Rate-dependent strength of porous ice–silica mixtures and its implications for the shape of small to middle-sized icy satellites

Porosity is one of the most important physical properties in the rheology of small icy satellites composed of ice–silicate mixtures. Deformation experiments involving ice and 1 μm silica bead mixtures were conducted to clarify the effect of porosity on the flow law of ice–silica mixtures. Mixtures with silica mass contents of 0, 30, and 50 wt.% were used for the experiments, and the porosity was changed from 0% to 25% in each mixture. The temperature ranged from −10 to −20 °C, and the strain rate was changed from 1.2 × 10⁻⁶ to 4.2 × 10⁻⁴ s⁻¹. As a result, it was found that the ice–silica mixtures deformed plastically, and that the relationship between the maximum stress, σ_max, on the stress–strain curve and the applied strain rate, , could be described by the following flow law: . The mixture became softer as the porosity or silica mass content increased, and the stress exponent n and activation energy Q were independent of porosity, depending only on the silica mass content. Furthermore, the parameter A₀ could be written as A₀ = B(1 − ?)^−α, where ? is the porosity. The constants B and α also depended only on the silica mass content, and they increased with the increase in this content. The Maxwell relaxation time was calculated in order to estimate the conditions for topographic relaxation of icy satellites, and it was found that topographic relaxation occurred at temperatures higher than 160 K in the case of icy satellites with mean radii of 200 km.     

Oxygen- and magnesium-isotope compositions of calcium-aluminum-rich inclusions from CR2 carbonaceous chondrites

We report both oxygen- and magnesium-isotope compositions measured in situ using a Cameca ims-1280 ion microprobe in 20 of 166 CAIs identified in 47 polished sections of 15 CR2 (Renazzo-type) carbonaceous chondrites. Two additional CAIs were measured for oxygen isotopes only. Most CR2 CAIs are mineralogically pristine; only few contain secondary phyllosilicates, sodalite, and carbonates - most likely products of aqueous alteration on the CR2 chondrite parent asteroid. Spinel, hibonite, grossite, anorthite, and melilite in 18 CAIs have ¹⁶O-rich (Δ¹⁷O = −23.3 ± 1.9‰, 2σ error) compositions and show no evidence for postcrystallization isotopic exchange commonly observed in CAIs from metamorphosed CV carbonaceous chondrites. The inferred initial ²⁶Al/²⁷Al ratios, (²⁶Al/²⁷Al)₀, in 15 of 16 ¹⁶O-rich CAIs measured are consistent with the canonical value of (4.5-5) × 10⁻⁵ and a short duration (<0.5 My) of CAI formation. These data do not support the “supra-canonical” values of (²⁶Al/²⁷Al)₀ [(5.85-7) × 10⁻⁵] inferred from whole-rock and mineral isochrons of the CV CAIs. A hibonite-grossite-rich CAI El Djouf 001 MK #5 has uniformly ¹⁶O-rich (Δ¹⁷O = −23.0 ± 1.7‰) composition, but shows a deficit of ²⁶Mg and no evidence for ²⁶Al. Because this inclusion is ¹⁶O-rich, like CAIs with the canonical (²⁶Al/²⁷Al)₀, we infer that it probably formed early, like typical CAIs, but from precursors with slightly nonsolar magnesium and lower-than-canonical ²⁶Al abundance. Another ¹⁶O-enriched (Δ¹⁷O = −20.3 ± 1.2‰) inclusion, a spinel-melilite CAI fragment Gao-Guenie (b) #3, has highly-fractionated oxygen- and magnesium-isotope compositions (∼11 and 23‰/amu, respectively), a deficit of ²⁶Mg, and a relatively low (²⁶Al/²⁷Al)₀ = (2.0 ± 1.7) × 10⁻⁵. This could be the first FUN (Fractionation and Unidentified Nuclear effects) CAI found in CR2 chondrites. Because this inclusion is slightly ¹⁶O-depleted compared to most CR2 CAIs and has lower than the canonical (²⁶Al/²⁷Al)₀, it may have experienced multistage formation from precursors with nonsolar magnesium-isotope composition and recorded evolution of oxygen-isotope composition in the early solar nebula over  My. Eight of the 166 CR2 CAIs identified are associated with chondrule materials, indicating that they experienced late-stage, incomplete melting during chondrule formation. Three of these CAIs show large variations in oxygen-isotope compositions (Δ¹⁷O ranges from −23.5‰ to −1.7‰), suggesting dilution by ¹⁶O-depleted chondrule material and possibly exchange with an ¹⁶O-poor (Δ¹⁷O > −5‰) nebular gas. The low inferred (²⁶Al/²⁷Al)₀ ratios of these CAIs (<0.7 × 10⁻⁵) indicate melting >2 My after crystallization of CAIs with the canonical (²⁶Al/²⁷Al)₀ and suggest evolution of the oxygen-isotope composition of the inner solar nebula on a similar or a shorter timescale. Because CAIs in CR2 and CV chondrites appear to have originated in a similarly ¹⁶O-rich reservoir and only a small number of CR2 and CV CAIs were affected by chondrule melting events in an ¹⁶O-poor gaseous reservoir, the commonly observed oxygen-isotope heterogeneity in CAIs from metamorphosed CV chondrites is most likely due to fluid-solid isotope exchange on the CV asteroidal body rather than gas-melt exchange. This conclusion does not preclude that some CV CAIs experienced oxygen-isotope exchange during remelting, instead it implies that such remelting is unlikely to be the dominant process responsible for oxygen-isotope heterogeneity in CV CAIs. The mineralogy, oxygen and magnesium-isotope compositions of CAIs in CR2 chondrites are different from those in the metal-rich, CH and CB carbonaceous chondrites, providing no justification for grouping CR, CH and CB chondrites into the CR clan.     

In situ stress measurements in NIED boreholes in and around the fault zone near the 1995 Hyogo-ken Nanbu earthquake, Japan

Abstract The 1995 Hyogo-ken Nanbu (Kobe) earthquake, M 7.2, occurred along the north-east–south-west trending Rokko–Awaji Fault system. Three boreholes of 1001 m, 1313 m and 1838 m deep were drilled in the vicinity of the epicenter of the earthquake. Each borehole is located at characteristic sites in relation to active faults and the aftershock distribution. In particular, the Nojima–Hirabayashi borehole [Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drilling] in Awaji Island was drilled to a depth of 1838 m, approximately 320 m southeast from the surface rupture of the Nojima Fault, and it crosses fracture zones below a depth of 1140 m. In situ stress measurements by the hydraulic fracturing method were conducted in these boreholes within 1.5 years after the earthquake. Measurement results suggest the following: (i) Differential stress values are very small, approximately 10 MPa at a depth of 1000 m at each site; (ii) the orientation of maximum horizontal compression is almost the same in the boreholes, perpendicular to the surface trace of the faults, north-west–south-east; (iii) fault types estimated from the state of stress differ among these sites; and (iv) the differential stress value just beneath the fault fracture zone decreases abruptly to one-half of that above the fault zone in the Hirabayashi NIED drilling. These features support the idea that the shear stress along the Rokko–Awaji Fault system decreased to a low level just after the earthquake.     

Characteristics of Porphyry Cu Mineralization at Waisoi (Namosi District), Viti Levu, Fiji

The porphyry Cu deposits at Waisoi in Namosi district, Viti Levu are separated into two deposits: the Waisoi East deposit and the Waisoi West deposit. In the Waisoi East deposit, quartz porphyry is exposed and in the Waisoi West deposit, diorite porphyry is sporadically exposed in addition to a small body of quartz porphyry. The mineralization in the Waisoi East deposit is characterized by the bornite–chalcopyrite–pyrite assemblage associated with traces of molybdenite and native gold. Polyphase fluid inclusions in stockwork quartz veinlets show homogenization temperatures ranging from 210 to >500°C. The high‐grade Cu mineralization in the Waisoi West deposit is characterized by the bornite–chalcopyrite–pyrite assemblage accompanied with sheeted and stockwork quartz veinlets. Polyphase fluid inclusions occasionally containing hematite flakes in quartz veinlets in the center of the Waisoi West deposit homogenize at temperatures ranging from 450°C to >500°C. However, fluid inclusions in stockwork quartz veinlets in the periphery, homogenize at lower temperatures around 210°C. Both in the Waisoi East and Waisoi West deposits, primary bornite–chalcopyrite–pyrite assemblage in the high Cu‐grade zone was deposited at the upper stability limit of chalcopyrite with respect to sulfur fugacity. Thus, the principal Cu mineralization at the Waisoi deposits occurred at a relatively high sulfur fugacity, that is, in a high‐sulfidation environment.     

Fracture-zone conditions on a recently active fault: insights from mineralogical and geochemical analyses of the Hirabayashi NIED drill core on the Nojima fault, southwest Japan, which ruptured in the 1995 Kobe earthquake

An 1800-m-deep borehole into the Nojima fault zone was drilled at Nojima-Hirabayashi, Japan, after the 1995 Hyogo-ken Nanbu (Kobe) earthquake. Three possible fracture zones were detected at depths of about 1140, 1300, and 1800 m. To assess these fracture zones in this recently active fault, we analyzed the distributions of fault rocks, minerals, and chemical elements in these zones. The central fault plane in the shallowest fracture zone was identified by foliated blue-gray gouge at a depth of 1140 m. The degree of fracturing was evidently greater in the hanging wall than in the footwall. Minerals detected in this zone were quartz, orthoclase, plagioclase, and biotite, as in the parent rock (granodiorite), and also kaolinite, smectite, laumontite, stilbite, calcite, ankerite, and siderite, which are related to hydrothermal alteration. Biotite was absent in both the hanging wall and footwall across the central fault plane, but it was absent over a greater distance from the central fault plane in the hanging wall than in the footwall. Major element compositions across this zone suggested that hydrothermal alteration minerals such as kaolinite and smectite occurred across the central fault plane for a greater distance in the hanging wall than in the footwall. Similarly, H₂O+ and CO₂ had higher concentrations in the hanging wall than in the footwall. This asymmetrical distribution pattern is probably due to the greater degree of wall–rock fracturing and associated alteration in the hanging wall. We attributed the characteristics of this zone to fault activity and fluid–rock interactions. We analyzed the other fracture zones along this fault in the same way. In the fracture zone at about 1300 m depth, we detected the same kinds of hydrothermal alteration minerals as in the shallower zone, but they were in fewer samples. We detected relatively little H₂O+ and CO₂, and little evidence for movement of the major chemical elements, indicating little past fluid–rock interaction. In the fracture zone at about 1800 m depth, H₂O+ and CO₂ were very enriched throughout the interval, as in the fracture zone at about 1140 m depth. However, smectite was absent and chlorite was present, indicating the occurrence of chloritization, which requires a temperature of more than 200 °C. Only smectite can form under the present conditions in these fracture zones. The chloritization probably occurred in the past when the fracture zone was deeper than it is now. These observations suggest that among the three fracture zones, that at about 1140 m depth was the most activated at the time of the 1995 Hyogo-ken Nanbu (Kobe) earthquake.     

Warped temperature profiles observed in the sediment of geothermally active areas in the Japan Sea— A hypothesis of double diffusive sinking

Some temperature profiles observed in sea floor sediments of the Japan Sea, west of the northern part of Honshu, show distinct gradients changing with depth, for which we use the term warping. Using a simplified model, this warping can be attributed to an abrupt temperature change in the bottom water just above the sediment. The bottom water temperature change might be explained by the hypothesis that warm and salt surface water in the region sank to the sea bottom, through colder and less saline water, maintaining a relatively warmer temperature than the bottom water which originates from ordinary lateral intrusion.     

Water masses and hydrography in the tropical Pacific during Japanese Pacific Climate Study '91 cruise

Hydrographic measurements by CTD were made in the western-central Equatorial Pacific (160°W–147°E) during the Japanese Pacific Climate Study cruise in January–February 1991. InT-S diagram, three water masses are seen in the layer of kg/m³: salinity water corresponding to the Tropical Water of eastern South Pacific origin, less saline water in the North Pacific, and water with salinity between the above two, found on the equator. In three meridional sections (160°W–160°E), the Tropical Water of eastern South Pacific origin extends further equatorward than the climatological data of Levitus (1982).     

Transition of solar cycle length in association with the occurrence of grand solar minima indicated by radiocarbon content in tree-rings

In this paper, we review the variation of the 11-year solar cycle since the 15th century revealed by the measurement of radiocarbon content in single-year tree-rings of Japanese cedar trees. Measurements of radiocarbon content in absolutely dated tree-rings provide a calibration curve for accurate dating of archaeological matters, but at the same time, enable us to examine the variations of solar magnetic activity in the pre-historical period. The Sun holds several long-term quasi-cyclic variations in addition to the fundamental 11-year sunspot activity cycle and the 22-year polarity reversal cycle, and it is speculated that the property of the 11-year and the 22-year solar cycle varies in association with such long-term quasi-cycles. It is essential to reveal the details of solar variations around the transition time of solar dynamo for illuminating the mechanisms of the long-term solar variations. We therefore have investigated the property of the 11-year and 22-year cycles around the two grand solar minima; the Maunder Minimum (1645–1715 AD) and the Spoerer Minimum (1415–1534 AD), the periods of prolonged sunspot minima. As a result, slight stretching of the “11-year” and the “22-year” solar cycles was found during these two grand solar activity minima; continuously during the Maunder Minimum and only intermittently during the Spoerer Minimum. On the contrary, normal or slightly shortened 11-year cycles were detected during the interval period of these two minima. It suggests the inverse correlation between the solar cycle length and solar magnetic activity level, and also the change of meridional flow during the grand solar activity minima. Further measurements for the beginning of the grand solar minima will provide a clue to the occurrence of such prolonged sunspot disappearance. We also discuss the effect of solar variations to radiocarbon dating.     

Diel tuning of photosynthetic systems in ice algae at Saroma-ko Lagoon, Hokkaido, Japan

Ice algae are the major primary producers in seasonally ice-covered oceans during the cold season. Diurnal change in solar radiation is inevitable for ice algae, even beneath seasonal sea ice in lower-latitude regions. In this work, we focused on the photosynthetic response of ice algae under diurnally changing irradiance in Saroma-ko Lagoon, Japan. Photosynthetic properties were assessed by pulse-amplitude modulation (PAM) fluorometry. The species composition remained almost the same throughout the investigation. The maximum electron transport rate (rETR_max), which indicates the capacity of photosynthetic electron transport, increased from sunrise until around noon and decreased toward sunset, with no sign of the afternoon depression commonly observed in other photosynthetic organisms. The level of non-photochemical quenching, which indicates photoprotection activity by dissipating excess light energy via thermal processes, changed with diurnal variations in irradiance. The pigment composition appeared constant, except for xanthophyll cycle pigments, which changed irrespective of irradiance. These results indicate that ice algae tune their photosynthetic system harmonically to achieve efficient photosynthesis under diurnally changing irradiance, while avoiding damage to photosystems. This regulation system may be essential for productive photosynthesis in ice algae.     

Geometry of the Nojima Fault at Nojima-Hirabayashi, Japan – I. A Simple Damage Structure Inferred from Borehole Core Permeability

The 1995 Kobe (Hyogo-ken Nanbu) earthquake, M = 7.2, ruptured the Nojima fault in southwest Japan. We have studied core samples taken from two scientific drillholes that crossed the fault zone SW of the epicentral region on Awaji Island. The shallower hole, drilled by the Geological Survey of Japan (GSJ), was started 75 m to the SE of the surface trace of the Nojima fault and crossed the fault at a depth of 624 m. A deeper hole, drilled by the National Research Institute for Earth Science and Disaster Prevention (NIED) was started 302 m to the SE of the fault and crossed fault strands below a depth of 1140 m. We have measured strength and matrix permeability of core samples taken from these two drillholes. We find a strong correlation between permeability and proximity to the fault zone shear axes. The half-width of the high permeability zone (approximately 15 to 25 m) is in good agreement with the fault zone width inferred from trapped seismic wave analysis and other evidence. The fault zone core or shear axis contains clays with permeabilities of approximately 0.1 to 1 microdarcy at 50 MPa effective confining pressure (10 to 30 microdarcy at in situ pressures). Within a few meters of the fault zone core, the rock is highly fractured but has sustained little net shear. Matrix permeability of this zone is approximately 30 to 60 microdarcy at 50 MPa effective confining pressure (300 to 1000 microdarcy at in situ pressures). Outside this damage zone, matrix permeability drops below 0.01 microdarcy. The clay-rich core material has the lowest strength with a coefficient of friction of approximately 0.55. Shear strength increases with distance from the shear axis. These permeability and strength observations reveal a simple fault zone structure with a relatively weak fine-grained core surrounded by a damage zone of fractured rock. In this case, the damage zone will act as a high-permeability conduit for vertical and horizontal flow in the plane of the fault. The fine-grained core region, however, will impede fluid flow across the fault.