The building blocks of continental crust: Evidence for a major change in the tectonic setting of continental growth at the end of the Archean

Oceanic arcs are commonly cited as primary building blocks of continents, yet modern oceanic arcs are mostly subducted. Also, lithosphere buoyancy considerations show that oceanic arcs (even those with a felsic component) should readily subduct. With the exception of the Arabian–Nubian orogen, terranes in post-Archean accretionary orogens comprise < 10% of accreted oceanic arcs, whereas continental arcs compose 40–80% of these orogens. Nd and Hf isotopic data suggest that accretionary orogens include 40–65% juvenile crustal components, with most of these (> 50%) produced in continental arcs.Felsic igneous rocks in oceanic arcs are depleted in incompatible elements compared to average continental crust and to felsic igneous rocks from continental arcs. They have lower Th/Yb, Nb/Yb, Sr/Y and La/Yb ratios, reflecting shallow mantle sources in which garnet did not exist in the restite during melting. The bottom line of these geochemical differences is that post-Archean continental crust does not begin life in oceanic arcs. On the other hand, the remarkable similarity of incompatible element distributions in granitoids and felsic volcanics from continental arcs is consistent with continental crust being produced in continental arcs.During the Archean, however, oceanic arcs may have been thicker due to higher degrees of melting in the mantle, and oceanic lithosphere would be more buoyant. These arcs may have accreted to each other and to oceanic plateaus, a process that eventually led to the production of Archean continental crust. After the Archean, oceanic crust was thinner due to cooling of the mantle and less melt production at ocean ridges, hence, oceanic lithosphere is more subductable. Widespread propagation of plate tectonics in the late Archean may have led not only to rapid production of continental crust, but to a change in the primary site of production of continental crust, from accreted oceanic arcs and oceanic plateaus in the Archean to primarily continental arcs thereafter.     

The relationship of Irgarol and its major metabolite to resident phytoplankton communities in a Maryland marina, river and reference area

The objectives of this study were to: (1) measure water column concentrations of Irgarol 1051 and its major metabolite GS26575 annually (2004-2006) during mid-June and mid-August at 14 sites in a study area comprised of three sub-regions chosen to reflect a gradient in Irgarol exposure (Port Annapolis marina, Severn River and Severn River reference area); (2) use a probabilistic approach to determine ecological risk of Irgarol and its major metabolite in the study area by comparing the distribution of exposure data with toxicity-effects endpoints; and (3) measure both functional and structural resident phytoplankton parameters concurrently with Irgarol and metabolite concentrations to assess relationships and determine ecological risk at six selected sites in the three study areas described above. The three-year summer mean Irgarol concentrations by site clearly showed a gradient in concentrations with greater values in Back Creek (400-500 ng/L range), lower values in the Severn River sites near the confluence with Back Creek (generally values less than 100 ng/L) and still lower values (<10 ng/L) at the Severn River reference sites at the confluence with Chesapeake Bay. A similar spatial trend, but with much lower concentrations, was also reported for GS26575. The probability of exceeding the Irgarol plant 10th centile of 193 ng/L and the microcosm NOEC (323 ng/L) suggested high ecological risk from Irgarol exposure at Port Annapolis marina sites but much lower risk at the other sites. There were no statistically significant differences among the three site types (marina, river and reference) with all years combined or among years within a site type for the following functional and structural phytoplankton endpoints: algal biomass, gross photosynthesis, biomass normalized photosynthesis, chlorophyll a, chlorophyll a normalized photosynthesis and taxa richness. Therefore, based on the above results, Irgarol adverse effects predicted from the plant 10th centile and the microcosm NOEC in the high Irgarol exposure area (Back Creek/Port Annapolis marina) were not confirmed with the actual field data for the receptor species (phytoplankton). These results also highlight the importance of unconfined field studies with a chemical gradient in providing valuable information regarding the responses of resident phytoplankton to herbicides.     

A local model for analysis of pump and treat systems with vertical barrier walls

We present a mathematical model of local, steady groundwater flow near a vertical barrier wall. Flow features represented in the model include an impermeable arc-shaped barrier wall and multiple wells; distant boundary conditions are not included explicitly, but their effects on the local flow field are modelled by specifying a uniform flow at infinity and a constant areal recharge within a local domain. We develop an explicit closed-form solution to the boundary-value problem using the analytic element method. The solution is an extension of a harmonic solution presented by Anderson and Mesa [Anderson EI, Mesa E. The effects of vertical barrier walls on the hydraulic control of contaminated groundwater. Adv Water Resourc 2006;29(1):89–98] which does not include the effects of recharge. We demonstrate that the general solution with recharge consists of the harmonic solution superposed on a special case of the harmonic solution along with two elementary one-dimensional flow solutions. The results are used to investigate the effects of areal recharge on the capture zone envelopes of the pumping wells and on the reduction in discharge that can be achieved by including a barrier wall in a pump and treat design. We find that the benefits of including an open barrier wall in a design, measured as a reduction in the pumping rate required to contain a plume, increase for higher recharge rates. Dimensionless plots of capture zone envelopes are presented for a practical well and barrier wall configuration.     

Using amphibole phenocrysts to track vapor transfer during magma crystallization and transport: An example from Mount St. Helens,Washington

In order to evaluate and further constrain models for volatile movement and vapor enrichment of magma stored at shallow levels, amphibole phenocrysts from 2004–2005 Mount St. Helens dacite were analyzed for major and selected trace elements (Li, Cu, Zn, Mn, and REE) and Li isotopes. Several recent studies have examined fluid-mobile trace element abundances in phencryst phases and melt inclusions as a means of tracking volatile movement within subvolcanic magmatic systems, and high Li contents in plagioclase phenocrysts from 1980 and 2004 Mount St. Helens dacites have been interpreted as evidence that shallow magma was fluxed by a Li-bearing vapor phase prior to eruption.     

The thermospheric semiannual density response to solar EUV heating

The goal of this study was to characterize the thermospheric semiannual density response to solar heating during the last 35 years. Historical radar observational data have been processed with special orbit perturbations on 28 satellites with perigee heights ranging from 200 to 1100 km. Approximately 225,000 very accurate average daily density values at perigee have been obtained for all satellites using orbit energy dissipation rates. The semiannual variation has been found to be extremely variable from year to year. The magnitude of the maximum yearly difference, from the July minimum to the October maximum, is used to characterize the yearly semiannual variability. It has been found that this maximum difference can vary by as much as 100% from one year to the next. A high correlation has been found between this maximum difference and solar EUV data. The semiannual variation for each year has been characterized based on analyses of annual and semiannual cycles, using Fourier analysis, and equations have been developed to characterize this yearly variability. The use of new solar indices in the EUV and FUV wavelengths is shown to very accurately describe the semiannual July minimum phase shifting and the variations in the observed yearly semiannual amplitude.     

Recent water quality trends and a comparison to sediment-core records for two riverine lakes of the Upper Mississippi River basin: Lake St. Croix and Lake Pepin

Long-term water quality monitoring data from two riverine lakes in the Upper Mississippi River basin, Lakes St. Croix and Pepin, were analyzed to compare the long-term average water quality conditions and land use distributions, water quality trends and loads at lake inlets and outlets, trends from long-term versus short-term monitoring records, and the ability of paleolimnological cores to accurately infer lake water quality conditions. During the 1976–2004 period, the long-term average concentrations of nutrients, suspended solids, and chlorophyll-a were consistently lower at the Lake St. Croix inlet versus the Lake Pepin inlet, which drains a greater proportion of urban and agricultural runoff. Despite these differences, nutrient trends were similar at the inlets to both lakes; reductions in total phosphorus and ammonium concentrations were attributed to improvements in point source technologies, whereas increasing nitrate concentrations were attributed to both point source changes and nonpoint source increases. Despite improvements in several water quality variables, nitrate concentrations are increasing in both lakes, sediment trends indicate persistent nonpoint source inputs to Lake Pepin, and current total phosphorus concentrations remain well above pre-1950s levels in both lakes. Since urban development and agriculture are increasing in the Lake St. Croix and Lake Pepin Watersheds, continued point source regulation and additional nonpoint source control efforts will be needed to further improve water quality in these lakes. The 1976–2004 trends for most water quality variables were similar at inlet versus outlet sites on Lake St. Croix. Trends at Lake Pepin inlet versus outlet sites were less similar, but data availability limited the comparison to the 1993–2003 period. While the truncated data record highlighted short-term trends in both lakes, the full data record was most useful for exploring general patterns in water quality. Length of monitoring record affected our ability to detect trends at the inlets to both lakes, and altered the magnitude of detected trends. During the two decades of the 1980s and 1990s, paleolimnological estimates of retained phosphorus loads were similar to those estimated from recent water quality monitoring. These similarities support the use of paleolimnological approaches to infer past water quality conditions in Lakes St. Croix and Pepin. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

Times of sand: Sedimentary history and archaeology at the Sigatoka Dunes,Fiji

The orthodox archaeological sequence at the Sigatoka Dunes site (VL 16/1) in Fiji proposes three phases of occupation spanning Fijian prehistory, each associated with a period of dune stability. It has been taken as the standard model of Fijian prehistory for more than 30 years. Recently, however, it has been argued that there is no stratigraphic support for three discrete levels and that the occupation history was fragmented, complex, and continuous within a volatile dune system. We present new data, from optical and radiocarbon dating, to argue that a three‐phase model, although somewhat more complex in detail, remains the most robust interpretation of site history. The longest stable phase (Level 2) began 2500–2300 cal yr B.P. and is possibly associated with relatively low ENSO frequency. Substantial sand dune accumulation began after ˜1300 cal yr B.P. © 2006 Wiley Periodicals, Inc.     

The Sloan Digital Sky Survey monitor telescope pipeline

The photometric calibration of the Sloan Digital Sky Survey (SDSS) is a multi‐step process which involves data from three different telescopes: the 1.0‐m telescope at the US Naval Observatory (USNO), Flagstaff Station, Arizona (which was used to establish the SDSS standard star network); the SDSS 0.5‐m Photometric Telescope (PT) at the Apache Point Observatory (APO), NewMexico (which calculates nightly extinctions and calibrates secondary patch transfer fields); and the SDSS 2.5‐m telescope at APO (which obtains the imaging data for the SDSS proper). In this paper, we describe the Monitor Telescope Pipeline, MTPIPE, the software pipeline used in processing the data from the single‐CCD telescopes used in the photometric calibration of the SDSS (i.e., the USNO 1.0‐m and the PT). We also describe transformation equations that convert photometry on the USNO‐1.0m u ′g ′r ′i ′z ′ system to photometry the SDSS 2.5m ugriz system and the results of various validation tests of the MTPIPE software. Further, we discuss the semi‐automated PT factory, which runs MTPIPE in the day‐to‐day standard SDSS operations at Fermilab. Finally, we discuss the use of MTPIPE in current SDSS‐related projects, including the Southern u ′g ′r ′i ′z ′ Standard Star project, the u ′g ′r ′i ′z ′ Open Star Clusters project, and the SDSS extension (SDSS‐II). (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)