Structure of the Cobar Basin,New South Wales,based on seismic reflection profiling

The Cobar Basin in central western New South Wales is a mineral‐rich Early Devonian basin typical of those that characterize the Siluro‐Devonian history of the Lachlan Orogen of southeastern Australia. One hundred and seventy kilometres of seismic profiling in three lines across the basin have shown it to be asymmetrical in shape with an east‐dipping western margin that is steeper than the moderately west‐dipping eastern margin. Maximum basin thickness is around 6 km, but there are significant thickness changes, especially from south to north, which reflect the effect of synsedimentary faulting. Seismic profiling suggests that the basin deformed by thin‐skinned tectonics; postulated strike‐slip effects were not visible on the sections. The seismic profiling has, for the first time, imaged the western synrift basin margin which is generally not exposed. Strain variations during deformation along this edge were taken up by the formation of a major jog ('dog‐leg') which has propagated into the basin as a tear fault. Intrabasinal tears, as well as thrusts, which link into one or more detachments, provide potential pathways for mineralizing fluids during basin inversion.     

Analysis of the ferromagnetic contribution to the susceptibility by low field and high field methods in sedimentary rocks of the Southern Pyrenees and Northern Ebro foreland basin (Spain)

Magnetic susceptibility in rocks is the sum of the contributions of different magnetic particles (paramagnetic, diamagnetic and ferromagnetic s.l.). These contributions can be measured at variable temperatures or at variable fields (hysteresis loops). Both are time‐consuming techniques that cannot be routinely used in magnetic fabrics analysis. In this study, we propose a simplified method to determine the ferro‐ and paramagnetic contributions to the susceptibility, based on the discrete measurement of susceptibility at two different fields (near 0 and 2.5 T). The results obtained in samples from the Southern Pyrenees and Ebro Basin indicate that the ferromagnetic contribution vary considerably within homogeneous susceptibility values and within the expected range of paramagnetic values. Standard bulk susceptibilities higher than 200 10^?6 SI contribute significantly to the ferromagnetic fraction (>50% on average).     

Linking a prolonged Neo‐Tethyan magmatic arc in South Asia: Zircon U‐Pb and Hf isotopic constraints from the Lohit Batholith,NE India

The Neo‐Tethyan subduction that operated before the India‐Asia collision resulted in an Andean‐type convergent margin in South Asia and was associated with extensive arc magmatism that formed the Transhimalayan batholiths. Magmatism in the Gangdese Batholith, the largest batholith exposed in the Lhasa terrane of southern Tibet, is considered to have lasted from the early Jurassic to Eocene. However, eastward correlation of the Gangdese Batholith is uncertain because it is truncated by the eastern Himalayan syntaxis. Here, we report new data from the Lohit Batholith, NE India, including: (i) zircon U‐Pb ages of five granitoids from ca. 148 to 96 Ma; and (ii) zircon Hf isotopes of these rocks that yield high and positive ε_Hf(T) values. We argue that the Lohit Batholith is the eastward extension of the Gangdese Batholith, and can be correlated southward to the Wuntho‐Popa arc in West Burma, thus linking a prolonged Neo‐Tethyan magmatic arc system from southern Tibet to Southeast Asia.     

Chloride transfer in cement‐based materials. Part 1. Theoretical basis and modelling

In this first part of the work, we develop macroscopic models for migration and diffusion–migration of ionic species in saturated porous media, based on periodic homogenization. The prior application is chloride transport in cementitious materials. The dimensional analysis of Nernst–Planck equation lets appear to dimensionless numbers characterizing the ionic transfer in the porous medium. Using experimental data obtained from electrodiffusion tests on cement‐based materials (Part II), these dimensionless numbers are linked to the perturbation parameter ?. For a strong imposed electrical field, the asymptotic expansion of Nernst–Planck equation leads to a macroscopic model where the migration is predominant. For a weak imposed electrical field or in natural diffusion, we obtain a macroscopic model coupling diffusion and migration at the same order. In both models, the expression of the homogenized diffusion tensor is identical and only involves the geometric properties of the material microstructure. Copyright © 2012 John Wiley & Sons, Ltd.     

Phase equilibria constraints on melting of stromatic migmatites from Ronda (S. Spain): insights on the formation of peritectic garnet

Stromatic metatexites occurring structurally below the contact with the Ronda peridotite (Ojén nappe, Betic Cordillera, S Spain) are characterized by the mineral assemblage Qtz+Pl+Kfs+Bt+Sil+Grt+Ap+Gr+Ilm. Garnet occurs in low modal amount (2–5 vol.%). Very rare muscovite is present as armoured inclusions, indicating prograde exhaustion. Microstructural evidence of melting in the migmatites includes pseudomorphs after melt films and nanogranite and glassy inclusions hosted in garnet cores. The latter microstructure demonstrates that garnet crystallized in the presence of melt. Re‐melted nanogranites and preserved glassy inclusions show leucogranitic compositions. Phase equilibria modelling of the stromatic migmatite in the MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂–O₂–C (MnNCaKFMASHOC) system with graphite‐saturated fluid shows P–T conditions of equilibration of 4.5–5 kbar, 660–700 °C. These results are consistent with the complete experimental re‐melting of nanogranites at 700 °C and indicate that nanogranites represent the anatectic melt generated immediately after entering supersolidus conditions. The P–T estimate for garnet and melt development does not, however, overlap with the low‐temperature tip of the pure melt field in the phase diagram calculated for the composition of preserved glassy inclusions in garnet in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (NCKFMASH) system. A comparison of measured melt compositions formed immediately beyond the solidus with results of phase equilibria modelling points to the systematic underestimation of FeO, MgO and CaO in the calculated melt. These discrepancies are present also when calculated melts are compared with low‐T natural and experimental melts from the literature. Under such conditions, the available melt model does not perform well. Given the presence of melt inclusions in garnet cores and the P–T estimates for their formation, we argue that small amounts (<5 vol.%) of peritectic garnet may grow at low temperatures (≤700 °C), as a result of continuous melting reactions consuming biotite.     

Failure and size effect for notched and unnotched concrete beams

Modelling failure in geomaterials, concrete or other quasi‐brittle materials and proper accounting for size effect, geometry and boundary effects are still pending issues. Regularised failure models are capable of describing size effect on specimens with a specific geometry, but extrapolations to other geometries are rare, mostly because experimental data presenting size effect for different geometries and for the same material are lacking. Three‐point bending fracture tests of geometrically similar notched and unnotched specimens are presented. The experimental results are compared with numerical simulations performed with an integral‐type non‐local model. Comparisons illustrate the shortcomings of this classical formulation, which fails to describe size effect over the investigated range of geometries and sizes. Finally, experimental results are also compared with the universal size effect law. Copyright © 2013 John Wiley & Sons, Ltd.     

Spatial and temporal variability of surface water repellency in sandy loam soils of NW Spain under Pinus pinaster and Eucalyptus globulus plantations

This work was undertaken for two main purposes. One was to examine spatial and temporal variability in surface water repellency under field conditions in sandy loam forest soils of NW Spain, and its relationship to weather and soil moisture conditions. The other purpose was to get further inside in the dynamics of soil water repellency by studying a wetting–drying cycle under controlled laboratory conditions. Both for the field and laboratory study, water repellency was determined using the Water Drop Penetration Time test. Soil water repellency under field conditions was found to exhibit a seasonal pattern, i.e. it peaked during the summer and was absent between November and May. The time required for repellency to become re‐established during the spring was shorter under eucalyptus than under pine. Spatial variability peaked at an early stage of soil drying and was minimal during the wet period when soils were hydrophilic as well as at the end of the summer, when repellency was strongest. Spatial and temporal variability in water repellency was found to be negatively correlated with soil moisture and, to a lesser extent, with antecedent rainfall. The moisture range of the so‐called transition zone (below which the soil is hydrophobic and also above which it is hydrophobic) differed for the pine (21–50%) and eucalyptus plantations (17–36%). The lower and upper bounds of the transition zone agreed well with the soil moisture contents at the permanent wilting point and at field capacity, respectively. The laboratory results with samples in the wetting phase confirmed those of the field tests. Water repellency increased slightly during the drying phase, but not so much as in the field. Copyright © 2011 John Wiley & Sons, Ltd.     

Multivariate statistical analysis and environmental isotopes of Amman/Wadi Sir (B2/A7) groundwater,Yarmouk River Basin,Jordan

Multivariate statistical techniques, cluster and factor analyses were applied on the Amman/Wadi Sir groundwater chemistry, Yarmouk River basin, north Jordan. The main objective was to investigate the main processes affecting the groundwater chemical quality and its evolution. The k‐means cluster analysis yields three groups with distinct ionic concentrations. Cluster 1 comprises the vast majority of the sampled wells, and the water that belongs to this cluster can be classified as freshwater. Cluster 2 comprises only 2% of the sampled wells; it has the highest ionic concentration. The water of this cluster can be classified as brackish water. Cluster 3 involves 23% of the sampled wells, and it has total ionic concentration intermediate to that of clusters 1 and 2. Factor analysis yields a three‐factor model, which explains 76.77% of the groundwater quality variation. Factor 1 ‘salinity factor’ involves EC, Na⁺, Cl^‐, SO₄^‐2, K⁺ and Mg⁺² and reflects groundwater salinization because of overpumping. Factor 2 ‘hardness factor’ includes Ca⁺², HCO₃^‐ and the pH value and signifies soil–water/rock interaction. Factor 3 ‘nitrate factor’ involves only NO₃^‐ and points to groundwater contamination because of human activities, mainly untreated wastewater, and crops and animal cultivation in the unconfined portion of the aquifer. Factors 1 and 3 can be described as human‐induced factors, whereas factor 2 can be described as geogenic factor. Factors' scores were mapped to deduce the controlling processes on the groundwater chemistry. Stable isotope composition of ¹⁸O and ²H has revealed that the groundwater is a mixture of two water types. The radioactive isotopes tritium and ¹⁴ C were used to evaluate present day recharge to the aquifer and to estimate the groundwater age, respectively. Present day recharge to the groundwater is taking place in the unconfined portion of the aquifer as it is indicated by the measurable tritium content and low groundwater age. Copyright © 2012 John Wiley & Sons, Ltd.