Secondary alteration of the impactite and mineralization in the basal Tertiary sequence,Yaxcopoil‐1, Chicxulub impact crater,Mexico

Abstract The 65 Ma Chicxulub impact crater formed in the shallow coastal marine shelf of the Yucatán Platform in Mexico. Impacts into water‐rich environments provide heat and geological structures that generate and focus sub‐seafloor convective hydrothermal systems. Core from the Yaxcopoil‐1 (Yax‐1) hole, drilled by the Chicxulub Scientific Drilling Project (CSDP), allowed testing for the presence of an impact‐induced hydrothermal system by: a) characterizing the secondary alteration of the 100 m‐thick impactite sequence; and b) testing for a chemical input into the lower Tertiary sediments that would reflect aquagene hydrothermal plume deposition. Interaction of the Yax‐1 impactites with seawater is evident through redeposition of the suevites (unit 1), secondary alteration mineral assemblages, and the subaqueous depositional environment for the lower Tertiary carbonates immediately overlying the impactites. The least‐altered silicate melt composition intersected in Yax‐1 is that of a calc‐alkaline basaltic andesite with 53.4–56 wt% SiO_{2(volatile‐free)}. The primary mineralogy consists of fine microlites of diopside, plagioclase (mainly Ab 47), ternary feldspar (Ab 37 to 77), and trace apatite, titanite, and zircon. The overprinting alteration mineral assemblage is characterized by Mg‐saponite, K‐montmorillonite, celadonite, K‐feldspar, albite, Fe‐oxides, and late Ca and Mg carbonates. Mg and K metasomatism resulted from seawater interaction with the suevitic rocks producing smectite‐K‐feldspar assemblages in the absence of any mixed layer clay minerals, illite, or chlorite. Rare pyrite, sphalerite, galena, and chalcopyrite occur near the base of the impactites. These secondary alteration minerals formed by low temperature (0–150°C) oxidation and fixation of alkalis due to the interaction of glass‐rich suevite with down‐welling seawater in the outer annular trough intersected at Yax‐1. The alteration represents a cold, Mg‐K‐rich seawater recharge zone, possibly recharging higher temperature hydrothermal activity proposed in the central impact basin. Hydrothermal metal input into the Tertiary ocean is shown by elevated Ni, Ag, Au, Bi, and Te concentrations in marcasite and Cd and Ga in sphalerite in the basal 25 m of the Tertiary carbonates in Yax‐1. The lower Tertiary trace element signature reflects hydrothermal metal remobilization from a mafic source rock and is indicative of hydrothermal venting of evolved seawater into the Tertiary ocean from an impact‐generated hydrothermal convective system.     

ISO SWS Spectroscopy of Proto-Planetary Nebulae

We are obtaining low- (SWS01) and medium-resolution (SWS06) spectra of PPNe to investigate spectral features arising in these transitional objects. Three sources with the 21 μm feature have been confirmed, one new source found, and evidence of some substructure seen. This revised version was published online in August 2006 with corrections to the Cover Date.     

shinyNORRRM: A Cross-Platform Software to Calculate the CIPW Norm

In this paper, a novelty-free software to assess an efficient CIPW Norm (± 0.006 wt.% in differences between input and output data) is presented. The package is available in the official repository for user-contributed R packages (CRAN: Comprehensive R Archive Network). The software is able to handle big data sets and considers minor and trace element compositions. The algorithm can calculate odd minerals in igneous rocks, such as cancrinite and calcite, adjust the Fe⁺³/Fe⁺² ratio in different standard approaches, and recalculate the compositions of the rocks in an anhydrous basis (100 ± 0.003 wt.% volatile-free adjusted). Furthermore, the package calculates several petrological parameters, and the graphical outputs are displayed following IUGS scheme standards. The prime aspect of shinyNORRRM is the symbiosis of native R functions with the R package’s shiny (Web Application Framework for R) to run the norm in a user-friendly interface. shinyNORRRM can be executed in any operating system and requires no previous programming knowledge, thus promising to be the universal computational program in this matter. The output data are printed in the standard comma-separated values (*.csv) format, which is highly compatible with general spreadsheet editors. In this work, the algorithm of our program is validated using already compiled whole-rock geochemical databases.

     

A three-level framework for multi-risk assessment

The effective management of the risks posed by natural and man-made hazards requires all relevant threats and their interactions to be considered. This paper proposes a three-level framework for multi-risk assessment that accounts for possible hazard and risk interactions. The first level is a flow chart that guides the user in deciding whether a multi-hazard and risk approach is required. The second level is a semi-quantitative approach to explore if a more detailed, quantitative assessment is needed. The third level is a detailed quantitative multi-risk analysis based on Bayesian networks. Examples that demonstrate the application of the method are presented.     

Equatorial Atlantic sea surface temperature variations: Research note

Abstract

Monthly mean sea surface temperature (SST) anomalies were computed for six 10°‐wide boxes stretching across the equatorial Atlantic Ocean for the period 1890–1979. These values were used to produce a time‐longitude section of the interannual SST variability along the equator. This section shows cycles of basin‐wide warming and cooling occurring with irregular periods that typically range between two and four years. The warming and cooling events in these cycles normally display some westward phase propagation. The peak magnitudes of the interannual SST anomalies are generally of the order of 1°C or less, except in the Gulf of Guinea where they can be somewhat larger.

An estimate was made of the basin‐wide equatorial SST anomaly in each month (excluding the Gulf of Guinea). This was composited around the times of the warm and cold extremes of the Pacific Southern Oscillation. This analysis revealed a detectable, but rather weak, tendency for phase locking of the interannual SST variations in the equatorial Pacific and Atlantic oceans.     

Calculation of the effect of stratospheric mean wind variations on the solar semidiurnal barometric oscillation

Abstract

A simple perturbation procedure is developed for incorporating the effects of mean zonal winds in atmospheric tidal calculations. This method is used to determine the variation of the solar semidiurnal surface pressure oscillation, S₂(p), that is expected to result from the mean wind changes during the course of the quasi‐biennial oscillation of the tropical stratosphere. The results are consistent with earlier observations of a quasi‐biennial variation in S₂(p). Some new observations of biennial variability in S₂(p) at four tropical stations are also discussed.     

Identifying coherent spatiotemporal modes in time-uncertain proxy paleoclimate records

High-resolution sedimentary paleoclimate proxy records offer the potential to expand the detection and analysis of decadal- to centennial-scale climate variability during recent millennia, particularly within regions where traditional high-resolution proxies may be short, sparse, or absent. However, time uncertainty in these records potentially limits a straightforward objective identification of broad-scale patterns of climate variability. Here, we describe a procedure for identifying common patterns of spatiotemporal variability from time uncertain sedimentary records. This approach, which we term Monte Carlo Empirical Orthogonal Function analysis, uses iterative age modeling and eigendecomposition of proxy time series to isolate common regional patterns and estimate uncertainties. As a test case, we apply this procedure to a diverse set of time-uncertain lacustrine proxy records from East Africa. We also perform a pseudoproxy experiment using climate model output to examine the ability of the method to extract shared anomalies given known signals. We discuss the advantages and disadvantages of our approach, including possible extensions of the technique.     

Tree-ring reconstructed summer temperature anomalies for temperate East Asia since 800 C.E.

We develop a summer temperature reconstruction for temperate East Asia based on a network of annual tree-ring chronologies covering the period 800–1989 C.E. The East Asia reconstruction is the regional average of 585 individual grid point summer temperature reconstructions produced using an ensemble version of point-by-point regression. Statistical calibration and validation tests indicate that the regional average possesses sufficient overall skill to allow it to be used to study the causes of temperature variability and change over the region. The reconstruction suggests a moderately warm early medieval epoch (ca. 850–1050 C.E.), followed by generally cooler ‘Little Ice Age’ conditions (ca. 1350–1880 C.E.) and 20th century warming up to the present time. Since 1990, average temperature has exceeded past warm epochs of comparable duration, but it is not statistically unprecedented. Superposed epoch analysis reveals a volcanic forcing signal in the East Asia summer temperature reconstruction, resulting in pulses of cooler summer conditions that may persist for several years. Substantial uncertainties remain, however, particularly at lower frequencies, thus requiring caution and scientific prudence in the interpretation of this record.     

Action targets: a new approach to international greenhouse gas controls

Abstract

This article introduces and explores a new form of international commitment to limit greenhouse gas (GHG) emissions, called an action target. Action targets differ from other forms of targets, such as the Kyoto Protocol's fixed targets, in that they define a quantity of GHG abatement to be achieved, rather than a future emission level to be reached. This article explains the basic mechanics of how action targets might operate, and analyses the approach across a range of criteria, including uncertainty management and contributions to sustainable development in non-Annex I (developing) countries. The analysis suggests that action targets might improve the prospects of widening and deepening developing country participation in the international climate regime.     

Evolution of a Holocene banner bank controlled by morphodynamics and structural setting of a macrotidal coast: Saint-Brieuc Bay(NW-Europe)

The morphology and internal structure of the Horaine Bank(Bay of Saint-Brieuc, NW France) are described based on multibeam echosounder and high-resolution seismic datasets coupled with vibro-core data. The Horaine Bank shows large-scale bedforms in the lee of a submerged rocky shoal, which allowed defining it as a Banner Bank.The internal structure of the sandbank reveals four seismic units(U1–U4) on a Cambrian basement(U0). The basal unit U1 is interpreted as reworked lowstand fluvial sediments those infilled micro incised valleys during a rise in sea level. This unit is overlain by paleo-coastal barrier sand-spit(U2) whose development was controlled by swell in the context of a rapid rise in sea level. The successive prograding unit(U3) is interpreted as flooding deposits in continuity with unit U2. The unit U4 is characterized by oblique reflectors oriented in two opposite directions. This last unit, dated post 3500 yr BP, corresponds to migrating dunes superimposed on the bank and observable in the high-resolution bathymetric data. The strong correlation between tidal currents and the apparent clockwise migration of dune crests suggests the presence of a tidal gyre controlling the present-day dynamics of most of the Horaine bank dunes. This study proposes a new model for the construction of banner banks characterized by the gradual transition of a sand spit to a banner bank during marine transgression and ensuing hydrodynamic variability.