Radium and thorium isotopes in the surface waters of the East Pacific and coastal Southern California

A fiber extraction technique is used to concentrate Ra and Th isotopes from 1000 liters or more of seawater. Natural²²⁶Ra and²³⁴Th are used as yield tracers. In the equatorial Pacific the²²⁸Ra activity of surface water varies from 20 to 1 dpm/1000 kg and generally decreases away from continental shelf areas. Across the Peru Current System, this decrease is modeled as one-dimensional diffusion and indicates the possibility of two flow regimes with distinct characteristic mixing lengths and apparent eddy diffusivities of 10⁵ and 10⁷ cm²/s. The perturbing effects of advection and equatorial upwelling west of the Galapagos Islands are noted. Off the coast of Southern California a vertical²²⁸Ra distribution gives an apparent diffusivity of 1.6 cm²/s for the upper thermocline.²²⁶Ra concentrations near the coast appear to be higher than the open ocean values at comparable depths, which may reflect supply of this isotope from continental shelf sediments and/or upwelling. The insoluble daughter/soluble parent activity ratios²²⁸Th/²²⁸Ra and²³⁴Th/²³⁸U in the equatorial Pacific surface water display latitudinal trends which may be correlated with productivity variations. Near the coast of California these ratios reflect the differing oceanographic conditions north and south of Pt. Conception indicating a mean chemical removal time constant on the order of 4 months for Th and other highly reactive elements within the Southern California Bight. The²³²Th content of seawater sampled is less than 0.1 μg/1000 1; most of the published values for seawater²³²Th could well be too high. A comparison of the two methods of determining²²⁸Ra (via²²⁸Ac and via²²⁸Th) made on 64 seawater samples shows that the time delay required by the²²⁸Th method is more than compensated by its better analytical simplicity and precision.     

The abundance of cadmium and zinc in meteorites

A stable isotope dilution technique using solid source mass spectrometry has been used to accurately determine Cd and Zn in a wide range of materials. The abundance of Cd has been determined in 19 iron, 28 stone and 1 stony-iron meteorites, together with a number of other samples. The abundance of Zn has also been determined for most of these samples. This has enabled the relationship between Cd and Zn to be examined in iron and stone meteorites. The abundance pattern of Zn in iron meteorites supports the existence of chemical groups.     

The occurrence of selected human pharmaceutical compounds in UK estuaries

This report describes a scoping study conducted in order to establish whether pharmaceutical compounds may be present in UK estuaries. Surface water samples collected from five UK estuaries were analysed for the presence of 14 pharmaceutical compounds selected from the priority lists of the UK Environment Agency and the Oslo and Paris Commission (OSPAR). The pharmaceutical compounds/metabolites clofibric acid, clotrimazole, dextropropoxyphene, diclofenac, ibuprofen, mefenamic acid, propranolol, tamoxifen and trimethoprim were detected at measurable concentrations in the samples collected. The concentrations of erythromycin, lofepramine, paracetamol, sulfamethoxazole and acetyl-sulfamethoxazole were all below the limits of detection of the methods used (between 4 and 20 ng l(-1)). The anti-fungal agent clotrimazole was the most frequently detected at a maximal concentration of 22 ng l(-1) and a median concentration of 7 ng l(-1). The analgesic compound ibuprofen was detected at a maximal concentration of approximately 930 ng l(-1) and a median concentration of 48 ng l(-1), whilst the other pharmaceutical compounds were detected between the limits of detection of the method used and 570 ng l(-1).     

A simple method to reduce discharge of sewage microorganisms from an Antarctic research station

The majority of coastal Antarctic stations release untreated sewage into the near-shore marine environment. This study examined bacterial reproduction within the temporary sewage-holding tanks of Rothera Research Station (Adelaide Island, Antarctic Peninsula) and monitored sewage pollution in the local marine environment. By continuously flushing the sewage-holding tanks with cold seawater we inhibited microbial reproduction and decreased the numbers of bacteria subsequently released into the sea by >90%. The widespread use of this simple method could significantly reduce the numbers of faecal coliform and other non-native microorganisms introduced into the Antarctic marine environment.     

Working rivers: the geomorphological legacy of English freshwater mills

Freshwater mills historically were found throughout England serving a wide variety of uses. The decline in the need for water power over the last 100 years saw a reduction in the number of operational mills. Despite this decline, the associated river structures were rarely removed and many of these have exceeded their design life and have failed or are now starting to fail, with important geomorphological implications for the river. This paper investigates the geomorphological impacts of mills and their structures on English rivers, and considers their legacy for the contemporary management of these systems.     

Mapping Soils,Vegetation, and Landforms: An Integrative Physical Geography Field Experience*

Students in a graduate seminar at Michigan State University produced a series of detailed vegetation, soils, and landform maps of a 1.5‐square‐mile (3.9 km²) study area in southwest Lower Michigan. The learning outcomes (maps) and skill development objectives (sampling strategies and various GIS applications) of this field‐intensive mapping experience were driven by the assumption that students learn and understand relationships among physical landscape variables better by mapping them than they would in a classroom‐based experience. The group‐based, problem‐solving format was also intended to foster collaboration and camaraderie. The study area lies within a complex, interlobate moraine. Fieldwork involved mapping in groups of two or three, as well as soil and vegetation sampling. Spatial data products assembled and used in the project included topographic maps, a digital elevation model (DEM), aerial photographs, and NRCS (National Resource Conservation Service) soil maps. Most of the soils are dry and sandy, with the main differentiating characteristic being the amount of, and depth to, subsurface clay bands (lamellae) or gravelly zones. The presettlement (early 1830s) vegetation of the area was oak forest, oak savanna, and black oak “barrens.” Upland sites currently support closed forests of white, black, and red oak, with a red maple, dogwood, and sassafras understory. Ecological data suggest that these oak forests will, barring major disturbance, become increasingly dominated by red maple. This group‐based, problem‐solving approach to physical geography education has several advantages over traditional classroom‐based teaching and could also be successfully applied in other, field‐related disciplines.     

Regional Population and Employment Change in Australia 1991–2001: Inertia in the Face of Rapid Change?

Analyses of the patterns of national population change have been influenced by the US experience where major differences between a older north and a newer south are prominent in many studies. The current paper argues that these perspectives overlook some inertia in the pattern of population and jobs. Drawing upon US and European experience the paper explores the pattern of change in Australia. There it finds that population has favoured newer locations but that gains in share of national population have not been large. At the same time some of the older regions have maintained population share, or at worst recorded small declines. That broad insight is enriched by sectoral analysis where it is clear that only the retail sector has experienced the large gains in new regions; employment change in other sectors showed the links with population change are weak. The paper concludes that simple notions of new region population and employment gains are oversimplified and overlook the substantial development around established centres. In particular it is possible that the old regions are re-structuring their spatial form and spilling over statistical boundaries and so actually maintaining established role in national networks.     

Petrogenesis and tectonic setting of the peralkaline Pine Canyon caldera, Trans-Pecos Texas, USA

The Pine Canyon caldera is a small (6–7 km diameter) ash-flow caldera that erupted peralkaline quartz trachyte, rhyolite, and high-silica rhyolite lavas and ash-flow tuffs about 33–32 Ma. The Pine Canyon caldera is located in Big Bend National Park, Texas, USA, in the southern part of the Trans-Pecos Magmatic Province (TPMP). The eruptive products of the Pine Canyon caldera are assigned to the South Rim Formation, which represents the silicic end member of a bimodal suite (with a “Daly Gap” between 57 and 62 wt.% SiO₂); the mafic end member consists primarily of alkali basalt to mugearite lavas of the 34–30 Ma Bee Mountain Basalt. Approximately 60–70% crystallization of plagioclase, clinopyroxene, olivine, magnetite, and apatite from alkali basalt coupled with assimilation of shale wall rock (M_a/M_c = 0.3–0.4) produced the quartz trachyte magma. Variation within the quartz trachyte–rhyolite suite was the result of 70% fractional crystallization of an assemblage dominated by alkali feldspar with subordinate clinopyroxene, fayalite, ilmenite, and apatite. High-silica rhyolite is not cogenetic with the quartz trachyte–rhyolite suite, and can be best explained as the result of  5% partial melting of a mafic granulite in the deep crust under the fluxing influence of fluorine. Variation within the high-silica rhyolite is most likely due to fractional crystallization of alkali feldspar, quartz, magnetite, biotite, and monazite. Lavas and tuffs of the South Rim Formation form A-type rhyolite suites, and are broadly similar to rock series described in anorogenic settings both in terms of petrology and petrogenesis. The Pine Canyon caldera is interpreted to have developed in a post-orogenic tectonic setting, or an early stage of continental rifting, and represents the earliest evidence for continental extension in the TPMP.     

Formation of subantarctic mode water in the southeastern Indian Ocean

Subantarctic Mode Water (SAMW) is the name given to the relatively deep surface mixed layers found directly north of the Subantarctic Front in the Southern Ocean, and their extension into the thermocline as weakly stratified or low potential vorticity water masses. The objective of this study is to begin an investigation into the mechanisms controlling SAMW formation, through a heat budget calculation. ARGO profiling floats provide estimates of temperature and salinity typically in the upper 2,000 m and the horizontal velocity at various parking depths. These data are used to estimate terms in the mode water heat budget; in addition, mode water circulation is determined with ARGO data and earlier ALACE float data, and climatological hydrography. We find a rapid transition to thicker layers in the central South Indian Ocean, at about 70°S, associated with a reversal of the horizontal eddy heat diffusion in the surface layer and the meridional expansion of the ACC as it rounds the Kerguelen Plateau. These effects are ultimately related to the bathymetry of the region, leading to the seat of formation in the region southwest of Australia. Upstream of this region, the dominant terms in the heat budget are the air–sea flux, eddy diffusion, and Ekman heat transport, all having approximately equal importance. Within the formation area, the Ekman contribution dominates and leads to a downstream evolution of mode water properties.