重庆市主城区软件和信息技术服务企业空间格局演化与区位选择

基于重庆市工商企业注册数据,利用核密度分析、多距离空间聚类等空间分析方法,分析了重庆市主城区软件和信息技术服务企业2002—2017年的空间格局演化特征,并借助Tobit模型探讨其区位选择影响因素。研究表明：1）从现状分布看,距离城市中心4~12 km的城市中间圈层是重庆市主城区软件和信息技术服务企业分布的主要空间,并呈“双峰”圈层分布特征,空间分布表现为“一主两次”多中心格局,集聚特征显著。2）2002—2017年,企业分布出现郊区化现象的同时大量向距离城市中心6~8 km范围集中,圈层分布由“双峰”结构向“单峰”结构转变,空间格局由单中心分布演变为“一主两次”多中心格局,集聚强度与规模持续提高。3）产业集聚因素对重庆市主城区软件和信息技术服务企业的区位选择影响最为显著,其次是相关区位条件和市内交通因素的影响,对外交通和空间政策因素在企业区位选择中的作用未通过显著性检验。     

弥渡金宝山铂钯矿床超基性岩浆演化与成矿

早期深部硫化物熔离是成矿主导控制因素,岩浆晚期高温流体活动阶段普遍遭受蛇纹石化.金属硫化物的富集部位也就是铂钯矿化部位.金属硫化物是在铁质超基性岩中寻找铂钯矿体的间接标志.     

东海污损生物群落研究Ⅲ.群落结构

计算东海29 个试验点污损生物群落之间的相似系数,并进行聚类分析。根据分析结果,东海污损生物群落可分为4 个类型: 河口群落、近岸群落、内湾群落和远岸群落     

Carbonate metasomatism in the lithospheric mantle: Implications for cratonic destruction in North China

The activity of melts and fluids may have played a key role in inducing the destruction of the eastern North China Craton in the early Cretaceous. Carbonate melts are important agents in mantle metasomatism and can significantly modify the physical and chemical properties of the subcontinental lithospheric mantle. Carbonate metasomatism can be identified by specific geochemical indices in clinopyroxene, such as high Ca/Al and low Ti/Eu ratios. This study presents the spatial and temporal variations of carbonate metasomatism in the lithospheric mantle beneath the eastern North China Craton. Three types of carbonate metasomatism are classified based on the geochemical compositions of clinopyroxene in mantle peridotites. Clinopyroxene formed by Type 1 carbonate metasomatism is characterized by very high Ca/Al ratios(15–70) and~(87)Sr/~(86)Sr ratios(0.706–0.713). Clinopyroxene derived from Type 2 carbonate metasomatism shows relatively high Ca/Al ratios(5–18) and~(87)Sr/~(86)Sr ratios(0.703–0.706). However, clinopyroxene resulting from Type 3 carbonate metasomatism has low Ca/Al ratios(5–9) and~(87)Sr/~(86)Sr ratios(0.702–0.704). Deep(garnet-bearing) and shallow(spinel-bearing) lithospheric mantle beneath the Sulu orogen and surrounding areas in the eastern North China Craton were affected by intense Type 1 carbonate metasomatism before the late Triassic. The deep subduction of the South China Block with its accompanying carbonate sediments was the trigger for Type 1 carbonate metasomatism, which reduced strength of the lithospheric mantle and provided a prerequisite for the destruction of the eastern North China Craton in the early Cretaceous. After the destruction of the eastern North China Craton, the ancient relict lithospheric mantle, represented by spinel harzburgite xenoliths hosted in the late Cretaceous to Cenozoic basalts,only recorded Type 2 carbonate metasomatism. This implies that the lithospheric mantle experienced the intense Type 1 carbonate metasomatism was completely destroyed and not preserved during decratonization. Spinel lherzolite xenoliths hosted in the late Cretaceous to Cenozoic basalts represent the young, fertile lithospheric mantle formed after the cratonic destruction and only a few samples record Type 2 and 3 carbonate metasomatisms. We suggest that carbonate melts derived from the subduction-modified asthenospheric mantle with variable proportions of recycled crustal material was responsible for the Type 2 and 3 carbonate metasomatisms. The carbonate metasomatism of the lithospheric mantle beneath the Jiaodong Peninsula and surrounding areas is very pervasive and is spatially consistent with the remarkable thinning of lithospheric mantle and giant gold deposits in this region. Therefore, we conclude that carbonate metasomatism in the lithospheric mantle played a crucial part in the modification, destruction and gold deposits in the eastern North China Craton.     

Facies-constrained prestack seismic probabilistic inversion driven by rock physics

Seismic Rock physics plays a bridge role between the rock moduli and physical properties of the hydrocarbon reservoirs. Prestack seismic inversion is an important method for the quantitative characterization of elasticity, physical properties, lithology and fluid properties of subsurface reservoirs. In this paper, a high order approximation of rock physics model for clastic rocks is established and one seismic AVO reflection equation characterized by the high order approximation(Jacobian and Hessian matrix) of rock moduli is derived. Besides, the contribution of porosity, shale content and fluid saturation to AVO reflectivity is analyzed. The feasibility of the proposed AVO equation is discussed in the direct estimation of rock physical properties. On the basis of this, one probabilistic AVO inversion based on differential evolution-Markov chain Monte Carlo stochastic model is proposed on the premise that the model parameters obey Gaussian mixture probability prior model. The stochastic model has both the global optimization characteristics of the differential evolution algorithm and the uncertainty analysis ability of Markov chain Monte Carlo model. Through the cross parallel of multiple Markov chains, multiple stochastic solutions of the model parameters can be obtained simultaneously, and the posterior probability density distribution of the model parameters can be simulated effectively. The posterior mean is treated as the optimal solution of the model to be inverted.Besides, the variance and confidence interval are utilized to evaluate the uncertainties of the estimated results, so as to realize the simultaneous estimation of reservoir elasticity, physical properties, discrete lithofacies and dry rock skeleton. The validity of the proposed approach is verified by theoretical tests and one real application case in eastern China.     

A fundamental theorem for eco-environmental surface modelling and its applications

We propose a fundamental theorem for eco-environmental surface modelling(FTEEM) in order to apply it into the fields of ecology and environmental science more easily after the fundamental theorem for Earth's surface system modeling(FTESM). The Beijing-Tianjin-Hebei(BTH) region is taken as a case area to conduct empirical studies of algorithms for spatial upscaling, spatial downscaling, spatial interpolation, data fusion and model-data assimilation, which are based on high accuracy surface modelling(HASM), corresponding with corollaries of FTEEM. The case studies demonstrate how eco-environmental surface modelling is substantially improved when both extrinsic and intrinsic information are used along with an appropriate method of HASM. Compared with classic algorithms, the HASM-based algorithm for spatial upscaling reduced the root-meansquare error of the BTH elevation surface by 9 m. The HASM-based algorithm for spatial downscaling reduced the relative error of future scenarios of annual mean temperature by 16%. The HASM-based algorithm for spatial interpolation reduced the relative error of change trend of annual mean precipitation by 0.2%. The HASM-based algorithm for data fusion reduced the relative error of change trend of annual mean temperature by 70%. The HASM-based algorithm for model-data assimilation reduced the relative error of carbon stocks by 40%. We propose five theoretical challenges and three application problems of HASM that need to be addressed to improve FTEEM.     

Multi-trace basis-pursuit seismic inversion for resolution enhancement

Seismic inversion is an important tool that transfers interface information of seismic data to formation information, which renders the seismic data easily understood by geologists or petroleum engineers. In this study, a novel multi-trace basis-pursuit inversion method based on the Bayesian theory is proposed to enhance the vertical resolution and overcome the lateral instability of inversion results between different traces occasionally seen in the traditional trace-by-trace basis-pursuit inversion method. The Markov process is initially introduced to describe the relationship between adjacent seismic traces and their correlation, which we then close couple in the equation of our new inversion method. A recursive function is further derived to simplify the inversion process by considering the particularity of the coefficient matrix in the multi-trace inversion equation. A series of numerical-analysis and field data examples demonstrates that both the traditional and the new methods for P-wave impedance inversion are helpful in enhancing the resolution of thin beds that are usually difficult to discern from original seismic profiles, thus highlighting the importance of acoustic-impedance inversion for thin bed interpretation. Furthermore, in addition to yielding thin bed inversion results with enhanced lateral continuity and high vertical resolution, our proposed method is robust to noise and cannot be easily contaminated by it, which we verify using both synthetic and field data.     

From 2D to 3D Modeling of Mineral Prospectivity Using Multi-source Geoscience Datasets,Wulong Gold District,China

Natural Resources Research - The Wulong gold district (WGD) is located at the northeastern margin of the North China Carton (NCC) on the Liaodong Peninsula, China. The results of early mineral...     

Bulk organic δC and C/N as indicators for sediment sources in the Pearl River delta and estuary,southern China

Preservation of organic matter in estuarine and coastal areas is an important process in the global carbon cycle. This paper presents bulk δ¹³C and C/N of organic matter from source to sink in the Pearl River catchment, delta and estuary, and discusses the applicability of δ¹³C and C/N as indicators for sources of organic matter in deltaic and estuarine sediments. In addition to the 91 surface sediment samples, other materials collected in this study cover the main sources of organic material to estuarine sediment. These are: terrestrial organic matter (TOM), including plants and soil samples from the catchment; estuarine and marine suspended particulate organic carbon (POC) from both summer and winter. Results show that the average δ¹³C of estuarine surface sediment increases from −25.0 ± 1.3‰ in the freshwater environment to −21.0 ± 0.2‰ in the marine environment, with C/N decreasing from 15.2 ± 3.3 to 6.8 ± 0.2. In the source areas, C₃ plants have lower δ¹³C than C₄ plants (−29.0 ± 1.8‰ and −13.1 ± 0.5‰ respectively). δ¹³C increases from −28.3 ± 0.8‰ in the forest soil to around −24.1‰ in both riverbank soil and mangrove soil due to increasing proportion of C₄ grasses. The δ¹³C_POC increases from −27.6 ± 0.8‰ in the freshwater areas to −22.4 ± 0.5‰ in the marine-brackish-water areas in winter, and ranges between −24.0‰ in freshwater areas and −25.4‰ in brackish-water areas in summer. Comparison of the δ¹³C and C/N between the sources and sink indicates a weakening TOM and freshwater POC input in the surface sedimentary organic matter seawards, and a strengthening contribution from the marine organic matter. Thus we suggest that bulk organic δ¹³C and C/N analysis can be used to indicate sources of sedimentary organic matter in estuarine environments. Organic carbon in surface sediments derived from anthropogenic sources such as human waste and organic pollutants from industrial and agricultural activities accounts for less than 10% of the total organic carbon (TOC). Although results also indicate elevated δ¹³C of sedimentary organic matter due to some agricultural products such as sugarcane, C₃ plants are still the dominant vegetation type in this area, and the bulk organic δ¹³C and C/N is still an effective indicator for sources of organic matter in estuarine sediments.     

The interannual and decadal variability of the sea level in the Japan/East Sea

Sea level observed by altimeter during the 1993–2007 period and the thermosteric sea level from 1945 through 2005 obtained by using the global ocean temperature data sets recently published are used to investigate the interannual and decadal variability of the sea level in the Japan/East Sea (JES) and its response to El Niño and Southern Oscillation (ENSO). Both the interannual variations of the sea level observed by altimeter and those of the thermosteric sea level obtained from reanalyzed data in the JES are closely related to ENSO. As a result, one important consequence is that the sea level trends are mainly caused by the thermal expansion in the JES. An ‘enigma’ is revealed that the correlation between the thermosteric sea level and ENSO during the PDO (Pacific Decadal Oscillation) warm phase (post mid-1970s) is inconsistent with that during the cold phase (pre mid-1970s) in the JES. The thermosteric sea level trends and the Southern Oscillation Index (SOI) suggest a strong negative correlation during the period 1977–1998, whereas there appears a relatively weak positive correlation during the period 1945–1976 in the JES. Based on the SODA (Simple Oceanographic Data Assimilation) datasets, possible mechanisms of the interannual and decadal variability of the sea level in the JES are discussed. Comprehensive analysis reveals that the negative anomalies of SOI correspond to the positive anomalies of the southeast wind stress, the net advective heat flux and the sea level in the JES during the PDO warm phase. During the PDO cold phase, the negative anomalies of SOI correspond to the positive anomalies of the southwest wind stress, the negative anomalies of the net advective heat flux and the sea level in the JES.