Strong variation in weathering of layered rock maintains hillslope‐scale strength under high precipitation

The evolution of volcanic landscapes and their landslide potential are both dependent upon the weathering of layered volcanic rock sequences. We characterize critical zone structure using shallow seismic V_p and V_s profiles and vertical exposures of rock across a basaltic climosequence on Kohala peninsula, Hawai’i, and exploit the dramatic gradient in mean annual precipitation (MAP) across the peninsula as a proxy for weathering intensity. Seismic velocity increases rapidly with depth and the velocity–depth gradient is uniform across three sites with 500–600 mm/yr MAP, where the transition to unaltered bedrock occurs at a depth of 4 to 10 m. In contrast, velocity increases with depth less rapidly at wetter sites, but this gradient remains constant across increasing MAP from 1000 to 3000 mm/yr and the transition to unaltered bedrock is near the maximum depth of investigation (15–25 m). In detail, the profiles of seismic velocity and of weathering at wet sites are nowhere monotonic functions of depth. The uniform average velocity gradient and the greater depths of low velocities may be explained by the averaging of velocities over intercalated highly weathered sites with less weathered layers at sites where MAP > 1000 mm/yr. Hence, the main effect of climate is not the progressive deepening of a near‐surface altered layer, but rather the rapid weathering of high permeability zones within rock subjected to precipitation greater than ~1000 mm/yr. Although weathering suggests mechanical weakening, the nearly horizontal orientation of alternating weathered and unweathered horizons with respect to topography also plays a role in the slope stability of these heterogeneous rock masses. We speculate that where steep, rapidly evolving hillslopes exist, the sub‐horizontal orientation of weak/strong horizons allows such sites to remain nearly as strong as their less weathered counterparts at drier sites, as is exemplified by the 50°–60° slopes maintained in the amphitheater canyons on the northwest flank of the island. Copyright © 2017 John Wiley & Sons, Ltd.     

Long-Term Evaluation of Mulch Biowall Performance to Treat Chlorinated Solvents

Permeable reactive barriers (PRBs), such as mulch biowalls, have been installed at numerous groundwater cleanup sites, and laboratory and field studies have demonstrated biotic and abiotic processes that degrade chlorinated volatile organic compounds (CVOCs) in groundwater passing through these engineered remedies. However, the longevity of mulch biowalls remains a fundamental research question. Soil and groundwater sampling at seven mulch biowalls at Altus Air Force Base (AFB) approximately 10 years after installation demonstrated the ongoing degradation of CVOCs. Trichloroethene was not detected in five of seven groundwater samples collected from the biowall despite upgradient detections above federal drinking water standards. Microbial sampling established the presence of key dechlorinating bacteria and the abundance of genes encoding specific enzymes for degradation, high methane concentrations, low sulfate concentrations, and negative oxidation-reduction potential, all indicative of highly reducing conditions within the biowalls and favorable conditions for CVOC destruction via microbial reductive dechlorination. High cellulose content (>79%) of the mulch, elevated total organic carbon (TOC) content in groundwater, and elevated potentially bioavailable organic carbon (PBOC) measurements in soil samples further supports an ongoing, long-lived source of carbon. These results demonstrate the ongoing and long-term efficacy of the mulch biowalls at Altus AFB. In addition, concentrations of bacteria, TOC, PBOC, and other geochemical parameters suggest a modest impact of the biowalls downgradient. The continued presence of CVOCs downgradient may be attributable to back diffusion from low-permeability shale. However, the biowalls continue to provide benefits by removing CVOCs in groundwater, thus reducing further CVOC loading to the downgradient, low-permeability strata.     

Field Demonstration of the Horizontal Treatment Well (HRX Well®) for Passive In Situ Remediation

The horizontal reactive media treatment well (HRX Well®) uses directionally drilled horizontal wells filled with a treatment media to induce flow-focusing behavior created by the well-to-aquifer permeability contrast to passively capture proportionally large volumes of groundwater. Groundwater is treated in situ as it flows through the HRX Well and downgradient portions of the aquifer are cleaned via elution as these zones are flushed with clean water discharging from the HRX Well. The HRX Well concept is particularly well suited for sites where long-term mass discharge control is a primary performance objective. This concept is appropriate for recalcitrant and difficult-to-treat constituents, including chlorinated solvents, per- and polyfluoroalkyl substances (PFAS), 1,4-dioxane, and metals. A full-scale HRX Well was installed and operated to treat trichloroethene (TCE) with zero valent iron (ZVI). The model-predicted enhanced flow through the HRX Well (compared to the flow in and equivalent cross-sectional area orthogonal to flow in the natural formation before HRX Well installation) and treatment zone width was consistent with flows and widths estimated independently by point velocity probe (PVP) testing, HRX Well tracer testing, and observed treatment in downgradient monitoring wells. The actual average capture zone width was estimated to be between 45 and 69 feet. Total TCE mass discharge reduction was maintained through the duration of the performance monitoring period and exceeded 99.99% (%). Decreases in TCE concentrations were observed at all four downgradient monitoring wells within the treatment zone (ranging from 50 to 74% at day 436), and the first arrival of treated water was consistent with model predictions. The field demonstration confirmed the HRX Well technology is best suited for long-term mass discharge control, can be installed under active infrastructure, requires limited ongoing operation and maintenance, and has low life cycle energy and water requirements.     

Modelling road surface sediment production using a vector geographic information system

Field investigations indicate that unpaved roads are the largest sediment source on St John, US Virgin Islands. Cross-sectional measurements of eroded road surfaces were used to establish an empirical relationship to predict annual road surface erosion as a function of road gradient and contributing drainage area. A model (ROADMOD) for estimating and mapping average annual sediment production from a road network was developed by combining this empirical relationship with a series of network algorithms to analyse road data stored in a vector geographic information system. ROADMOD was used to estimate road surface erosion in two St John catchments with very different road densities but similar land cover, topography and soils. Unpaved roads were found to increase sediment production in the more densely roaded catchment by a factor of three to eight, and in the less-roaded catchment by a factor of 1·3–2·0. Turbidity measurements in the receiving bays of these two catchments are consistent with model predictions and observed sediment delivery processes. Although this model was developed specifically for St John, it can easily be adapted to other locations by substituting a locally derived predictive equation for road erosion. Model assumptions, limitations and potential improvements are discussed. © 1998 John Wiley & Sons, Ltd.     

A groundwater salinity hotspot and its connection to an intermittent stream identified by environmental tracers (Mt Lofty Ranges,South Australia)

High and variable levels of salinity were investigated in an intermittent stream in a high-rainfall area (～800 mm/year) of the Mt. Lofty Ranges of South Australia. The groundwater system was found to have a local, upslope saline lens, referred to here as a groundwater salinity ‘hotspot’. Environmental tracer analyses (δ¹⁸O, δ²H, ^87/86Sr, and major elements) of water from the intermittent stream, a nearby permanent stream, shallow and deep groundwater, and soil-water/runoff demonstrate seasonal groundwater input of very saline composition into the intermittent stream. This input results in large salinity increases of the stream water because the winter wet-season stream flow decreases during spring in this Mediterranean climate. Furthermore, strontium and water isotope analyses demonstrate: (1) the upslope-saline-groundwater zone (hotspot) mixes with the dominant groundwater system, (2) the intermittent-stream water is a mixture of soil-water/runoff and the upslope saline groundwater, and (3) the upslope-saline-groundwater zone results from the flushing of unsaturated-zone salts from the thick clayey regolith and soil which overlie the metamorphosed shale bedrock. The preferred theory on the origin of the upslope-saline-groundwater hotspot is land clearing of native deep-rooted woodland, followed by flushing of accumulated salts from the unsaturated zone due to increased recharge. This cause of elevated groundwater and surface-water salinity, if correct, could be widespread in Mt. Lofty Ranges areas, as well as other climatically and geologically similar areas with comparable hydrogeologic conditions.     

Comparing flow regime,channel hydraulics,and biological communities to infer flow–ecology relationships in the Mara River of Kenya and Tanzania

Abstract

Equatorial rivers of East Africa exhibit unusually complex seasonal and inter-annual flow regimes, and aquatic and adjacent terrestrial organisms have adapted to cope with this flow variability. This study examined the annual flow regime over the past 40 years for three gauging stations on the Mara River in Kenya and Tanzania, which is of international importance because it is the only perennial river traversing the Mara-Serengeti ecoregion. Select environmental flow components were quantified and converted to ecologically relevant hydraulic variables. Vegetation, macroinvertebrates, and fish were collected and identified at target study sites during low and high flows. The results were compared with available knowledge of the life histories and flow sensitivities of the riverine communities to infer flow–ecology relationships. Management implications are discussed, including the need to preserve a dynamic environmental flow regime to protect ecosystems in the region. The results for the Mara may serve as a useful model for river basins of the wider equatorial East Africa region.

Editor Z.W. Kundzewicz; Guest editor M. Acreman     

The dayside magnetospheric boundary layer at Mercury

Magnetic field and plasma data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft on the outbound portions of the first (M1) and second (M2) flybys of Mercury reveal a region of depressed magnetic field magnitude and enhanced proton fluxes adjacent to but within the magnetopause, which we denote as a dayside boundary layer. The layer was present during both encounters despite the contrasting dayside magnetic reconnection, which was minimal during M1 and strong during M2. The overall width of the layer is estimated to be between 1000 and 1400 km, spanning most of the distance from the dayside planetary surface to the magnetopause in the mid-morning. During both flybys the magnetic pressure decrease was ∼1.6 nPa, and the width of the inner edge was comparable to proton gyro-kinetic scales. The maximum variance in the magnetic field across the inner edge was aligned with the magnetic field vector, and the magnetic field direction did not change markedly, indicating that the change in field intensity was consistent with an outward plasma-pressure gradient perpendicular to the magnetic field. Proton pressures in the layer inferred from reduced distribution observations were 0.4 nPa during M1 and 1.0 nPa during M2, indicating either that the proton pressure estimates are low or that heavy ions contribute substantially to the boundary-layer plasma pressure. If the layer is formed by protons drifting westward from the cusp, there should be a strong morning–afternoon asymmetry that is independent of the interplanetary magnetic field (IMF) direction. Conversely, if heavy ions play a major role, the layer should be strong in the morning (afternoon) for northward (southward) IMF. Future MESSENGER observations from orbit about Mercury should distinguish between these two possibilities.     

The morphology and hydrology of small spring-dominated channels

Small, low order channels located in wet meadows along the Mogollon Rim of northern Arizona that receive the bulk of their flow from spring discharge exhibit a morphology that differs markedly from channels that receive the bulk of their flow from runoff. These small, spring-dominated channels generally have dense vegetation cover, vertical (or near vertical) banks with flat channel beds that are armored with clasts up to 60 mm. Clasts armoring the spring-dominated channels become mobile at 45 to 85% of the bankfull depth. The lack of fine-grained material in the bed of the spring-dominated channels reflects the small drainage size, lack of fine grain input from the spring, and winnowing affect of the consistent discharge. Minor amounts of large woody debris were present in some of the spring-dominated channels, however, unlike previous studies it does not appear to play a role in the spring-dominated channel morphology. Sinuosity values for spring-dominated channels averaged 1.19, while the average sinuosity values for the runoff-dominated channels, 1.08, were significantly lower. Measured width-to-depth ratios averaged 2.4 in the spring-dominated channels, much lower than the average ratio of 11.6 found for the runoff-dominated channels. The standard deviation of width-to-depth ratios was higher for runoff-dominated channels, reflecting a more variable channel profile. A third channel type, here referred to as hybrid channels, receive significant flow from both springs and runoff. These channels have characteristics that fall between spring-dominated and runoff-dominated channels.Elevation, gradient, organic matter content, and sediment grain size distribution of the wet meadows in which the channels are formed do not exhibit significant differences between channel types, suggesting that these factors are not responsible for the observed differences in channel morphologies. The major differences in controls on the channel morphology found between the spring-dominated and runoff-dominated channels are the discharge regime and the sediment input. The hydrology unique to the spring-dominated channels and the lack of fine-grained sediment input combine to create the observed differences.