Application of organic petrology and geochemistry to coal waste studies

Coal wastes produced during mining activities are commonly deposited in nearby dumps. These wastes mostly composed of minerals and variable amounts (usually 20-30%) of organic matter start to weather immediately after deposition. Oxidation of the organic matter can lead to self heating and self combustion as a result of organic and mineral matter transformations. The degree of alteration depends on the properties of the wastes, i.e., the maceral and microlithotype composition of the organic matter and its rank.Alteration of wastes also depends on the heating history, i.e., the rate of heating, final heating temperature, duration of heating, and the degree of air access. Although air is probably necessary to initiate and drive the heating processes, these usually take place under relatively oxygen depleted conditions. With slow heating, color of organic matter particles changes, irregular cracks and oxidation rims develop around edges and cracks, and bitumen is expelled. As a result, massive and detritic isotropic and strongly altered organic matter forms. On the other hand, higher heating rates cause the formation of devolatilization pores, oxidation rims around these pores and along cracks, vitrinite-bands-mantling particles, and bitumen expulsions.Organic compounds generated from the wastes include n-alkanes, iso-alkanes, alkylcyclohexanes, acyclic isoprenoids, mainly pristane, phytane and, in some cases, farnesane, sesquiterpanes, tri- and tetracyclic diterpanes, tri- and pentacyclic triterpanes, and steranes, polycyclic aromatic hydrocarbons (mostly with two- to five rings, rarely six rings), and phenols. The compounds formed change during the heating history. The fact that phenols are found in dumps where heating has not yet been completed, but are absent in those where heating ceased previously suggests the presence of water washing. The organic compounds formed may migrate within the dumps. However, when they migrate out of the dumps, they become a hazard to environment.This paper is a review on transformations of organic matter (both maceral composition and reflectance and chemical composition) in coal wastes deposited in coal waste dumps. Immediately after deposition the wastes are exposed to weathering conditions and sometimes undergo self heating processes.     

Tephra stratigraphy on the North Icelandic shelf: extending tephrochronology into marine sediments off North Iceland

Tephra stratigraphical and tephrochronological studies of marine core MD99‐2275 on the North Icelandic shelf have revealed 58 new tephra horizons within the last 7050 cal. a BP, bringing the total number of identified tephra layers to 76. So far, over 100 tephra layers have been identified in the entire core spanning the last 15 000 years. The majority of the newly identified tephra layers are basaltic in composition and originate from the most active volcanic systems in Iceland, namely Grímsvötn, Veidivötn‐Bárdarbunga and Katla. A total of 40 tephra layer land–sea correlations have been made within this time period, of which 16 represent absolutely dated tephra markers. In addition, two tephra marker series are revealed in the marine sediments and in the terrestrial tephra stratigraphy, located between c. 2300–2600 and between 5700–5900 years. For the last 15 000 years, 21 tephra markers have been recognized. The marine tephra layer frequency (TLF) reveals two peaks, within the last 2000 years, and between 5000 and 7000 years ago. It shows the same general characteristics as the terrestrial TLF curve in Iceland, which indicates that marine sediments can yield important information about volcanism in Iceland. This is useful in time segments in which terrestrial records are poor or non‐existent. The study contributes to a high‐resolution tephrochronological framework on the North Icelandic shelf, with core MD99‐2275 representing a potential stratotype section in the area, and for the northern North Atlantic–Nordic Seas region, as well as being an important contribution to the Lateglacial–early Holocene volcanic history of Iceland.     

Discovery of Pyrrhotite-Chalcopyrite-Bearing Amphibole Megacrysts in Tongling Area, Anhui Province

Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts, belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts.amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well.     

A rational method for development of limit state for liquefaction evaluation based on shear wave velocity measurements

This papers presents a new approach for developing a limit state for liquefaction evaluation based on field performance data. As an example to illustrate the new approach, a database that consists of, among many other features, in situ shear wave velocity measurements and field observations of liquefaction/non‐liquefaction in historic earthquakes is analysed. This database is first used to train a neural network to classify liquefaction/non‐liquefaction based on soil resistance parameters and load parameters. The successfully trained and tested neural network is then used to establish a limit state, a multiple dimension boundary that separates ‘zone’ of liquefaction from ‘zone’ of non‐liquefaction. The limit state yields cyclic resistance ratio for a given set of soil resistance parameters. Examination of all cases in the database show that the developed limit state has a high degree of accuracy in predicting the occurrence of liquefaction/non‐liquefaction. The developed neural network model can accurately predict the cyclic resistance ratio of soils. Copyright © 2000 John Wiley & Sons, Ltd.     

Indications of an extreme event deposits along the west coast of India: evidences from GPR investigations

The ground-penetrating radar (GPR) was used to trace the subsurface details in the Palshet coastal zone (Maharashtra) as it exhibits an interesting array of geomorphological features. Furthermore, our main goal was to identify and locate features that might have formed during a reported extreme event and its effects on the flow of the nearby Sundri River. Two profiles (8 and 4 m depth) were collected across the beach and along the backshore, respectively. While the 8-m depth profile (west to east; across the beach) indicates a series of coastline regression in this area, the 4-m depth profile along the coastline (north to south) in the backshore zone reveals two significant incidents viz., (1) stages of development of the paleo-channels that indicate the migration of the Sundri River towards south and (2) huge sediment deposits up to 2.5-m thick in the backshore area. The erosional relict surface (~2.5 m depth) was traced along with various spells of sediments that perhaps occurred due to an extreme event. Sand samples were collected from two trial pits along the GPR profiles to understand the sedimentology and mineralogy in the backshore area. These data together with beach profiles and geomorphological maps suggest that the sands were deposited by an extreme event perhaps during the 1854 cyclonic storm. The sands were trapped in suitable geomorphological sites along the Palshet coast and these sand deposits of about 2.5 m thickness forced the River Sundri to shift its course towards the south. This new revelation facilitates a further study that could focus on the nearby coastal areas to document such extreme event deposits and their influence on the geomorphic set-up.     

Nitrogen and carbon isotopic composition of bone collagen from marine and terrestrial animals

The stable nitrogen and carbon isotope ratios of bone collagen prepared from more than 100 animals representing 66 species of birds, fish, and mammals are presented. The δ¹⁵N values of bone collagen from animals that fed exclusively in the marine environment are, on average, 9%. more positive than those from animals that fed exclusively in the terrestrial environment; ranges for the two groups overlap by less than 1%. Bone collagen δ¹⁵N values also serve to separate marine fish from the small number of freshwater fish we analyzed. The bone collagen δ¹⁵N values of birds and fish that spent part of their life cycles feeding in the marine environment and part in the freshwater environment are intermediate between those of animals that fed exclusively in one or the other system. Further, animals that fed at successive trophic levels in the marine and terrestrial environment are separated, on average, by a 3%. difference in the δ¹⁵N values of their bone collagen. Specifically, carnivorous and herbivorous terrestrial animals have mean δ¹⁵N values for bone collagen of + 8.0 and + 5.3%., respectively. Among marine animals, those that fed on fish have a mean δ¹⁵N value for bone collagen of + 16.5%., whereas those that fed on invertebrates have a mean δ¹⁵N value of + 13.3%. These results support previous suggestions of a 3%. enrichment in δ¹⁵N values at each successively higher trophic level. In contrast to the results for δ¹⁵N values, the ranges of bone collagen δ¹³C values from marine and terrestrial feeders overlap to a great extent. Additionally, bone collagen δ¹³C values do not reflect the trophic levels at which the animals fed. These results indicate that bone collagen δ¹⁵N values will be useful in determining relative dependence on marine and terrestrial food sources and in investigating trophic level relationships among different animal species within an ecosystem. This approach should be applicable to animals represented by prehistoric or fossilized bone in which collagen is preserved.     

A numerical investigation of the thermal state of the earth's mantle

An idealized convecting mantle with internal heat generation and viscosity dependent on temperature and pressure is examined with numerical calculations. Temperature and viscosity are coupled and self-regulating in the quasi-steady solutions. The lack of any tendency for upwelling flow to constrict itself to narrow channels argues against the existence of plumes. Unsteadiness is an essential feature of mantle convection, not only for mixing at large Rayleigh numbers, but also to prevent the flow from being impeded by continuous rigid regions.     

Updated Expressions for Determining Temperatures and Emission Measures from Goes Soft X-Ray Measurements

{We investigate the conversion of the 0.5–4 and 1–8 Å soft X-ray flux measurements made by detectors on the Geostationary Operational Environmental Satellites (GOES) into temperature and emission measures of coronal plasma using modern spectral models and modern understanding of coronal abundances. In particular, the original analysis by Thomas, Starr and Crannell (1985) is updated to take into account the realization that coronal abundances may be quite different from photospheric abundances. An important result of this analysis is that the derived temperatures and emission measures depend strongly on the assumed abundances even at high temperatures where continuum rather than spectral lines dominates the Sun’s X-ray spectrum. This occurs because the higher coronal abundances mean that most of the continuum is due to free–bound emission processes, not free–free emission, and thus is abundance-dependent. We find significant differences between modern calculations of the temperature response of the flux measurements and the versions currently in use: for a typical flare, emission measures may be up to a factor of 4 smaller than the current software suggests. Derived temperatures are similar for both photospheric and coronal abundances for cool flares (e.g., 15 MK), but for hot flares (e.g., 35 MK) coronal abundances can lead to significantly (~25%) lower temperatures being derived.     

Evidence of Kinetic Alfvén Waves in the Solar Wind at 1 AU

Several independent lines of observational evidence of the existence of kinetic Alfvén waves (KAWs) in the solar wind are briefly reviewed. Each piece of evidence is inconclusive when considered separately, but when taken together, it is reasonable to conclude from these observations that KAWs in the form of kinetic Alfvén turbulence are almost always present in the free-flowing solar wind near 1 AU and, by inference, perhaps throughout much of the heliosphere.