Chemistry of the heavily urbanized Bagmati River system in Kathmandu Valley, Nepal: export of organic matter, nutrients, major ions, silica, and metals

Water quality in less-developed countries is often subject to substantial degradation, but is rarely studied in a systematic way. The concentration and flux of major ions, carbon, nitrogen, silicon, and trace metals in the heavily urbanized Bagmati River within Kathmandu Valley, Nepal, are reported. The concentrations of all chemical species increased with distance downstream with the exceptions of protons and nitrate, and showed strong relationships with population density adjacent to the river. Total dissolved nitrogen (TDN), dominated by NH₄, was found in high concentrations along the Bagmati drainage system. The export of dissolved organic carbon (DOC) and TDN were 23 and 33 tons km^?2 year^?1, respectively, at the outlet point of the Kathmandu Valley, much higher than in relatively undeveloped watersheds. The cationic and silica fluxes were 106 and 18 tons km^?2 year^?1 at the outlet of the Bagmati within Kathmandu Valley, and 36 and 32 tons km^?2 year^?1 from the relatively pristine headwater area. The difference between headwaters and the urban site suggests that the apparent weathering flux is three times higher than the actual weathering rate in the heavily urbanized Bagmati basin. Fluxes of cations and silica are above the world average, as well as fluxes from densely populated North American and European watersheds. End-member composition of anthropogenic sources like sewage or agricultural runoff is needed to understand the drivers of this high rate of apparent weathering.     

Observations on the crystal structures of lueshite

Laboratory powder XRD patterns of the perovskite-group mineral lueshite from the type locality (Lueshe, Kivu, DRC) and pure NaNbO₃ demonstrate that lueshite does not adopt the same space group (Pbma; #57) as the synthetic compound. The crystal structures of lueshite (2 samples) from Lueshe, Mont Saint-Hilaire (Quebec, Canada) and Sallanlatvi (Kola, Russia) have been determined by single-crystal CCD X-ray diffraction. These room temperature X-ray data for all single-crystal samples can be satisfactorily refined in the orthorhombic space group Pbnm (#62). Cell dimensions, atomic coordinates of the atoms, bond lengths and octahedron tilt angles are given for four crystals. Conventional neutron diffraction patterns for Lueshe lueshite recorded over the temperature range 11–1,000 K confirm that lueshite does not adopt space group Pbma within these temperatures. Neutron diffraction indicates no phase changes on cooling from room temperature to 11 K. None of these neutron diffraction data give satisfactorily refinements but suggest that this is the space group Pbnm. Time-of-flight neutron diffraction patterns for Lueshe lueshite recorded from room temperature to 700 °C demonstrate phase transitions above 550 °C from Cmcm through P4/mbm to \(Pm\overline{3} m\) above 650 °C. Cell dimensions and atomic coordinates of the atoms are given for the three high-temperature phases. The room temperature to 400 °C structures cannot be satisfactorily resolved, and it is suggested that the lueshite at room temperature consists of domains of pinned metastable phases with orthorhombic and/or monoclinic structures. However, the sequence of high-temperature phase transitions observed is similar to those determined for synthetic NaTaO₃, suggesting that the equilibrated room temperature structure of lueshite is orthorhombic Pbnm.     

Exploring Mobility Indoors: an Application of Sensor‐based and GIS Systems

The popularization of tracking devices, such as GPS, accelerometers and smartphones, have made it possible to detect, record, and analyze new patterns of human movement and behavior. However, employing GPS alone for indoor localization is not always possible due to the system's inability to determine location inside buildings or in places of signal occlusion. In this context, the application of local wireless networks for determining position is a promising alternative solution, although they still suffer from a number of limitations due to energy and IT‐resources. Our research outlines the potential for employing indoor wireless network positioning and sensor‐based systems to improve the collection of tracking data indoors. By applying various methods of GIScience we developed a methodology that can be applicable for diverse human indoor mobility analysis. To show the advantage of the proposed method, we present the result of an experiment that included mobility analysis of 37 participants. We tracked their movements on a university campus over the course of 41 days and demonstrated that their movement behavior can be successfully studied with our proposed method.     

The Pleistocene evolution of the East Antarctic Ice Sheet in the Prydz bay region: stable isotopic evidence from ODP Site 1167

Ocean Drilling Program Leg 188, Prydz Bay, East Antarctica is part of a larger initiative to explore the Cenozoic history of the Antarctic Ice Sheet through direct drilling and sampling of the continental margins. In this paper, we present stable isotopic results from Ocean Drilling Program (ODP) Site 1167 located on the Prydz Channel Trough Mouth Fan (TMF), the first Antarctic TMF to be drilled. The foraminifer-based δ¹⁸O record is interpreted along with sedimentary and downhole logging evidence to reconstruct the Quaternary glacial history of Prydz Bay and the adjacent Lambert Glacier Amery Ice Shelf System (LGAISS). We report an electron spin resonance age date of 36.9±3.3 ka at 0.45 m below sea floor and correlate suspected glacial–interglacial cycles with the global isotopic stratigraphy to improve the chronology for Site 1167. The δ¹⁸O record based on planktonic (Neogloboquadrina pachyderma (s.)) and limited benthic results (Globocassidulina crassa), indicates a trend of ice sheet expansion that was interrupted by a period of reduced ice volume and possibly warmer conditions during the early–mid-Pleistocene (0.9–1.38 Ma). An increase in δ¹⁸O values after 900 ka appears to coincide with the mid-Pleistocene climate transition and the expansion of the northern hemisphere ice sheet. The δ¹⁸O record in the upper 50 m of the stratigraphic section indicates as few as three glacial–interglacial cycles, tentatively assigned as marine isotopic stages (MIS) 16–21, are preserved since the Brunhes/Matuyama paleomagnetic reversal (780 ka). This suggests that there is a large unconformity near the top of the section and/or that there may have been few extreme advances of the ice sheet since the mid-Pleistocene climate transition resulting in lowered sedimentation rates on the Prydz Channel TMF. The stable isotopic record from Site 1167 is one of the few available from the area south of the Antarctic Polar Front that has been linked with the global isotopic stratigraphy. Our results suggest the potential for the recovery of useful stable isotopic records in other TMFs.     

Observations of the evolution of the aerosol, cloud and boundary‐layer characteristics during the 1st ACE‐2 Lagrangian experiment

During the 1st Lagrangian experiment of the North Atlantic Regional Aerosol Characterisation Experiment (ACE‐2), a parcel of air was tagged by releasing a smart, constant level balloon into it from the Research Vessel Vodyanitskiy . The Meteorological Research Flight's C‐130 aircraft then followed this parcel over a period of 30 h characterising the marine boundary layer (MBL), the cloud and the physical and chemical aerosol evolution. The air mass had originated over the northern North Atlantic and thus was clean and had low aerosol concentrations. At the beginning of the experiment the MBL was over 1500 m deep and made up of a surface mixed layer (SML) underlying a layer containing cloud beneath a subsidence inversion. Subsidence in the free troposphere caused the depth of the MBL to almost halve during the experiment and, after 26 h, the MBL became well mixed throughout its whole depth. Salt particle mass in the MBL increased as the surface wind speed increased from 8 m s⁻¹ to 16 m s⁻¹ and the accumulation mode (0.1μm to 3.0 μm) aerosol concentrations quadrupled from 50 cm⁻³ to 200 cm⁻³. However, at the same time the total condensation nuclei (>3 nm) decreased from over 1000 cm⁻³ to 750 cm⁻³. The changes in the accumulation mode aerosol concentrations had a significant effect on the observed cloud microphysics. Observational evidence suggests that the important processes in controlling the Aitken mode concentration which, dominated the total CN concentration, included, scavenging of interstitial aerosol by cloud droplets, enhanced coagulation of Aitken mode aerosol and accumulation mode aerosol due to the increased sea salt aerosol surface area, and dilution of the MBL by free tropospheric air.     

Neoproterozoic (Cryogenian) stromatolites from the Wolfe Basin,east Kimberley,Western Australia: Correlation with the Centralian Superbasin

Linella avis, an early to middle Neoproterozoic (Tonian to Cryogenian) stromatolite, occurs in the Eliot Range Dolomite, part of the Ruby Plains Group in the Wolfe Basin, east Kimberley. Previously, this dolomite was assigned to the Mesoproterozoic Bungle Bungle Dolomite in the Osmond Basin, which contains a different suite of stromatolites. Linella avis, which also occurs in the Neoproterozoic Bitter Springs Formation of the Amadeus Basin, central Australia, appears to be restricted to rocks aged around 850 to 800 Ma. The presence of L. avis indicates that the Ruby Plains Group is a probable correlative of the Heavitree Quartzite and Bitter Springs Formation, and is probably much younger than the Bungle Bungle Dolomite. If the correlation suggested here is correct, the Wolfe Basin, together with the Amadeus and Ngalia Basins, formed part of the Centralian Superbasin.     

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.     

Effects of carbon dioxide on deep-sea harpacticoids revisited

As part of the evaluation of the environmental impact of sequestering carbon dioxide in the deep ocean, we exposed the sediment-dwelling fauna at a station in Monterey Submarine Canyon (36.378°N, 122.676°W, 3262 m) to carbon dioxide-rich seawater and found that most of the harpacticoid copepods were killed. In an expanded, follow-on experiment on the continental rise nearby (36.709°N, 123.523°W, 3607 m), not only did harpacticoids survive exposure to carbon dioxide-rich seawater, but we found no evidence from seven additional metrics that the harpacticoids had been affected. We infer that during the second experiment the harpacticoids were not exposed to a stressful dose. During the second experiment, carbon dioxide-rich seawater appears to have been produced more slowly than in the first, probably because of differences in the near-bottom flow regimes. We conclude that local physical circumstances can substantially influence the results of experiments of this type and will complicate the evaluation of the environmental consequences of deep-ocean carbon dioxide sequestration.     

Preserving the unpreservable: a lost world rediscovered at Christian Malford, UK

The small village of Christian Malford, Wiltshire (UK) is known to palaeontologists the world over because of the chance discovery of an astonishing fossil bonanza in the mid-nineteenth century. Pits in the Jurassic Oxford Clay yielded thousands of specimens of exquisitely preserved ammonites, fish and crustaceans, but became most famous for squid-like cephalopods and belemnites (collectively termed coleoids) with fossilized soft-parts. The precise location of the find has remained obscure, until now, and a new attempt is underway to understand the ancient environment that triggered this unusual preservation.