Distribution of hydrate on Europa: Further evidence for sulfuric acid hydrate

Sulfuric acid hydrate has been proposed as an important species on Europa's surface, the acid being produced by radiolysis of surficial sulfur compounds. We investigated the spectral properties of disordered and crystalline forms of sulfuric acid and suggest that the hydration properties of Europa's hypothesized sulfuric acid lie between two end members: liquid sulfuric acid and its higher crystalline hydrates. The spectra of these end members are similar except for spectral shifts at the band edges. We measured the optical constants of sulfuric acid octahydrate and used these with simple radiative transfer calculations to fit Europa spectra obtained by Galileo's Near Infrared Mapping Spectrometer (NIMS). The global distribution of the hydrate that we associate here with hydrated sulfuric acid shows a strong trailing-side enhancement with a maximum fractional hydrate abundance of 90% by volume, corresponding to a sulfur atom to water molecule ratio of 10%. The hydrate concentration spatially correlates with the ultraviolet and visible absorption of the surface and with the sulfur dioxide concentration. The asymmetric global distribution is consistent with Iogenic plasma ion implantation as the source of the sulfur, possibly modified by electron irradiation and sputtering effects. The variegated distribution also correlates with geologic forms. A high spatial resolution image shows resolved lineae with less hydrate appearing within the lineae than in nearby crustal material. The low concentration of hydrated material in these lineae argues against their conveying sulfurous material to the surface from the putative ocean.     

Origin of the Archean Earth impactors

A survey of current near-Earth asteroids and inner solar system comets suggests C class asteroids may have been the impactors during the Archean period resulting in the formation of spherule beds because of their carbonaceous composition and large diameters.     

Spatial pattern of recent sediment and diatom accumulation in a small,monomictic, eutrophic lake

Spatial variability of sediment and diatom deposition was assessed in a small monomictic, eutrophic lake in Northern Ireland (Lough Augher, Co. Tyrone) using measurements from 17 sediment cores. Loss-onignition profiles in water depths >6 m showed good repeatability, while littoral cores were more variable with localised profiles. Dry mass accumulation rates, derived by biostratigraphic correlation to a ²¹⁰Pb dated master core, were variable and not correlated with water depth. Basin mean dry mass accumulation rate was 0.068 g cm^-2 yr^-1 (range 0.036–0.09) prior to 1900, and 0.19 g cm^-2 yr^-1 (range 0.11–0.3) after 1974. Post-1940 cumulative fluxes were estimated for dry mass (range 3.49–916 g cm^-2) and diatoms (range 16.9–113.8×10⁷ frustules cm^-2). Cumulative dry mass was inversely correlated (r=–0.64) with distance from the inflow, indicating its localised influence. No variable was correlated with water depth except frustules of planktonic diatoms (r=0.66). However, high cumulative fluxes of diatoms and dry mass away from the inflow suggest that the expansion of the littoral macrophyte community may be responsible for decreased resuspension in shallow water, and together with increased sediment trapping, has enhanced sediment accumulation in shallow water over recent time periods.     

The troposphere-stratosphere radiation field at twilight: A spherical model

Time-dependent calculations of trace constituent distributions require as input the dissociating radiation field as a function of altitude and solar zenith angle. An isotropic, spherical, multiple scattering model of the radiation field has been developed to determine the radiation field at twilight. Comparison of the spherical model with a plane parallel model at twilight shows that: (1) for solar zenith angles less than 92°, plane parallel solutions for the source function are suitable if the initial deposition of solar energy is calculated for a spherical atmosphere; (2) for solar zenith angles greater than 92°, the plane parallel radiation field can be several orders of magnitude smaller than that calculated with the spherical model; (3) at altitudes above 40 km and at all solar zenith angles, the spherical model predicts 10–20% less radiation than the radiation field calculated with the plane parallel model. Calculations of the rate of photodissociation of NO₂ in the troposphere and stratosphere show that the spherical model yields significantly higher values at solar zenith angles greater than 92°.     

Forecasting off-road trafficability

Forecasting off-road trafficability represents an interesting problem in the earth science field, since variables ranging from solar insolation to soil shear strength are involved. However, existing trafficability models do not include precipitation-soil moisture deterministic submodels. Instead, they frequently commence with soil moisture and invoke empirical relationships to predict trafficability. This investigation couples a deterministic soil moisture submodel to a principal empirical soil moisture-trafficability model. Sensitivity analysis shows the impact cloud cover, as well as other variables, can have on the trafficability of three soil types, and the complexity of the post-storm trafficability response.     

Road-cut slope topography and stability relationships in St Lucia,West Indies

Slope topography is shown to be a significant factor in controlling the porewater pressures in road-cut slopes in the residual volcanic soils of St Lucia, West Indies. It is shown that this control diminishes as the permeability of the material decreases. This finding is confirmed by stability envelopes in which ‘stable’ and failed slopes are examined as a function of slope topography and material properties.     

Linear and planar structure in ordered multivariate data as applied to progressive demagnetization of palaeomagnetic remanence

Summary. Consider a sequence of, say, 10 to 20 vector observations in three-dimensional space. It is suspected that a few subsets of consecutive observations are made up of collinear points. The purpose of this paper is to construct a statistically based algorithm to find such linear segments and to assess their accuracy. A similar assessment is made for coplanar sets of points.
This algorithm is applied here to palaeomagnetic data and is claimed to be superior to previous methods of palaeomagnetic analysis in terms of completeness and balance of analysis, treatment of measurement errors and other sources of scatter, criteria for identification of linear and planar sets of points, and statistical rigour. Stability spectra, with statistically based confidence limits, are obtained as a by-product.     

THE CANYONLANDS METEORITE

The Canyonlands meteorite weighing 1,520 grams was found near the confluence of the Green and Colorado Rivers, Utah, near lat 38°11′N.; long 109°53′W. It is a shocked, brecciated H6 chondrite containing large black veins which do not differ in composition from the main chondritic mass. A black fusion crust remains on part of the meteorite.