Oceanic plastic particle pollution: Suspected effect on fat deposition in red phalaropes

In a sample of seven red phalaropes (Phalaropus fulicarius: Aves) collected from a flock of 6000 late spring migrants, six stomachs contained plastic particles. A negative correlation between amount of plastic and fat condition suggests a detrimental effect of a widespread oceanic pollutant on a marine bird.     

Correlation of Alaskan varve thickness with climatic parameters, and use in paleoclimatic reconstruction

The thickness of varves in the sediments of Skilak Lake, Alaska, are correlated with the mean annual temperature (r = 0.574), inversely correlated with the mean annual cumulative snowfall (r = −0.794), and not correlated with the mean annual precipitation (r = 0.202) of the southern Alaska climatological division for the years 1907–1934 A.D. Varve thickness in Skilak Lake is sensitive to annual temperature and snowfall because Skilak Glacier, the dominant source of sediment for Skilak Lake, is sensitive to these climatic parameters. Trends of varve thickness are well correlated with trends of mean annual cumulative snowfall ( ) of the southern Alaska climatological division and with trends of mean annual temperature of the southern ( ) and northern ( ) Alaska climatological divisions. Trends of varve thickness also correlate with trends of annual temperature in Seattle and North Head, Washington ( , respectively). Comparisons of trends of varve thickness with trends of annual temperature in California, Oregon, and Washington suggest no widespread regional correlation. Trends of annual snowfall in the southern Alaska climatological division and trends of annual temperature in the southern and northern Alaska climatological divisions are reconstructed for the years 1700–1906 A.D. Climatic reconstructions on the basis of varve thickness in Skilak Lake utilize equations derived from the regression of series of smoothed climatological data on series of smoothed varve thickness. Reconstruction of trends of mean annual cunulative snowfall in the southern Alaska climatological division suggests that snowfall during the 1700s and 1800s was much greater than that during the early and mid-1900s. The periods 1770–1790 and 1890–1906 show marked decreases in the mean annual snowfall. Reconstructed trends of the annual temperature of the northern and southern Alaska climatological divisions suggest that annual temperatures during the 1700s and 1800s were lower than those of the early and mid-1900s. Two periods of relatively high annual temperatures coincide with the periods of low annual snowfall thus determined.     

Solid-state astrochemistry in star-forming regions

Surface-catalysed chemical reactions, the molecules they form, and the implications for star formation were key themes in an international workshop on "Solid-state chemistry in star-forming regions" at the Lorentz Centre, Leiden University, the Netherlands from 14–17 April 2003. Helen Fraser, David Williams, Ian Sims, Anita Richards and Jeremy Yates report.     

Chemical and isotopic constraints on the generation and transport of magma beneath the East Pacific Rise

Interpretation of U-series disequilibria in midocean ridge basalts is highly dependent on the bulk partition coefficients for U and Th and therefore the mineralogy of the mantle source. Distinguishing between the effect of melting processes and variable source compositions on measured disequilibria (²³⁸U-²³⁰Th-²²⁶Ra and ²³⁵U-²³¹Pa) requires measurement of the radiogenic isotopes Hf, Nd, Sr, and Pb. Here, we report measurements of ²³⁸U-²³⁰Th-²²⁶Ra and ²³⁵U-²³¹Pa disequilibria; Hf, Nd, Sr, and Pb isotopic; and major and trace element compositions for a suite of 20 young midocean ridge basalts from the East Pacific Rise axis between 9°28′ and 9°52′N. All of the samples were collected within the axial summit trough using the submersible Alvin. The geological setting and observational data collected during sampling operations indicate that all the rocks are likely to have been erupted from 1991 to 1992 or within a few decades of that time. In these samples, ²³⁰Th excesses and ²²⁶Ra excesses are variable and inversely correlated. Because the eruption ages of the samples are much less than the half-life of ²²⁶Ra, this inverse correlation between ²³⁰Th and ²²⁶Ra excesses can be considered a primary feature of these lavas. For the lava suite analyzed in this study, ²²⁶Ra and ²³⁰Th excesses also vary with lava composition: ²²⁶Ra excesses are negatively correlated with Na₈ and La/Yb and positively correlated with Mg#. Conversely, ²³⁰Th excesses are positively correlated with Na₈ and La/Yb and negatively correlated with Mg#. Th/U, ²³⁰Th/²³²Th, and ²³⁰Th excesses are also variable and correlated to one another. ²³¹Pa excesses are large but relatively constant and independent of Mg#, La/Yb, Th/U, and Na₈. The isotope ratios ¹⁴³Nd/¹⁴⁴Nd, ¹⁷⁶Hf/¹⁷⁷Hf, ⁸⁷Sr/⁸⁶Sr, and ²⁰⁸Pb/²⁰⁶Pb are constant within analytical uncertainty, indicating that they were derived from a common source. The source is homogeneous with respect to parent/daughter ratios Lu/Hf, Sm/Nd, Rb/Sr, and Th/U; therefore, the measured variations of Th/U, ²³⁰Th, and ²²⁶Ra excesses and major and trace element compositions in these samples are best explained by polybaric melting of a homogeneous source, not by mixing of compositionally distinct sources.     

Exploring the Functions of Different Forms of Trust in Collaborative Natural Resource Management

Successful natural resource management increasingly requires collaboration across boundaries and between diverse stakeholder groups, and trust is a key ingredient of successful collaboration. This study represents an early qualitative empirical attempt to understand how different forms of trust develop, function, and interact in collaborative natural resource management initiatives. We conducted case studies of four landscape-level initiatives in the Collaborative Forest Landscape Restoration Program (CFLRP). Our results suggest that three forms of trust, affinitive, rational, and procedural trust, were all important for successful collaboration, but different forms of trust appeared to function more powerfully during convening, recruitment, retention, and ongoing collaboration of stakeholders, with affinitive trust particularly important for convening, and rational and procedural trust gaining importance for recruiting and retention of members. We discuss the implications of the findings in both theoretical and practical terms.     

Validation of SeaWiFS chlorophyll a in Massachusetts Bay

Massachusetts Bay, a semi-enclosed embayment (50×100 km) in the Northwest Atlantic, is the focus of a monitoring program designed to measure the effects of relocating the Boston Harbor sewage outfall to a site 15 km offshore in Massachusetts Bay. The Massachusetts Water Resources Authority (MWRA) in situ monitoring program samples selected stations up to 17 times per year to observe seasonal changes in phytoplankton biomass and other water quality variables. We investigated the feasibility of augmenting the monitoring data with satellite ocean color data to increase the spatial and temporal resolution of quantitative phytoplankton measurements. In coastal regions such as Massachusetts Bay, ocean color remote sensing can be complicated by in-water constituents whose concentrations vary independently of phytoplankton and by inaccurate modeling of absorbing aerosols that tend to be concentrated near the coast. An evaluation of in situ and sea-viewing wide field-of-view sensor (SeaWiFS) measurements from 1998 to 2005 demonstrated that SeaWiFS overestimated chlorophyll a mainly due to atmospheric correction errors that were amplified by absorption from elevated concentrations of chlorophyll a and colored dissolved organic matter. Negative water-leaving radiances in the 412 nm band, an obvious artifact of inadequate atmospheric correction, were recorded in approximately 60–80% of the cloud-free images along the coast, while the remaining portions of the Bay only experience negative radiances 35–55% of the time with a clear nearshore to offshore decrease in frequency. Seasonally, the greatest occurrences of negative 412 nm radiances were in November and December and the lowest were recorded during the summer months. Concentrations of suspended solids in Massachusetts Bay were low compared with other coastal regions and did not have a significant impact on SeaWiFS chlorophyll a measurements. A regional empirical algorithm was developed to correct the SeaWiFS data to agree with in situ observations. Monthly SeaWiFS composites illustrated the spatial extent of a bimodal seasonal pattern, including prominent spring and fall phytoplankton blooms; and the approximate 115 cloud-free scenes per year revealed interannual variations in the timing, magnitude and duration of phytoplankton blooms. Despite known artifacts of SeaWiFS in coastal regions, this study provided a viable chlorophyll a product in Massachusetts Bay that significantly increased the spatial and temporal synoptic coverage of phytoplankton biomass, which can be used to gain a comprehensive ecosystem-wide understanding of phytoplankton dynamics at event, seasonal and interannual timescales.     

High-Resolution 0.33-0.92 μm Spectra of Iapetus, Hyperion, Phoebe, Rhea, Dione, and D-Type Asteroids: How Are They Related?

New high-resolution spectra in the 0.33 to 0.92 μm range of Iapetus, Hyperion, Phoebe, Dione, Rhea, and three D-type asteroids were obtained on the Palomar 200-inch telescope and the double spectrograph. The spectra of Hyperion and the low-albedo hemisphere of Iapetus can both be closely matched by a simple model that is the linear admixture of the spectrum of a medium-sized, high-albedo icy saturnian satellite and D-type material. Our results support an exogenous origin to the dark material on Iapetus; furthermore, this material may share a common origin and a similar means of transport with material on the surface of Hyperion. The recently discovered retrograde satellites of Saturn (Gladman et al., Nature412, 163-166) may be the source of this material. The leading sides of Callisto and the Uranian satellites may be subjected to a similar alteration mechanism as that of Iapetus: accretion of low-albedo dust originating from outer retrograde satellites. Phoebe does not appear to be related to either Iapetus or Hyperion. Separate spectra of the two hemispheres of Phoebe show no identifiable global compositional differences.     

A Search for Water Ice at the Lunar Poles with Clementine Images

Optical and near-IR signatures of water ice on the Moon's surface were sought in the permanently shadowed regions near its poles. Significant amounts of multiply-scattered radiation partly illuminate primary shadows cast by craters and other features. If there is water ice in the permanently shadowed regions of the Moon's surface, its spectral signature should appear in this multiply-scattered light. This investigation can be done most effectively with observations obtained by spacecraft, because most selenocentric positions occupied by the Earth will also be occupied by the Sun at some point in time, and because the lunar poles are seen only obliquely to a terrestrial observer. Images obtained by Clementine are particularly well-suited to this task, because the spacecraft's polar orbit allowed images of the poles to be acquired on nearly every orbit, resulting in literally thousands of images taken within a few degrees of each pole, and because the filters on the ultraviolet-visual camera (UVVIS) and the near infrared camera (NIR) occur at major absorption bands or within important continuum features of water ice. Approximately 5800 images obtained by the UVVIS camera and 1800 images obtained by the NIR camera were calibrated and combined into coadded mosaics to create multispectral maps of the lunar poles with the highest possible signal-to-noise. Unfortunately, analysis of our UVVIS mosaics indicates that any possible signal from multiply-scattered light in primary shadows was overwhelmed by instrumental stray light. For the NIR camera, we were able to determine the normalized reflectance of several regions that were identified by Margot et al. (1999, Science284, 1658-1660) as permanent shadows. We have identified one permanently shadowed crater with a 1.5-μm band spectral signature indicative of between 2.5 and 21% fractional coverage of H₂O frost. However, the same region shows a 2.0 μm spectral signature that is inconsistent with the presence of any water.