data from a public opinion survey of 800 homeowners living in a major urban area in Southern Appalachia, USA. Publicly available geographic information system (GIS) data were analyzed to measure tree canopy density around survey respondents’ properties. Structural equation modeling was used to test the validity of the hypothesized relationships among the survey-derived constructs and the spatial data as predictors of public support for urban forest protection policy. The results suggest that homeowners living around urban trees place greater importance on various attributes of trees, and that tree knowledge and experience are indirectly and positively related to support for urban forest protection.     

Aligned olivine in the Springwater pallasite

The mechanism by which olivine grains became embedded within iron‐nickel alloy in pallasite meteorites continues to be a matter of scientific debate. Geochemical and textural observations have failed to fully elucidate the origin and history of the olivine crystals; however, little research attention has been devoted to their crystallographic orientations within the metal matrix. Using electron backscatter diffraction, we have collected crystallographic orientation data for 296 crystals within ～65 cm² sample surface from Springwater. Though no global crystallographic preferred orientation exists, very low misorientations are observed among [100] axes of olivine crystals within specific texturally defined domains. Combined with a thorough characterization of large‐scale Springwater textures, the definitively nonrandom spatial distribution of olivine orientations provides clues regarding the nature of the olivine's initial formation environment as well as the sequence of events subsequent to metal incorporation.     

Review: the environmental status and implications of the nitrate time lag in Europe and North America

The efficacy of water quality policies aiming to reduce or prevent nitrate contamination of waterbodies may be constrained by the inherent delay or “time lag” of water and solute transport through unsaturated (soil) and saturated (groundwater) pathways. These delays must be quantified in order to establish realistic deadlines, thresholds and policy expectations, and to design effective best management practices. The objective of this review is to synthesise the current state of research on nitrate-related time lags in both the European and North American environmental and legislative contexts. The durations of time lags have been found to differ according to climatic, pedological, landscape and management scenarios. Elucidation of these driving factors at a watershed scale is essential where water quality is impaired or at risk. Finally, the existence of time lags is increasingly being acknowledged at a policy level and incorporated into the development of environmental legislation. However, the full impact of these time lags is not yet fully understood or appreciated, and continued outreach and education in scientific, public and policy venues is still required.     

The Asian Development Bank and the production of poverty: Neoliberalism,technocratic modernization and land dispossession in the Greater Mekong Subregion

In 1992 the Asian Development Bank coordinated a meeting between government representatives from China, Cambodia, Laos, Myanmar, Thailand and Vietnam to discuss regional economic integration. From that meeting the Greater Mekong Subregion was formed to promote peace and prosperity within the Mekong countries. Yet, despite more than more than USD 14 billion being spent on facilitating trade, development and infrastructural ties between these nations, poverty remains widespread. This article provides a critical analysis of the Asian Development Bank and its approach to development and poverty alleviation within the Greater Mekong Subregion. It suggests that the institution's technocratic neoliberal development ideology provides a discursive legitimation to processes of displacement and dispossession that has seen the production of new forms of poverty. To make this argument, the article draws on an ethnographic study of the local‐scale implications of forced resettlement at the Luang Prabang Airport. It conducts an analysis of how the Asian Development Bank defines and measures poverty, and critiques the institution's resettlement guidelines for the airport project.     

The Effects of Plant Invasion and Ecosystem Restoration on Energy Flow through Salt Marsh Food Webs

We measured the effects of a plant invasion (Phragmites australis) on resident fish (Fundulus heteroclitus) in New England salt marshes by assessing diet quality at the food web base and by quantifying the importance of primary producers to secondary production using a recently developed Bayesian mixing model (Stable Isotope Analysis in R, “SIAR”). Spartina alterniflora, the dominant native plant, exhibited significantly greater leaf toughness and higher C/N ratios relative to P. australis. Benthic microalgae and phytoplankton (as suspended particulate matter) exhibited the lowest C/N indicating higher diet quality. We conducted a sensitivity analysis in SIAR by modeling F. heteroclitus at three separate trophic levels (1.5, 2.0, and 2.5) using species-specific discrimination factors to determine basal resource contributions. Overall, the best-fitting models include those that assume F. heteroclitus resides approximately 2.0 trophic levels above primary producers. Using discrimination factors from a range of data sources reported in the literature, our analyses revealed that consumers rely less on benthic microalgae and phytoplankton in restricted marshes (7–23 % and 11–44 %, respectively) relative to reference marshes (5–34 % and 23–48 %, respectively), resulting in a shift in diet toward invasive plant consumption (0–27 %). This is likely due to increased P. australis cover and marsh surface shading leading to decreased microalgal biomass, combined with reduced flooding of the marsh surface that favors terrestrial invertebrate assemblages. Restoration decreased the quantity of P. australis in the food web (0–15 %) and increased the importance of microalgae (1–30 %), phytoplankton (19–48 %), and native plants (23–63 %), indicating a shift in ecological recovery toward reference conditions.     

Estimating traveler populations at airport and cruise terminals for population distribution and dynamics

In recent years, uses of high-resolution population distribution databases are increasing steadily for environmental, socioeconomic, public health, and disaster-related research and operations. With the development of daytime population distribution, temporal resolution of such databases has been improved. However, the lack of incorporation of transitional population, namely business and leisure travelers, leaves a significant population unaccounted for within the critical infrastructure networks, such as at transportation hubs. This paper presents two general methodologies for estimating passenger populations in airport and cruise port terminals at a high temporal resolution which can be incorporated into existing population distribution models. The methodologies are geographically scalable and are based on, and demonstrate how, two different transportation hubs with disparate temporal population dynamics can be modeled utilizing publicly available databases including novel data sources of flight activity from the Internet which are updated in near-real time. The airport population estimation model shows great potential for rapid implementation for a large collection of airports on a national scale, and the results suggest reasonable accuracy in the estimated passenger traffic. By incorporating population dynamics at high temporal resolutions into population distribution models, we hope to improve the estimates of populations exposed to or at risk to disasters, thereby improving emergency planning and response, and leading to more informed policy decisions.     

Analytical models of steady-state plumes undergoing sequential first-order degradation

An exact, closed‐form analytical solution is derived for one‐dimensional (1D), coupled, steady‐state advection‐dispersion equations with sequential first‐order degradation of three dissolved species in groundwater. Dimensionless and mathematical analyses are used to examine the sensitivity of longitudinal dispersivity in the parent and daughter analytical solutions. The results indicate that the relative error decreases to less than 15% for the 1D advection‐dominated and advection‐dispersion analytical solutions of the parent and daughter when the Damköhler number of the parent decreases to less than 1 (slow degradation rate) and the Peclet number increases to greater than 6 (advection‐dominated). To estimate first‐order daughter product rate constants in advection‐dominated zones, 1D, two‐dimensional (2D), and three‐dimensional (3D) steady‐state analytical solutions with zero longitudinal dispersivity are also derived for three first‐order sequentially degrading compounds. The closed form of these exact analytical solutions has the advantage of having (1) no numerical integration or evaluation of complex‐valued error function arguments, (2) computational efficiency compared to problems with long times to reach steady state, and (3) minimal effort for incorporation into spreadsheets. These multispecies analytical solutions indicate that BIOCHLOR produces accurate results for 1D steady‐state, applications with longitudinal dispersion. Although BIOCHLOR is inaccurate in multidimensional applications with longitudinal dispersion, these multidimensional multispecies analytical solutions indicate that BIOCHLOR produces accurate steady‐state results when the longitudinal dispersion is zero. As an application, the 1D advection‐dominated analytical solution is applied to estimate field‐scale rate constants of 0.81, 0.74, and 0.69/year for trichloroethene, cis‐1,2‐dichloroethene, and vinyl chloride, respectively, at the Harris Palm Bay, FL, CERCLA site.