The behaviour of a Cu(II) ion selective electrode in seawater; copper consumption capacity and copper determinations

Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater.     

Sedimentogenesis in the White Sea: Vertical Fluxes of Suspended Particulate Matter and Absolute Masses of Bottom Sediments

Oceanology - A new approach has been applied to studying marine sedimentation using dispersed sedimentary material in sediment traps compared to the surface layer of bottom sediments. Based on...     

Antarctic Bottom Water Flow through the Eastern Part of the Philip Passage in the Weddell Sea

Oceanology - Measurements of currents and Antarctic Bottom Water properties overflowing the sill from the Weddell to the Scotia Sea are described. The bottom water overflows the sill of one of the...     

Mesoscale Variability of the Ocean in the Northern Part of the Weddell Sea

Oceanology - Results of a mesoscale survey in the Powell Basin in the northern part of the Weddell Sea are analyzed. The survey included 24 CTD casts (6 × 4) with an interval of six nautical...     

Automatic Profiling System for Underice Measurements

The article is devoted to the development of an autonomous profiling system for measuring the aquatic environment under ice. The system moves up and down in the water column along a cable with a load at the lower end, which is lowered into a lane in the ice. The system carrier is designed for transporting an acoustic Doppler current profiler and a salinity, temperature, and pressure probe. The system will be useful for long-term measurements of vertical profiles of the current speed and marine environment parameters, as well as ice draft. The article describes in detail the structure and operation of the system. The hydraulic scheme of the carrier buoyancy system is presented.

     

Coupled Earth’s Thermosohere-Ionosphere Global Dynamics Model

Izvestiya, Atmospheric and Oceanic Physics - A coupled Earth’s thermosohere-ionosphere global dynamics model (for altitudes of 90–500 km) is presented. This model is based on a...     

Algorithm for the Atmospheric Correction of Shortwave Channels of the MSU-MR Radiometer of the Meteor-M No. 2 Satellite

Izvestiya, Atmospheric and Oceanic Physics - The problem of atmospheric correction for shortwave channels of a multispectral low-resolution scanning radiometer onboard the Meteor-M No. 2 satellite...     

Incorporating Māori values into land management decision tools

ABSTRACT

Environmental sustainability and the long-term wellbeing of Māori (the indigenous people of New Zealand) are interdependent and degradation of landscapes risks the progressive degradation of Māori wellbeing. The present study developed an analysis framework based on Ki Uta Ki Tai (holistic-mountains to the sea- management philosophy advocated by Ngāi Tahu) for exploring relationships between landcover and Māori values to enable predictions of cultural values through space and time. We used this framework to predict how two Māori values (Overall Health and Cultural Land Use) have been altered as a result of landcover change between 2001–2012 in three Canterbury catchments. The area of native vegetation declined while exotic pasture increased between 2001–2012, and there were corresponding declines in both cultural health scores. These results suggest that the change in landcover has reduced the ability of the landscape to support Māori values. This framework for assessing changes in Māori values with respect to changing environmental conditions may identify opportunities for Māori to better engage in land use management decisions.