Temporal and spatial biomonitoring of heavy metals in eastern Aegean coastal waters using Amphibalanus amphitrite

This biomonitoring study presents the spatial and temporal distributions of heavy metals in the soft tissues of a major fouling species Amphibalanus amphitrite living on hard substrate at different sites along the eastern Aegean coast. A. amphitrite has been chosen as a strong candidate for monitoring heavy metals. Sediment and seawater samples were also collected to detect their metal contents in order to gain more information on the environmental conditions and possible bioaccumulation patterns. The physico-chemical characteristics of sampling stations have been measured in order to characterize the sampling area. The order of metal concentrations in barnacles, sediment and seawater decreased in the following order Cu > Fe > Zn > Mn > Cd > Cr > Pb > Hg, Fe > Mn > Zn > Cu > Pb > Cr > Hg > Cd and Fe > Zn > Mn > Cu > Pb > Cr > Cd > Hg, respectively. These results showed that barnacles accumulate Cu in a higher degree than both sediment and seawater. Moreover, metal concentrations in barnacle have the potential for use in any future regulatory framework monitoring and eventually controlling ambient metal pollution levels.     

Development of Predictive Models for the Specific Energy of Circular Diamond Sawblades in the Sawing of Granitic Rocks

This paper presents an experimental study on the sawing of granitic rocks by circular diamond sawblades. The influence of the operating variables and rock properties on the specific energy were initially investigated and analyzed. To determine the most significant operating variables and rock properties influencing the specific energy, statistical analyses were then employed and the models were built for the estimation of specific energy depending on the operating variables and the rock properties. Moreover, the derived models were validated through statistical tests such as the determination coefficient, t-test, F-test, and residuals. The results indicated that the specific energy decreased with the decreasing of peripheral speed and the increasing of traverse speed, cutting depth, and flow rate of cooling fluid, respectively. It was concluded that, rather than the physico-mechanical properties, the mineralogical properties were the dominant rock properties affecting the specific energy. Additionally, the peripheral speed was statistically determined as the most significant operating variable affecting the specific energy. The peripheral speed was followed by the cutting depth, traverse speed, and flow rate of cooling fluid with respect to their level of significance on the specific energy. Furthermore, the model results revealed that the developed models have high potentials as a guidance for practical applications.     

Constructing a 3D structural block diagram of the Central Basin in Marmara Sea by means of bathymetric and seismic data

In this study we made a comparative interpretation of multibeam bathymetric and seismic reflection data with different resolutions and penetration properties collected in the Central Basin of the Marmara Sea. Our main objectives were (i) to investigate and compare the active tectonic deformation observed on the sea bottom and within the uppermost sedimentary layers to that of the deep-seated deformation within the limits of resolution and penetration of the available geophysical data and (ii) to build a three-dimensional (3D) block diagram of the active tectonic and buried features by means of a sliced mapping technique. In this approach, we produced slice maps of the active and buried structural features at selected depths and then combined them to form a 3D structural block diagram. Motivation for our work was to produce a 3D structural diagram to derive a more detailed image of the structural features in the Central Basin where there is no available 3D seismic data. The observations from the bathymetry and seismic data and developed 3D diagram support the presence of a through-going strike-slip fault that forms a rotational depression zone against a right-stepping strike-slip faulting causing a pull-apart basin in the Central Depression zone.     

Wear Performance of Saw Blades in Processing of Granitic Rocks and Development of Models for Wear Estimation

This study investigates the wear performance of diamond circular saw blades in cutting of granitic rocks. An alternative wear measuring method is developed to measure the reduced blade radius without taking the blade off the machine. The effect on and contribution to the specific wear rate (SWR) of each operating variable are determined, and the SWR is correlated with rock properties. Morphologies of wearing surfaces of segments and rocks are also evaluated using scanning electron microscopy (SEM). Depending on both operating variables and rock properties, prediction models are developed for estimation of the SWR. Results show that the SWR increases with an increase in the peripheral speed and the traverse speed, while it decreases with an increase in the cutting depth and the flow rate of the cooling fluid. The peripheral speed, and the microhardness and proportions of minerals such as quartz, plagioclase, and feldspar are statistically determined as the significant variables affecting the SWR. Finally, it is disclosed that models developed for estimation of SWR have great potential for practical applications.     

Hybridization of mafic microgranular enclaves: mineral and whole-rock chemistry evidence from the Karamadazı Granitoid, Central Turkey

On the Eastern Tauride Belt, the Cretaceous calc-alkaline Karamadazı Granitoid consists of quartz diorite containing mafic microgranular enclaves (MME) and leucocratic granite. The quartz diorite consists of plagioclase (An_8-65), hornblende, biotite, K-feldspar, quartz, epidote and titanite. Subrounded MME in the quartz diorite are holocrystalline, fine-grained, quartz diorite to diorite in composition, and display a similar mineral assemblage to their host. Large crystals in MME and quartz diorite show various disequilibrium microstructures indicative of hybridization. Plagioclase crystals exhibit inverse, normal, and oscillatory zoning with maximum core-to-rim An content increase up to 38% in the enclave and 40% in the quartz diorite. Both hornblende and augite exhibit normal and reverse zoning even in the same sample. The new field, textural, mineral compositional, and geochemical evidence leads to the conclusion that MME could have formed through injection of successive pulses of basic magma into upward mobile magma chambers containing cooler, partially crystalline quartz diorite magma. The quartz diorites show similarity to high-Al TTG (tonalites–trondhjemites–granodiorites), with their high Na₂O, Sr, LREE, and low Mg#, Cr, HREE contents, and are suggested to be produced by extensive interaction between the crustal and mantle-derived melts through mixing at depth. In contrast, leucogranites have geochemical characteristics distinct from the quartz diorites and MME, and are probably not involved in MME genesis.     

Assessment of organotin (butyltin species) contamination in marine biota from the Eastern Aegean Sea, Turkey

The marine environment continues to be adversely affected by tributyltin (TBT) release from maritime traffic. Therefore the concentrations of TBT, dibutyltin (DBT) and monobutyltin (MBT) were measured in barnacles, mussels and fish along the Eastern Aegean coastline. The average concentrations of TBT ng Sn g⁻¹ were found to be 235 in fish, 116 in mussels and 635 in barnacles. The highest concentrations of TBT, DBT and MBT were observed in the barnacles which had been sampled in marinas and harbors. All mussels sampled showed values of TBT + DBT, which were below the “tolerable average residue level (TARL)” as currently accepted. This indicates a lack of risk to the consumer. However, 7 out of the 15 fish sampled displayed TBT + DBT levels above the TARL, which indicates that a fish consumer group may be at risk. Barnacles have high potential as biomonitors for the presence of organotin in the Aegean Sea.     

The origin of high magnetic remanence in fault pseudotachylites: Theoretical considerations and implication for coseismic electrical currents

Several examples of fault-related pseudotachylites display a significantly higher initial magnetic susceptibility than their granitic host rock (10:1 to 20:1). These higher values are attributed to the presence of fine magnetic particles formed during melt quenching. The hysteresis properties of the particles indicate a single domain (SD) to pseudo single domain (PSD) magnetic grain size. The Curie temperature (Tc) of the magnetic particles is close to 580 °C.The natural remanent magnetization (NRM) of these pseudotachylites is also significantly higher than that of the host rock (up to 300:1). Such anomalously high remanence cannot be explained by a magnetization acquired in the Earth's magnetic field, regardless of pseudotachylite age.Ground lightning and other strong electric pulses can cause anomalously high NRM intensities. A ground lightning explanation seems unlikely to explain the systematically high NRM intensities, particularly in the case of recently exposed samples that have been collected from active quarries. Alternatively, high NRM intensities could be explained by earthquake lightning (EQL), a seismic phenomenon occasionally reported in connection with large magnitude earthquakes (M > 6.0).The coseismic electrical properties of the pseudotachylite vein–host rock system are characterized by (1) a core of molten material (high conductivity), (2) vapor-rich margins of thermally and mechanically fractured host rocks (low conductivity) and (3) moderately fractured to undeformed host rock (normal conductivity). Such a core conductor bordered by insulating margins is potentially responsible for the propagation of EQL pulses.The coseismic thermal history of pseudotachylite veins has been modeled in 2-D using conductive heat transfer equations. It shows that EQL can be recorded only during a brief time interval (less than 1 min) for a given vein thickness and host-rock temperatures. If the vein is too thick or if the host rock is too hot, the pseudotachylite remains above Tc after the electric pulse has lapsed.