The structure and sequence of geological events in the Basement Complex of the Ibadan area,Western Nigeria

The Basement Complex in Western Nigeria in general, and in the Ibadan area in particular, is composed primarily of a banded gneiss in which hornblende-biotite rich bands alternate with quartz-oligoclase rich bands. The banded gneiss, which originated as part of a sedimentary sequence, contains large lenses of granite gneiss and thin intercolated layers of quartzite and amphibolite.Two distinct major structural events can be clearly identified in the early geological history of the Ibadan area. Detailed field studies suggest that the formation of the Ibadan Granite Gneiss, which had yielded an Eburnean Rb-Sr isochron age, was associated with the later of these events. Five phases of dyke or vein formation, two of which pre-date the formation of the Granite Gneiss, have also been identified giving an overall sequence of geological events the first of which may correspond to the beginning of the Liberian orogeny, around 3000 m.y. ago, and the last of which reflects the waning of the Pan-African thermo-tectonic event about 500 m.y. ago.     

Granite diapirism in the Rum Jungle area,Northern Australia

Early studies in the Rum Jungle area suggested an intrusive relationship between the Rum Jungle and Waterhouse “Granites”, and the overlying sediments. It was later shown that the granitic “intrusions” were Archaean basement complexes onto which Lower Proterozoic sediments had been deposited. Polyphase folding was postulated as being responsible for doming of the basement and cover rocks.This paper proposes to show that the domed structures in the Rum Jungle area, and the emplacement of Middle Proterozoic granites in the Pine Creek Geosyncline were related, and caused by diapiric intrusion of granites, in a solid state, into basement complexes and cover rocks.Structural and metamorphic evidence in support of diapiric intrusion in the Rum Jungle area includes: pebble deformation within steeply dipping beds of quartz conglomerate; disappearance of polyphase fold structures away from the basement complexes; bending of folded country-rock strata into concordance with the complex—sediment contact; and metamorphic and metasomatic alteration of sediments in contact with the basement complexes. Gravity data show mass deficiencies in the Archaean complexes which possibly coincide with young granite diapirs.     

A derivation of the equations for transport of liquid and heat in three dimensions in a fractured porous medium

Governing equations can be derived for transient, three-dimensional transport of heat and mass in compressible, liquid saturated fractured porous media. Recently developed mathematical techniques can be used which relate local space averages of derivatives of medium properties to the derivatives of those averages. Using these techniques, well established thermomechanical transport equations which apply at microscopic points may be transformed into equations in macroscopic variables; i.e. in variables which pertain to the scale of observation. In the absence of chemical reactions, transfer between source entities and the medium may be taken care of in a consistent, physically realistic way, such that macroscopic source terms arise naturally in the course of the macroscopization procedures.     

Sorted stripes orientated by wind action: Some observations from sub-antarctic marion island

Sorted stripes found on the volcanic scoria and glacial deposits of sub-Antarctic Marion Island indicate a distinct preferred orientation. Despite uniformity of slope and material, the stripes are predominantly aligned parallel to the wind. It is suggested that melting of needle ice by the early morning sun is of only limited importance in the sub-Antarctic owing to the almost continual overcast conditions. The effect of the wind is so great that in exposed situations stripes are formed on horizontal surfaces.     

An analytic stress model applied to the Snake River Plain (Northern Basin and Range province U.S.A.)

The complex representation of plane stress is used for an analytic model to describe the stress regime of the Snake River Plain (SRP) region of the western United States. The area is modeled as an infinite elastic sheet cut along a circular arc with tension applied at infinity. Modeling results include the following: (1) south of the Snake River Plain, the principal direction of tension rotates from the direction of the applied stress to a direction sub-parallel to the cut, consistent with the orientation of normal faulting and nodal planes given by fault plane solutions; (2) north of the Snake River Plain, calculated stress directions are consistent with the variable nature of faulting in that region; (3) a decrease in magnitude of predicted stresses is observed within the Snake River Plain consistent with relatively low levels of seismicity on the Plain.     

A thought on heat flow and tidal drag as possible driving forces of plate tectonics

The amount of useful work that can be extracted from the Earth's heat flow is examined from a thermodynamic standpoint.     

Radium and thorium isotopes in the surface waters of the East Pacific and coastal Southern California

A fiber extraction technique is used to concentrate Ra and Th isotopes from 1000 liters or more of seawater. Natural²²⁶Ra and²³⁴Th are used as yield tracers. In the equatorial Pacific the²²⁸Ra activity of surface water varies from 20 to 1 dpm/1000 kg and generally decreases away from continental shelf areas. Across the Peru Current System, this decrease is modeled as one-dimensional diffusion and indicates the possibility of two flow regimes with distinct characteristic mixing lengths and apparent eddy diffusivities of 10⁵ and 10⁷ cm²/s. The perturbing effects of advection and equatorial upwelling west of the Galapagos Islands are noted. Off the coast of Southern California a vertical²²⁸Ra distribution gives an apparent diffusivity of 1.6 cm²/s for the upper thermocline.²²⁶Ra concentrations near the coast appear to be higher than the open ocean values at comparable depths, which may reflect supply of this isotope from continental shelf sediments and/or upwelling. The insoluble daughter/soluble parent activity ratios²²⁸Th/²²⁸Ra and²³⁴Th/²³⁸U in the equatorial Pacific surface water display latitudinal trends which may be correlated with productivity variations. Near the coast of California these ratios reflect the differing oceanographic conditions north and south of Pt. Conception indicating a mean chemical removal time constant on the order of 4 months for Th and other highly reactive elements within the Southern California Bight. The²³²Th content of seawater sampled is less than 0.1 μg/1000 1; most of the published values for seawater²³²Th could well be too high. A comparison of the two methods of determining²²⁸Ra (via²²⁸Ac and via²²⁸Th) made on 64 seawater samples shows that the time delay required by the²²⁸Th method is more than compensated by its better analytical simplicity and precision.     

The abundance of cadmium and zinc in meteorites

A stable isotope dilution technique using solid source mass spectrometry has been used to accurately determine Cd and Zn in a wide range of materials. The abundance of Cd has been determined in 19 iron, 28 stone and 1 stony-iron meteorites, together with a number of other samples. The abundance of Zn has also been determined for most of these samples. This has enabled the relationship between Cd and Zn to be examined in iron and stone meteorites. The abundance pattern of Zn in iron meteorites supports the existence of chemical groups.     

The occurrence of selected human pharmaceutical compounds in UK estuaries

This report describes a scoping study conducted in order to establish whether pharmaceutical compounds may be present in UK estuaries. Surface water samples collected from five UK estuaries were analysed for the presence of 14 pharmaceutical compounds selected from the priority lists of the UK Environment Agency and the Oslo and Paris Commission (OSPAR). The pharmaceutical compounds/metabolites clofibric acid, clotrimazole, dextropropoxyphene, diclofenac, ibuprofen, mefenamic acid, propranolol, tamoxifen and trimethoprim were detected at measurable concentrations in the samples collected. The concentrations of erythromycin, lofepramine, paracetamol, sulfamethoxazole and acetyl-sulfamethoxazole were all below the limits of detection of the methods used (between 4 and 20 ng l(-1)). The anti-fungal agent clotrimazole was the most frequently detected at a maximal concentration of 22 ng l(-1) and a median concentration of 7 ng l(-1). The analgesic compound ibuprofen was detected at a maximal concentration of approximately 930 ng l(-1) and a median concentration of 48 ng l(-1), whilst the other pharmaceutical compounds were detected between the limits of detection of the method used and 570 ng l(-1).