Anomalous behavior of cristobalite in helium under high pressure

We have investigated the high-pressure behavior of cristobalite in helium by powder X-ray diffraction. Cristobalite transformed to a new phase at about 8 GPa. This phase is supposed to have a molar volume of about 30 % larger than cristobalite, suggesting the dissolution of helium atoms in its interstitial voids. On further compression, the new phase transformed to a different phase which showed an X-ray diffraction pattern similar to cristobalite X-I at about 21 GPa. On the other hand, when the new phase was decompressed, it transformed to another new phase at about 7 GPa, which is also supposed to have a molar volume of about 25 % larger than cristobalite. On further decompression, the second new phase transformed to cristobalite II at about 2 GPa. In contrast to cristobalite, quartz did not show anomalous behavior in helium. The behavior of cristobalite in helium was also consistent with that in other mediums up to about 8 GPa, where the volume of cristobalite became close to that of quartz. These results suggest that dissolution of helium may be controlled not only by the density (amount of voids) but also by the network structure of SiO₄ tetrahedra (topology of voids).     

Morphological classification of nearby galaxies based on asymmetry and luminosity concentration

We investigate the behaviour of the asymmetry parameter A as a morphological parameter using a 'volume-limited' sample of 349 galaxies  (distance ≤25 Mpc,  M_V ≤−18.5 mag)  and a larger magnitude-limited sample of 707 nearby galaxies. We confirm the correlation of A with morphological type. The late-type galaxies (Sdm, Sm and Im) have larger A than early-type galaxies, and they tend to have larger A than spiral galaxies. We investigate the usefulness of the A versus concentration index C _in diagram as a tool for the regular–irregular and early–late classification. The diagram is not very useful to the regular versus late-type irregular classification, as inferred previously, but it is found to be useful to the early–late classification.     

Geochemical characteristics of ores and surface waters for environmental risk assessment in the Pinpet iron deposit,southern Shan State,Myanmar

Mining operations in the Pinpet Fe deposit, which is the second‐largest Fe deposit in Myanmar, are currently suspended, in part because of possible contamination of heavy metals and hazardous elements (e.g., Fe, As, Cu, Zn, and U) into the surrounding aquatic environment and associated public concern. However, a scientific investigation of the source and degree of contamination in streams near the deposit has not yet been conducted. Therefore, we quantified heavy‐metal and hazardous‐element concentrations of stream waters and sediments in stream beds, and measured the speciation and concentration of these metals in deposit Fe ores using the sequential extraction method, to better understand the influence of mining activities on the surrounding environment. Geochemical results for Nan‐tank‐pauk stream and its tributaries indicate that the chemical compositions of their waters are controlled by carbonate bedrock and that no detectable contamination has occurred as a result of mining activity or hematite and limonite ore beneficiation processes in either the wet or dry seasons. All measured heavy‐metal and hazardous‐element concentrations were below the World Health Organization standards for drinking water and the proposed national drinking water quality standards in Myanmar. Bulk chemical compositions of stream‐bed and tailings dam sediments show that As, Zn, and Cu concentrations are similar to those in uncontaminated sediments. Results of bulk mineralogical and chemical analyses of ore samples reveal that some limonite ore samples contain substantial amounts of As (up to 2 wt%). However, sequential extraction results indicate that most (>90%) of the As in these As‐rich ores is hosted in insoluble fractions (e.g., crystalline Fe hydroxides and clays). Therefore, arsenic is unlikely to be released into the aquatic environment by interacting with water during ore beneficiation processes should the mine resume operations.     

Generalized method for non-linear seismic response analysis of a three dimensional soil–structure interaction system

Previous achievements using the dynamic non-linear analysis of an interaction system are reviewed briefly, after which a three dimensional (3D) model of the stress redistribution of soil based on the Mohr–Coulomb failure law is presented to evaluate the unbalanced tensor at every iteration in the load transfer method. A 3D, full non-linear analysis was used to examine the validity and accuracy of results obtained by 2D analysis by combining the model of redistributed stresses proposed here with the joint element model. Based on the numerical solution reported here, we concluded that both the 3D and 2D models of stress redistribution work well and reflect the yielding pattern of soil during excitation, but the former is more realistic. The failure area in the structural zone obtained by 3D analysis is slightly larger but similar to that obtained by 2D analysis. The ratio of maximum strain to yield strain and non-linear time ratio, β_s, for the soil elements in the structural zone are also a little larger. In contrast, the maximum separation values for the joint elements are much smaller and the separation pattern for the x-side wall interface is the reverse of that found by 2D analysis. These values, however, affect only responses in the short period range and the regions close to the interface. In general, the tendencies shown by 2D analysis for the effects of non-linear behaviour on structural responses are confirmed for the parameters investigated.     

Dynamic behaviour and identification of non-uniform ground by the discrete wave number method

Powell's method for minimizing a function of several variables without calculating derivatives is applied to recorded earthquake motion on the ground surface to identify ground characteristics that have irregular profiles. The identifications are made by designating the shear wave velocity depth and width of the irregularity of surface ground as unknown parameters and are based on the least square fit between the amplitude of the transfer function determined from accelerograms recorded at two observation sites and the corresponding transfer function calculated from the response analysis of a ground model. The discrete wave number method is used to analyze the response of ground with a non-uniform profile for the incidence of SH waves. The effect of the initial assumed values on the convergence is studied by evaluating the square error between the theoretical transfer function and that calculated from the parameters identified. The dispersive trend found for the accelerograms is explained by the calculated response of a ground model with a non-uniform profile.     

Welded tuffs and related pyroclastic deposits in northeastern Japan

Welded tuffs and related pyroclastic deposits are distributed at many localities in northeastern Japan, especially around the volcanoes of the Nasu volcanic zone running from north to south, but they are absent from the region along the Japan Sea. Their geological age varies from the Miocene to the Holocene, those of the Pleistocene being predominant in amount. Petrographically they cover rather a wide range from andesite to rhyolite, among which dacite is most common. The welded tuffs are always compact and hard, with well-developed columnar jointing, carrying parallel-layered obsidian lenticules; and various stages are observed from loose pyroclastic deposits to lava-like welded tuffs. Petrological, petrochemical, and physical properties of these deposits are studied in some detail. From these data some genetic consideration is given for the mechanism of welding, and also for the relation between the nature of parental magma and the formation of such pyroclastic deposits.     

Separation and sliding between soil and structure during strong ground motion

This paper presents an approach to the problem of separation and sliding between soil and structure in the finite element analysis of dynamic soil-structure interaction problems. Joint elements are arranged along the contact surface between soil and structure and they have a property such that tensile forces are not transmitted between the planes representing structure and soil in the finite element analysis. The dynamic properties governing the sliding are determined by the Mohr-Coulomb failure law determined from the cohesion and the friction angle between soil and structure. The proposed method is applied to (i) a model of a reactor building resting on the free surface of layered ground and (ii) a buried foundation structure. The numerical computations reveal the following results: that the translation is dominant in the motion of the structure when sliding is taking place between soil and structure, and that the rocking is dominant in the rest of the response. The amplitude of the response during sliding is increased on any one point of the structure and decreased on any one point of the ground compared with that of the fixed condition at the interface. In the case of the buried structure, it is observed in the computed results that the structure and soil move in the opposite direction along the vertical contact surface and are separated from each other in the near surface region during the strong phase of the excitation.     

Compressibility of calcium ferrite-type MgAl2O4

 In situ X-ray diffraction experiments of calcium ferrite-type MgAl₂O₄ have been carried out using a diamond anvil cell combined with synchrotron radiation and an imaging plate X-ray detector under hydrostatic pressures up to 9 GPa. The observed unit-cell volumes at various pressures were fitted to the Birch-Murnaghan equation of state, yielding a bulk modulus of K _{T 0}= 241(3) GPa when K′ _{T 0}=4 is assumed. This relatively large bulk modulus of calcium ferrite-type MgAl₂O₄ is consistent with that expected from the systematic relation between bulk modulus and molar volume for the most compounds possessing fcc oxygen packing. Received March 5, 1996/Revised, accepted October 15, 1996