Defect distribution and dissolution morphologies on low-index surfaces of α-quartz

The dissolution of prismatic and rhombohedral quartz surfaces by KOH/H₂O solutions was investigated by atomic force microscopy. Rates of dissolution of different classes of surface features (e.g., steps, voids, and dislocation etch pits) were measured. The prismatic surface etched almost two orders of magnitude faster than the rhombohedral surface, mostly due to the difference in the number and the rate of dissolution of extended defects, such as dislocations. Because of the presence of imperfect twin boundaries, defect densities on the prismatic surface were estimated at 50-100 μm⁻², whereas the rhombohedral surface possessed only ∼0.5-1.0 μm⁻², mostly in the form of crystal voids. Crystal voids etched almost one order of magnitude faster on the prismatic surface than on the rhombohedral surface due to differences in the number and the density of steps formed by voids on the different surfaces. In the absence of extended defects, both surfaces underwent step-wise dissolution at similar rates. Average rates of step retreat were comparable on both surfaces (∼3-5 nm/h on the prismatic surface and ∼5-10 nm/h on the rhombohedral surface). Prolonged dissolution left the prismatic surface reshaped to a hill-and-valley morphology, whereas the rhombohedral surface dissolved to form coalescing arrays of oval-shaped etch pits.     

Large-scale Vertical Momentum,Kinetic Energy and Moisture Fluxes in the Antarctic Sea-ice Region

There are very strong thermal gradients between the Antarctic continent and the sea-ice zone, and between that zone and the ocean to the north. As a result of these contrasts the sea-ice domain is one of strong cyclogenesis and high cyclone frequency. In this study we explore many aspects of that cyclonic behaviour and investigate the manner in which these systems influence, and are influenced by, the sea ice. Using the NCEP-DOE re-analyses (1979–2002) we have determined variables that are proportional to the mean of the wind stress and the mean rate at which mechanical energy is imparted to the surface. Using two decompositions of the wind field we have obtained estimates of how much of these fluxes are contributed to by the transient eddies. We find these to be significant over the sea ice and the ocean to the north, particularly when a new decomposition is used. The presence of frequent and vigorous cyclones is a central factor that determines the positive mean freshwater flux over the sea-ice zone in all seasons. This transfer to the ocean is smallest in summer (0.49 mm day⁻¹) and assumes a maximum of 1.27 mm day⁻¹ in winter.     

The Near Infrared Spectrum of Miranda: Evidence of Crystalline Water Ice

A spectrum from 1.2 to 2.5 μm of Uranus' small satellite Miranda obtained in June 1999 reveals strong water-ice signatures. It confirms the existence of a 2.0-μm water feature previously detected on Miranda and shows a strong second broad 1.5-μm water-ice absorption feature. The spectra also reveal a weak absorption band at 1.65 μm that is indicative of crystalline water ice. Reflectance models which combine the new spectra with new photometry indicate that the spectra are characteristic of a mostly water-ice surface, with a large fraction of carbonaceous or silicate contaminates, and the possible presence of ammonia hydrate, as implied by an apparent weak feature near 2.2 μm. The possible presence of other volatiles is also investigated.     

Oxyanion Concentrations in Eastern Sierra Nevada Rivers – 3. Boron, Molybdenum, Vanadium, and Tungsten

Water samples were collected from 10 locations along the Truckee River system, 14 locations along the Walker River system, and 12 locations along the Carson River, and analyzed for B, Mo, V, W, Na, Cl, and pH. Boron concentrations ranged from approximately 2 mol/kg in the upper reaches of the Truckee River to almost 1,200 mol/kg in Pyramid Lake. Molybdenum, V, and W had concentrations in the nanomolal range; Mo varied from a low of about 12 nmol/kg to a high of 3,200 nmol/kg (Walker Lake); V ranged from 9 nmol/kg to approximately 470 nmol/kg; and W varied from a low value around 0.8 nmol/kg (West Walker River) to 1,030 nmol/kg. The high concentrations of these oxyanion-forming trace elements in the rivers reflects (1) the relative stability of these oxyanions (e.g., MoO₄ ^2-, HVO₄ ^2-, WO₄ ^2-, B(OH)₃, and/or B(OH)₄ ^-) in the alkaline, well oxygenated river and lake waters, (2) contributions of hydrothermal waters (especially for B), and (3) weathering of rocks/regolith with high concentrations of these elements. In the case of Mo, V, and W, each exhibited relatively conservative behavior in the upper, oxygenated reaches of all three rivers. During the study period the region experienced a prolonged drought such that the lower reaches of each river were typified by no flow or stagnant waters and probably low oxygen and/or anoxic conditions (although not measured). Reductive processes occurring in the low flow to stagnant reaches of each river could have led to removal of Mo, V, and W from solution as coprecipitates with Fe monosulfides, or via sorption to Fe oxides/oxyhydroxides and/or organic matter. Boron, however, exhibited essentially no or minor removal from these rivers, and instead was added to each river via B-rich hydrothermal waters (e.g., Steamboat Creek from Steamboat Hot Springs), or by B-rich groundwaters via base-flow during the extensive drought.     

Major ion geochemistry of groundwaters from southern Nevada and eastern California, USA

The dissolved ionic constitutents of groundwaters are,in part,a recored of the minerals and rocks in aquifers through which the water has flowed.The chemical composition and association of these major ions in groundwaters have been used to trace groundwater flow paths and sources,In general,the chemical compostion of water in carbonate-rock aquifers in dominated by calcium,magnesium,and bicarbonate,whereas sodium,chloride,and sulfate can be dominant ions in the water that comes from volcanic aquifers or clay minerals.Since the 1990‘s,we have dealt with the geochemistry of groundwaters from more than 100 springs and wells in southern Nevada and eastrn california ,USA for major solutes and trace elements.This paper compiles the hydrochemical data of major ions of these groundwaters.Based on major ion geochemistry,groundwaters from southern Nevada and eastern California can be classified as carbonate aquifer water,volcanic aquifer water,and mixing water (either mixing of cabonate and volcanic aquifer waters or mixing with local recharges),Piper and stiff diagrams of major ions have graphically shown the general chemical characteristics,classification,and mixing relationships of groundwaters from southern Nevada and eastern California.     

TRAVEL TO WORK AND LABOR FORCE PARTICIPATION OF MEN AND WOMEN IN AN AUSTRALIAN METROPOLITAN AREA

For a number of social and cultural reasons, labor force participation rates of Australian women are low. One reason not previously investigated is the problem of geographic accessibility to employment, especially for suburban women. Results from journey-to-work studies show that females either work locally or in the central-city area, whereas males travel to more dispersed locations. Further investigation of female travel patterns from each of fifty-five suburban local government areas shows that the socioeconomic status of an area, together with its job mix, explains much variety in female work travel and suggests that workforce participation rates depend in part on local job availability. The research contributes to an understanding of the nature of occupational and geographical disaggregation of the Melbourne metropolitan labor market.     

Fifty-eight years and counting of watershed science at the Caspar Creek Experimental Watersheds in northern California

The Caspar Creek Experimental Watersheds are the site of a long-term paired watershed study in the northern Coast Ranges of California. The watersheds are predominately forested with coast redwood and Douglas-fir. Old-growth forest was logged between 1860 and 1904. Two harvesting experiments have been completed since then and a third experiment is currently underway. Caspar Creek data are split into three phases corresponding to three experiments: Phase 1 (1962–1985) reports on a selection harvest (1971–1973) and initial recovery in the South Fork watershed; Phase 2 (1985–2017) includes clearcut harvesting of ~50% of the North Fork watershed (1985–1992) and recovery; and Phase 3 (2017 onward) corresponds to a second selection harvest in the South Fork watershed with a range of subwatershed harvest intensities (2017–2019) and recovery. All three experiments included harvest-related road-building and relied primarily on measurements of streamflow and sediment delivery from both treated and reference watersheds. Major findings include modest increases in post-harvest peak flows and cumulative flow volumes, post-harvest low flows that initially increased and then decreased 12 to 15 years after harvesting, and the consequences of different yarding techniques and road design on sediment yields. Some of the data for Phase 1 and Phase 2 are available in a USDA Forest Service online archive. The archived data include precipitation, streamflow, suspended sediment concentrations, turbidity, accumulated weir pond sediment volumes, bedload transport rates, water stable isotope data, and geospatial data. Archiving activities are ongoing. Phase 3 data are currently being collected and will be archived after a post-harvest monitoring period.     

Young runoff fractions control streamwater age and solute concentration dynamics

We introduce a new representation of coupled solute and water age dynamics at the catchment scale, which shows how the contributions of young runoff waters can be directly referenced to observed water quality patterns. The methodology stems from recent trends in hydrologic transport that acknowledge the dynamic nature of streamflow age and explores the use of water age fractions as an alternative to the mean age. The approach uses a travel time‐based transport model to compute the fractions of streamflow that are younger than some thresholds (e.g., younger than a few weeks) and compares them to observed solute concentration patterns. The method is here validated with data from the Hubbard Brook Experimental Forest during spring 2008, where we show that the presence of water younger than roughly 2 weeks, tracked using a hydrologic transport model and deuterium measurements, mimics the variation in dissolved silicon concentrations. Our approach suggests that an age–discharge relationship can be coupled to classic concentration–discharge relationship, to identify the links between transport timescales and solute concentration. Our results highlight that the younger streamflow components can be crucial for determining water quality variations and for characterizing the dominant hydrologic transport dynamics.