High-pressure phase behavior of MnTiO<Subscript>3</Subscript>: decomposition of perovskite into MnO and MnTi<Subscript>2</Subscript>O<Subscript>5</Subscript>

The phase relations and compression behavior of MnTiO₃ perovskite were examined using a laser-heated diamond-anvil cell, X-ray diffraction, and analytical transmission electron microscopy. The results show that MnTiO₃ perovskite becomes unstable and decomposes into MnO and orthorhombic MnTi₂O₅ phases at above 38 GPa and high temperature. This is the first example of ABO₃ perovskite decomposing into AO + AB₂O₅ phases at high pressure. The compression behavior of volume, axes, and the tilting angle of TiO₆ octahedron of MnTiO₃ perovskite are consistent with those of other A²⁺B⁴⁺O₃ perovskites, although no such decomposition was observed in other perovskites. FeTiO₃ is also known to decompose into two phases, instead of transforming into the CaIrO₃-type post-perovskite phase and we argue that one of the reasons for the peculiar behavior of titanate is the weak covalency of the Ti–O chemical bonds.     

Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

Seismic behaviour of pile groups by hybrid experiments

Non-linear seismic soil-pile interaction was studied with a hybrid procedure that used a pseudo-dynamic testing (PDT) method modified to account for frequency dependence and developed for foundation-soil systems. The numerical scheme used in the conventional PDT was improved by the introduction of a time-dependent pseudo-forcing function derived from the frequency-dependent dynamic characteristics of the system by Hilbert transformation in the frequency domain. Single, 2-, 3- and 9-pile group foundation models were used, their mechanical characteristics later being determined from static and forced vibration dynamic tests. Amplitude scaling was used for three recorded accelerograms. Data recorded during an earthquake at the site of the experiments revealed that the proposed methodology predicts well seismic nonlinear interaction and accounts for frequency dependence and non-linearity in the time domain.     

Hybrid experiments on non-linear earthquake-induced soil-structure interaction

Non-linear seismic soil-structure interaction is studied through a hybrid procedure using the pseudo-dynamic testing (PDT) method which is modified to take into account frequency dependence and developed for foundation-soil systems. The numerical scheme used in conventional PDT is improved by introduction of a time-dependent pseudo-forcing function which is derived from frequency-dependent dynamic characteristics of the system by means of Hilbert transformation in the frequency domain. Surface, shallow and caisson foundation models that differed in size and depth of embedment were used. The mechanical characteristics of the systems were determined from static and forced vibration dynamic tests. An amplitude scaling technique was used for three recorded accelerograms.     

Implementation of integrated multi-channel analysis of surface waves and waveform inversion techniques for seismic hazard estimation

In this study, an integrated multi-channel analysis of Surface Waves (MASW) technique is applied to explore the geotechnical parameters of subsurface layers at the Zafarana wind farm. Moreover, a seismic hazard procedure based on the extended deterministic technique is used to estimate the seismic hazard load for the investigated area. The study area includes many active fault systems along the Gulf of Suez that cause many moderate and large earthquakes. Overall, the seismic activity of the area has recently become better understood following the use of new waveform inversion method and software to develop accurate focal mechanism solutions for recent recorded earthquakes around the studied area. These earthquakes resulted in major stress-drops in the Eastern desert and the Gulf of Suez area. These findings have helped to reshape the understanding of the seismotectonic environment of the Gulf of Suez area, which is a perplexing tectonic domain. Based on the collected new information and data, this study uses an extended deterministic approach to re-examine the seismic hazard for the Gulf of Suez region, particularly the wind turbine towers at Zafarana Wind Farm and its vicinity. Alternate seismic source and magnitude-frequency relationships were combined with various indigenous attenuation relationships, adapted within a logic tree formulation, to quantify and project the regional exposure on a set of hazard maps. We select two desired exceedance probabilities (10 and 20 %) that any of the applied scenarios may exceed the largest median ground acceleration. The ground motion was calculated at 50th, 84th percentile levels for both selected probabilities of exceeding the median.     

The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.     

A current measurement by moored savonius meters

A current measurement by four Savonius current meters is done for a little longer than eight days in the north-western Pacific. The result of a preliminary analysis of the records is described. Periods around twenty-four hours are dominant. The energy spectra match the -5/3 law for the frequency range up to the diurnal frequency.     

Unquenchable high-pressure perovskite polymorphs of MnSnO3 and FeTiO3

New high-pressure orthorhombic (GdFeO₃-type) perovskite polymorphs of MnSnO₃ and FeTiO₃ have been observed using in situ powder X-ray diffraction in a diamond-anvil cell with synchrotron radiation. The materials are produced by the compression of the lithium niobate polymorphs of MnSnO₃ and FeTiO₃ at room temperature. The lithium niobate to perovskite transition occurs reversibly at 7 GPa in MnSnO₃, with a volume change of -1.5%, and at 16 GPa in FeTiO₃, with a volume change of -2.8%. Both transitions show hysteresis at room temperature. For MnSnO₃ perovskite at 7.35 (8) GPa, the orthorhombic cell parameters are a=5.301 (2) A, b=5.445 (2) Å, c=7.690 (8) Å and V= 221.99 (15) ų. Volume compression data were collected between 7 and 20 GPa. The bulk modulus calculated from the compression data is 257 (18) GPa in this pressure region. For FeTiO₃ perovskite at 18.0 (5) GPa, cell parameters are a=5.022 (6) Å, b=5.169 (5) Å, c=7.239 (9) Å and V= 187.94 (36) ų. Based on published data on the quench phases, the FeTiO₃ perovskite breaks down to a rocksalt + baddelyite mixture of FeO and TiO₂ at 23 GPa. This is the first experimental verification of the pressure-induced breakdown of a perovskite to simple oxides.     

Evidence for erosion and deposition by the 2011 Tohoku-oki tsunami on the nearshore shelf of Sendai Bay,Japan

Ongoing geological research into processes operating on the nearshore continental shelf and beyond is vital to our understanding of modern tsunami-generated sediment transport and deposition. This paper investigates the southern part of Sendai Bay, Japan, by means of high-resolution seismic surveys, vibracoring, bathymetric data assimilation, and radioisotope analysis of a core. For the first time, it was possible to identify an erosional surface in the shallow subsurface, formed by both seafloor erosion and associated offshore-directed sediment transport caused by the 2011 Tohoku-oki tsunami. The area of erosion and deposition extends at least 1,100 m offshore from the shoreline down to water depths of 16.7 m. The tsunami-generated sedimentological signature reaches up to 1.2 m below the present seafloor, whereas bathymetric changes due to storm-related reworking over a period of 3 years following the tsunami event have been limited to the upper ~0.3 m, despite the fact that the study area is located on an open shelf facing the Pacific Ocean. Tsunami-generated erosion surfaces may thus be preserved for extended periods of time, and may even enter the rock record, because the depth of tsunami erosion can exceed the depth of storm erosion. This finding is also important for interpretation of modern submarine strata, since erosion surfaces in shallow (depths less than ~1 m) seismic records from open coast shelves have generally been interpreted as storm-generated surfaces or transgressive ravinement surfaces.