Collating Historic Weather Observations for the East Asian Region:Challenges,Solutions,and Reanalyses

正1.Introduction Historic instrumental weather observations,made on land or at sea from as early as the 17th century(e.g.,Camuffo et al.,2010),are integral to extending our understanding of the decadal and centennial variations of Earth’s climate and for comparison with paleo-proxy data.The potential of such data is shown to best effect when used in dynamical 4D global     

ENSO and Sea Surface Temperature Anomalies in Association with Canadian Wheat Yield Variability

Interannual variations of spring wheat yields in Canadian agricultural regions are analyzed, together with the associated sea surface temperature (SST) anomalies in the northern hemisphere tropics and extratropics, from 1961 to 2015. The cubic trend is calculated and used to represent the trend related to advances in agricultural technology over this time period. The correlations between Canadian wheat yields at regional scales and the tropical El Niño–Southern Oscillation (ENSO) variability are not robust at any stage of the evolution of ENSO. Based on the power spectrum and cross-spectrum analysis, the most prominent yield variance is found in the Canadian Prairies, with a significant power peak of 4.5 years but does not co-vary significantly with interannual ENSO variability. ENSO weakly affects temperature and precipitation anomalies in the Canadian Prairie Region in summer—two important agroclimatic conditions for crop growth—and hence insignificantly impacts wheat yields. This indicates that there would be little benefit to including tropical ENSO indices in the operational wheat yield forecasting system. For Canadian wheat yield forecasting, attention should be paid to the preceding winter and spring SST anomalies in the northern extratropics. The SST anomalies associated with yields in the Canadian Prairie region and Central Region are generally stronger than those associated with yields in the Canadian Pacific Coast Region and eastern Maritime Region. In association with the Prairie Region and Central Region yields, SST shows pronounced anomalies in the mid-high latitudes of the North Pacific from winter to summer. The non-linearity of the SST anomalies associated with the Canadian yields is also clearly evident. Stronger (weaker) SST anomalies in the extratropical North Pacific correspond to low wheat yields in the Prairie (Central) Region, while weaker (stronger) SST anomalies correspond to high yields in the Prairie (Central) Region.     

Population Shrinkage in Resource-dependent Cities in China: Processes,Patterns and Drivers

Resource-dependent cities(RCs)are a vulnerable group of urban settlements that often face population shrinkage;however,population changes in RCs in China are not well understood.This study offers new insight into this matter through a robust analysis that features a longer time scale,a larger sample of RCs,and a finer unit of analysis.It finds new evidence that problems of population shrinkage in RCs are more serious than previous literature has suggested.Approximately 30%of the studied units have experienced either long-term or short-term population shrinkage,and many more are experiencing a slowing down of population growth.Problems are especially common among three types of RCs:the resource-depleted RCs,the forestry-based RCs,and RCs in Northeast China.These results underscore transition policy inadequacies in addressing population loss,and call for a more comprehensive and diversified population policy that tackles the multifaceted factors that contribute to population shrinkage,including lack of industrial support,maladjustment to market oriented reformation,poor urban environment and natural population decline.     

The Influence of Salinity on the Uptake, Distribution, and Excretion of Metals by the Smooth Cordgrass, Spartina alterniflora (Loisel.), Grown in Sediment Contaminated by Multiple Metals

The effect of salinity on the concentration of metals in Spartina alterniflora tissues and excreted salts and the distribution of metals between these compartments was tested in a greenhouse experiment. S. alterniflora stems were planted in pots of dredge sediment that was amended with a suite of six metals (Cd, Cr, Cu, Ni, Pb, and Zn). The overlying water of individual pots was maintained at treatment salinities of 0, 15, or 30 practical salinity units. The proportion of total metal distributed to the tissues and excreted salt of S. alterniflora was not significantly influenced by salinity for any of the metals. The concentration of Pb in root and leaf tissues and in excreted salt was influenced by salinity, as was the concentration of Zn in root tissue and excreted salt. Contrary to expectations, the concentration of Pb and Zn in excreted salts decreased as salinity increased. Although the influence of salinity on the concentration of Pb and Zn in S. alterniflora tissue has not been previously reported, the influence of salinity on the tissue concentrations of Pb agrees with previous research on dicots.     

The importance of talc and chlorite “hybrid” rocks for volatile recycling through subduction zones; evidence from the high-pressure subduction mélange of New Caledonia

The transfer of fluid and trace elements from the slab to the mantle wedge cannot be adequately explained by simple models of slab devolatilization. The eclogite-facies mélange belt of northern New Caledonia represents previously subducted oceanic crust and contains a significant proportion of talc and chlorite schists associated with serpentinite. These rocks host large quantities of H₂O and CO₂ and may transport volatiles to deep levels in subduction zones. The bulk-rock and stable isotope compositions of talc and chlorite schist and serpentinite indicate that the serpentinite was formed by seawater alteration of oceanic lithosphere prior to subduction, whereas the talc and chlorite schists were formed by fluid-induced metasomatism of a mélange of mafic, ultramafic and metasedimentary rocks during subduction. In subduction zones, dehydration of talc and chlorite schists should occur at sub-arc depths and at significantly higher temperatures (∼ 800°C) than other lithologies (400–650°C). Fluids released under these conditions could carry high trace-element contents and may trigger partial melting of adjacent pelitic and mafic rocks, and hence may be vital for transferring volatile and trace elements to the source regions of arc magmas. In contrast, these hybrid rocks are unlikely to undergo significant decarbonation during subduction and so may be important for recycling carbon into the deep mantle. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Early diagenetic vivianite [Fe3(PO4)2 · 8H2O] in a contaminated freshwater sediment and insights into zinc uptake: A μ-EXAFS, μ-XANES and Raman study

The sediments in the Salford Quays, a heavily-modified urban water body, contain high levels of organic matter, Fe, Zn and nutrients as a result of past contaminant inputs. Vivianite [Fe₃(PO₄)₂ · 8H₂O] has been observed to have precipitated within these sediments during early diagenesis as a result of the release of Fe and P to porewaters. These mineral grains are small (<100 μm) and micron-scale analysis techniques (SEM, electron microprobe, μ-EXAFS, μ-XANES and Raman) have been applied in this study to obtain information upon the structure of this vivianite and the nature of Zn uptake in the mineral. Petrographic observations, and elemental, X-ray diffraction and Raman spectroscopic analysis confirms the presence of vivianite. EXAFS model fitting of the FeK-edge spectra for individual vivianite grains produces Fe–O and Fe–P co-ordination numbers and bond lengths consistent with previous structural studies of vivianite (4O atoms at 1.99–2.05 Å; 2P atoms at 3.17–3.25 Å). One analysed grain displays evidence of a significant Fe³⁺ component, which is interpreted to have resulted from oxidation during sample handling and/or analysis. EXAFS modelling of the Zn K-edge data, together with linear combination XANES fitting of model compounds, indicates that Zn may be incorporated into the crystal structure of vivianite (4O atoms at 1.97 Å; 2P atoms at 3.17 Å). Low levels of Zn sulphate or Zn-sorbed goethite are also indicated from linear combination XANES fitting and to a limited extent, the EXAFS fitting, the origin of which may either be an oxidation artifact or the inclusion of Zn sulphate into the vivianite grains during precipitation. This study confirms that early diagenetic vivianite may act as a sink for Zn, and potentially other contaminants (e.g. As) during its formation and, therefore, forms an important component of metal cycling in contaminated sediments and waters. Furthermore, for the case of Zn, the EXAFS fits for Zn phosphate suggest this uptake is structural and not via surface adsorption.     

Frequency domain electromagnetic and ground penetrating radar investigation of ephemeral streams: case study near the Southern High Plains,Texas

A frequency domain electromagnetic (FDEM) and ground penetrating radar (GPR) study was conducted on an ephemeral stream in north-central Texas to determine if FDEM and GPR measurements can be combined to determine the electrical characteristics of current and ancient stream channels. GPR data were collected at several frequencies to image sedimentary structures of different scale lengths, and to determine the formation porosity and water content of stream sediments. FDEM measurements were collected using Geonics EM31 and EM34 loop–loop instruments on a profile along the current stream channel and five profiles perpendicular to the channel. The results indicate that the greater spatial resolution of the EM31 mapped the current and possible ancient channels better than the EM34, however, the EM34 provided depth information on the formations underlying the channel sediments that the EM31 could not image. GPR measurements taken along a point bar deposit with 200, 100 and 25 MHz antennae indicated that the higher frequency antenna better resolved channel structures including laminar bedding, trough scours and cross-bedding, however, lower frequency antenna (25 MHz) imaged sedimentary structures within the underlying channel sediments. Common midpoint GPR measurements collected along the point bar deposit were used to estimate the sediment formation porosity (26%) and the water content, during a dry period, of the unsaturated (12%) and saturated (26 or 100% of the pore space) sediments. The combined results indicated that the FDEM data should be collected first because of the speed and ease of measurements. The FDEM data (especially the EM31) pointed to the locations of possible sedimentary structures, which can then be resolved by using different frequency GPR measurements.     

Crowdsourcing a cyclist perspective on suggested recreational paths in real-world networks

ABSTRACT

Routing and navigation services for leisure activities are conditioned by special needs and trade-offs. The advent of online communities and large crowdsourced datasets offers opportunities to improve the adoption of a user’s perspective in these suggested paths. This paper focuses on achieving two goals. First, the presented methodology analyses a dataset of 190,610 historical GPS traces to gain insights into the appreciation or attractiveness of each edge in a real-world network for a specific leisure activity (i.e. road cycling). Second, as literature on these leisure activities is still sparse, we want to create a thorough understanding of the activities at hand for future work. An appreciation model is proposed and the spread of this score is analyzed in shortest-path alternatives of popular routing engines for this activity. This analysis successfully discriminates these shortest paths based on the scoring value and three morphological parameters of the path. However, the robustness of the model should be improved to ensure the viability of the proposed approach in future work. More specifically, further research on the local optimality of the route choices will be imperative.     

Prediction of minesite-drainage chemistry through closure using operational monitoring data

Post-mining drainage chemistry depends strongly on geochemical and hydrologic processes that occur during the operational years. Where routine operational monitoring data are abundant, the dominant processes can often be evaluated with no additional, special studies. Thus, post-mining drainage chemistry can be predicted with confidence based on the operational data. This is referred to here as ‘empirical drainage-chemistry modelling’ (EDCM).This paper presents examples of EDCM using routine monitoring databases from several minesites, each containing thousands of analyses and spanning up to 30 years of mine operation and closure. Simple statistical interpretations in the EDCM can reveal annual cycles and trends that aqueous concentrations display during operation and into closure.A new compilation of 12 EDCM equations for copper versus pH is presented to illustrate similar trends with pH among the sites. However, this compilation also shows that average-annual copper concentrations at a particular pH can vary by three orders of magnitude, reflecting site-specific factors. Also, a new case study comparing actual closure concentrations to those predicted with EDCM in 1991 demonstrates that predictive accuracy is within a factor of two.     

Roof sequence response to emplacement of the Wills Mountain duplex: the roles of forethrusting and scales of deformation

This paper focuses on the behavior of a roof sequence in the Appalachian Plateau of West Virginia, U.S.A., and emplacement of the Wills Mountain duplex with 17.5 km of displacement. Unlike the Plateau along strike in Pennsylvania and New York where forethrusting was previously documented, this roof sequence lacks an underlying salt-dominated roof décollement. Kinematic analyses reveal that the roof sequence in the West Virginian Plateau accommodated about two-thirds of the 17.5 km of shortening by the adjacent Wills Mountain duplex, as a forethrusting kinematic response. The remaining shortening imbalance of about 5 km between the duplexes and younger roof sequence rocks is accommodated by additional forethrusting further into the foreland and local compensation. This kinematic response matches that along strike in the central Appalachians despite the loss of the salt décollement. We interpret that an Ordovician shale-dominated formation was sufficiently weak to substitute for the salt horizon. Thus, a weak mechanical unit rather than specifically a salt décollement is a necessary prerequisite for forethrusting. A contributing factor to forethrusting may be the subvertical front of the Wills Mountain duplex, which inhibited other responses by the roof sequence. Mesoscale and smaller processes, including grain-to-grain pressure solution, twinning and cleavage formation account for over 75% of the shortening in the roof sequence, and, if ignored, would result in an erroneous interpretation of backthrusting or local compensation. This result suggests that failure to consider all deformation scales could lead to incorrect kinematic conclusions in other tectonic systems.