The geochemistry of prograde and retrograde charnockite-gneiss reactions in southern India

Exposures in many quarries in southern India exhibit field evidence for incipient charnockitization of tonalitic and granitic gneiss (prograde relationship), or retrogression of charnockite to produce tonalitic gneiss (retrograde relationship). Few systematic geochemical relationships exist between adjacent gneisscharnockite sample pairs during either prograde or retrograde reactions. Most elements and element ratios exhibit inconsistent variations; however, prograde chamockites appear enriched in Ta, Pb, volatiles (chiefly CO₂), and in transition metals relative to Mg, and depleted in REE and Y compared to adjacent gneiss protoliths. Retrograde gneisses have higher Rb, Pb, Th, Hf, Zn relative to Co, Nb relative to Ta, Hf relative to Zr, and volatiles (chiefly H₂O) compared to parental charnockites. Of those elements (U, Th, Rb, Cs, Pb) significantly depleted in high-pressure charnockites exposed south of the prograde transition zone, only Pb is significantly replenished during retrogression. Evidence suggests that prograde fluids are relatively rich in CO₂ and retrograde fluids in H₂O and that the typical non-systematic geochemical variations during prograde and retrograde reactions reflect local effects at the wave front.     

http://www.sciencedirect.com/science/article/pii/S1674987113000820

The combined use of Hf,Nd and Sr isotopes is more useful in understanding the supercontinent cycle than the use of only Hf isotopic data from detrital zircons.Sr and Nd seawater isotopes,although not as precise as εNd and εHf distributions,also record input from ocean ridge systems.Unlike detrital zircons where sources cannot be precisely located because of crustal recycling,both the location and tectonic setting often can be constrained for whole-rock Nd isotopic data.Furthermore,primary zircon sources may not reside on the same continent as derivative detrital zircons due to supercontinent breakup and assembly.Common to all of the isotopic studies are geographic sampling biases reflecting outcrop distributions,river system sampling,or geologists,and these may be responsible for most of the decorrelation observed between isotopic systems.Distributions between 3.5 and 2 Ga based on εHf median values of four detrital zircon databases as well as our compiled εNd database are noisy but uniformly distributed in time,whereas data between 2 and 1 Ga data are more tightly clustered with smaller variations.Grouped age peaks suggest that both isotopic systems are sampling similar types of orogens.Only after 1 Ga and before 3.5 Ga do we see wide variations and significant disagreement between databases,which may partially reflect variations in both the number of sample locations and the number of samples per location.External and internal orogens show similar patterns in εNd and εHfwith age suggesting that both juvenile and reworked crustal components are produced in both types of orogens with similar proportions.However,both types of orogens clearly produce more juvenile isotopic signatures in retreating mode than in advancing mode.Many secular changes in εHf and εNd distributions correlate with the supercontinent cycle.Although supercontinent breakup is correlated with short-lived decreasing εHf and εNd （≤ 100 Myr） for most supercontinents,there is no isotopic evidence for the breakup of the Paleoproterozoic supercontinent Nuna.Assembly of supercontinents by extroversion is recorded by decreasing εNd in granitoids and metasediments and decreasing εHf in zircons,attesting to the role of crustal reworking in external orogens in advancing mode.As expected,seawater Sr isotopes increase and seawater Nd isotopes decrease during supercontinent assembly by extroversion.Pangea is the only supercontinent that has a clear isotopic record of introversion assembly,during which median εNd and εHf rise rapidly for ≤ 100 Myr.Although expected to increase,radiogenic seawater Sr decreases （and seawater Nd increases） during assembly of Pangea,a feature that may be caused by juvenile input into the oceans from new ocean ridges and external orogens in retreating mode.The fact that a probable onset of plate tectonics around 3 Ga is not recorded in isotopic distributions may be due the existence of widespread felsic crust formed prior to the onset of plate tectonics in a stagnant lid tectonic regime,as supported by Nd and Hf model ages.     

The Geochemistry of the Arabian Lithospheric Mantle--a Source for Intraplate Volcanism?

We present trace element and Sr–Nd–Hf–Pb isotopecompositions for clinopyroxenes from anhydrous spinel peridotiteand garnet ± spinel pyroxenite xenoliths of Pan-Africanlithospheric mantle from Jordan, including the first high-precisiondouble-spike Pb isotope measurements of mantle clinopyroxene.Clinopyroxenes from the peridotites are variably Th–U–LILE–LREEenriched and display prominent negative Nb, Zr and Ti anomalies.MREE–HREE abundances can generally be modelled as partialmelting residues of spinel lherzolite with primitive-mantle-likecomposition after extraction of 5–10% melt, whereas theenrichments in Th–U–LILE–LREE require a Pan-Africanor later metasomatic event. The large range of Nd, Sr, Pb andHf isotope ratios in both peridotites and pyroxenites (e.g.Nd 1·4–17·5; ²⁰⁶Pb/²⁰⁴Pb 17·2–20·4;Hf 0·6–164·6) encompasses compositionsmore radiogenic than mid-ocean ridge basalt (MORB), and Pb isotopescover almost the entire range of oceanic basalt values. Hf valuesare some of the highest ever recorded in mantle samples andare decoupled from Nd in the same samples. Marked correlationsbetween Sr–Nd–Pb isotopes, LILE–LREE enrichmentsand HFSE depletion suggest that the metasomatizing agent wasa carbonatitic-rich melt and isotopic data suggest that metasomatismmay have been related to Pan-African subduction. The metasomaticmelt permeated depleted upper mantle (<16 kbar) during Pan-Africansubduction at 600–900 Ma, and the variably metasomatizedmaterial was then incorporated into the Arabian lithosphericmantle. There is no evidence for recent metasomatism (<30Ma) related to the Afar plume like that postulated to have affectedsouthern Arabian lithospheric mantle. Hf isotopes in the mantleclinopyroxenes are unaffected by metasomatism, and even somestrongly overprinted lithologies record ancient (>1·2Ga) pre-metasomatic Lu–Hf signatures of the depleted uppermantle that was the protolith of the Arabian lithospheric mantle.The ‘resistance’ of the Lu–Hf isotopic systemto later metasomatic events resulted in the development of extremelyheterogeneous Hf isotopic signatures over time that are decoupledfrom other isotopic systems. No mantle sample in this studyexactly matches the chemical and isotopic signature of the sourceof Jordanian intraplate basalts. However, the xenolith compositionsare broadly similar to those of the source of Arabian intraplatebasalts, suggesting that the numerous Cenozoic intraplate volcanicfields throughout Arabia may be the product of melting uppermantle wedge material fertilized during Pan-African subductionand incorporated into the Arabian lithospheric mantle. We proposea model whereby the proto-Arabian lithospheric mantle underwenta major melting event in early Proterozoic–late Archeantimes (at the earliest at 1·2 Ga). Island-arc volcanismand major crust formation occurred during the Pan-African orogeny,which liberated fluids and possibly small-degree melts thatmigrated through the mantle creating zones of enrichment forcertain elements depending upon their compatibility. Immobileelements, such as Nb, were concentrated near the base of themantle wedge providing the source of the Nb-rich Jordanian volcanicrocks. More mobile elements, such as LILE and LREE, were transportedup through the mantle and fertilized the shallow mantle sourceof the Jordanian xenoliths. Following subduction, the mantlewedge became fossilized and preserved distinct enriched anddepleted zones. Lithospheric rifting in the Miocene triggeredpartial melting of spinel-facies mantle in the lower lithosphere,which mixed with deeper asthenospheric garnet-facies melts asrifting evolved. These melts entrained segments of variablycarbonatite-metasomatized shallow lithospheric mantle en routeto the surface. KEY WORDS: Arabian lithospheric mantle; Jordan; mantle xenoliths; Sr–Nd–Hf–Pb isotopes     

Some observations on the chemical weathering of the Dartmoor granite

The majority of geomorphological papers about Dartmoor have been essentially speculative, particularly when discussing weathering processes and the evolution of the Dartmoor landscape. In contrast, this article presents a synthesis of several experimental investigations aimed at studying the chemical weathering of Dartmoor granite through the systematic analysis of soil and water samples. This involved the computation of a geochemical budget to determine the amount of erosion in the catchment, as well as more detailed mineralogical investigations within a soil profile. The annual output of solutes due to weathering was 116 kg ha^?1 a^?1 of which the majority was silica (93 kg ha^?1 a^?1). From an examination of the soil mineralogy, it was calculated that these solutes were derived from the dissolution of approximately 200 kg ha^?1 a^?1 plagioclase, 90 kg ha^?1 a^?1 biotite, and 40 kg ha^?1 a^?1 orthoclase. As well as the weathering of granite, there was also the production of kaolinite (150 kg ha^?1 a^?1) and gibbsite (0.02 kg ha^?1 a^?1). Analysis of the soil water chemistry confirmed that kaolinite was the stable mineral phase in the regolith, although in areas where interflow was the dominant mode of water movement, the solute composition was in equilibrium with both kaolinite and gibbsite. Examination of the clay mineralogy confirmed these results. The microtexture of quartz grains was examined by the scanning electron microscope as another means of investigating the hydrochemical environment in the soil. Silica was found precipitated on all the grains examined but the maximum amount occurred in the Bs horizon. This evidence showed that, firstly, the dissolution of aluminosilicate minerals is greater than that calculated by the chemical budget and, secondly, that models of granite weathering must take localized weathering in the soil profile into account. The final part of the paper highlights the limitations of calculating denudation rates for an entire catchment and stresses the need to consider weathering as a highly localized phenomenon, particularly where there are high volumes of interflow at hill crest sites. Observations on granite decomposition in the future should be quantitative in approach and be related to the local site conditions.     

A tale of two intrusions—where familiar rock names no longer suffice

Two contrasting intrusions in Greenland are described which both have extreme compositions and mineralogy. Ilímaussaq is part of the Mezoproterozoic Gardar Province of southern West Greenland. It developed by extreme fractionation in the crust of non‐remarkable weakly alkaline basic magmas leading to extraordinarily high levels of many rare elements. Indeed, in this intrusion the zirconium mineral, eudialyte, attains rock‐forming status. Gardiner in the East Greenland sector of the Palaeogene North Atlantic Igneous Province, was formed from nephelinitic magmas formed at great depth in the mantle by very low degrees of partial melting. Here, the magmas were so silica‐poor that there are large amounts of rocks composed of the melilite group of minerals, generally with perovskite (CaTiO₄) as a major phase. Thus, extreme compositions at Ilímaussaq were caused by fractionation to very small amounts of melt while at Gardiner it was caused by very small degrees of mantle melting. Both intrusions are known for fine specimens of rare minerals; in the case of Ilímaussaq over 200 have been described. Rocks such as those found here require their own names as they cannot be accommodated in the usual petrological nomenclature.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

Geospatial method for computing supplemental multi-decadal US coastal land use and land cover classification products,using Landsat data and C-CAP products

This paper discusses the development and implementation of a method that can be used with multi-decadal Landsat data for computing general coastal US land use and land cover (LULC) maps consisting of seven classes. With Mobile Bay, Alabama as the study region, the method that was applied to derive LULC products for nine dates across a 34-year time span. Classifications were computed and refined using decision rules in conjunction with unsupervised classification of Landsat data and Coastal Change and Analysis Program value-added products. Each classification’s overall accuracy was assessed by comparing stratified random locations to available high spatial resolution satellite and aerial imagery, field survey data and raw Landsat RGBs. Overall classification accuracies ranged from 83 to 91% with overall κ statistics ranging from 0.78 to 0.89. Accurate classifications were computed for all nine dates, yielding effective results regardless of season and Landsat sensor. This classification method provided useful map inputs for computing LULC change products.     

Maps > Representation

Abstract

Colour is considered a key means of expression for use in cartographic works. This is because colours and the relations among them influence not only the aesthetic impression a map creates but also its overall utility. In addition to Newton’s spectral colour theory, today theories with origins in artistic technique are gaining ground in cartography. This article introduces J. Itten’s colour theory (first published in 1961 in The Art of Colour [Kunst der Farbe]) with special attention given to his concept of seven colour contrasts. The article also discusses the suitability and unsuitability of their application in practical cartography, and it contributes original examples employing thematic maps, a discipline with broad possibilities for the application of these inventive methods by today’s mapmakers.     

JPEG压缩对摄影测量点定位精度的影响

对某城区一对1：8000航摄立体数学影像利用Intergraph数字摄影测量工作站上的立体量测软件ISDM进行了手上量测，然后通过用自行开发的GPS辅助光束法区域风平差软件WuACPSGPS的单模型光束法平差精确测定了18个加密点的位置，经过对数字影像采用1到100不同的质量因子的JPEG压缩，获得一组质量各异的压缩影像，从分析重建影像点定位结果的变化入手，探讨了JPEG压缩对摄影测量点定位精的影响。试验且明，失真JPEG压缩对摄影测量点定位精度的影响是显著的，随着压缩比的增大，影像可视化质量逐渐衰减，像点量测精度不断降低，加密点位精度几乎呈线性趋势下降，且高程比平面减的速度要快得多。     

Plant growth problems in colliery spoil reclamation— a review

The extensive distribution and intrusive nature of colliery spoil heaps resulting from deep coalmining in Britain are introduced. With a view to reclamation, the severity of coal spoil as a potential medium for plant growth is demonstrated and a thorough review of the literature on physical, chemical and biological constraints to vegetation establishment is presented. Problems of toxicity resulting from the weathering of pyrites and the marked spatial and temporal variations in toxicities and nutrient deficiencies in colliery shales are emphasized. Methods for sampling and analysing coal spoil are reviewed and reclamation and after-use techniques are summarized. Although most research on this subject has been completed by applied ecologists and biologists, the relevance and interest of the topic to biogeographers should not be overlooked.