An empirical test of helium diffusion in apatite: borehole data from the Otway basin, Australia

We have analyzed helium ages of apatites from several boreholes in the Otway basin, Australia, to evaluate whether laboratory helium diffusivity can be accurately extrapolated to conditions relevant in nature. Downhole apatite helium ages define a broad swath of values from 78–71 Ma at the surface (15°C) to nearly zero at depths corresponding to ambient temperatures of 80°C. The width of the swath results from uncertainties in corrected borehole temperatures, differences in the thermal history experienced by the various boreholes, and possibly from slightly different helium diffusivities among the detrital apatite grains studied. In the eastern Otway basin, the shape and position of the helium age profile is in good agreement with predictions based on the extrapolation of laboratory diffusivity data for Durango apatite coupled with published thermal histories for this part of the basin. In contrast, helium ages are much younger than predicted in the western Otway basin. Based on measured ages from Otway sediments, which have been essentially isothermal over the last few million years, an empirical diffusivity (D/a²) of 2×10⁻¹⁵ s⁻¹ can be assigned to apatites residing at downhole temperatures of 67–97°C. This empirical diffusivity is consistent with laboratory diffusion measurements, demonstrating that such measurements are reasonably accurate and can be applied with confidence to natural geologic settings. Given this confirmation of the laboratory diffusivity data, the discrepancy between the observed and modeled helium age profiles in the western Otway basin suggests that these sediments recently experienced higher temperatures than presently supposed.     

The hypothetical chemical and spectroscopic activity of Germane in the atmosphere of Jupiter

It is suggested that in a reducing environment such as the Jovian atmosphere, GeH₄ may be spectroscopically active. Absorption features might be detectable in the 4.7μ window in the Jovian upper atmosphere.     

Photoelectric photometry of asteroids 9 Metis, 18 Melpomene, 60 Echo, 116 Sirona, 230 Athamantis, 694 Ekard,and 1984 KD

Photoelectric observations of seven asteroids were made from Gila Observatory between October 14, 1983, and June 21, 1984. The following synodic rotational periods and amplitudes are reported: 9 Metis, P = 5.04 hr, ΔM = 0.05; 18 Melpomene, P = 11.570 hr, ΔM = 0.22; 60 Echo, P = 25.208 hr, ΔM = 0.22; 116 Sirona, P = 12.028 hr, ΔM = 0.42; 230 Athamantis, P = 23.99 hr, ΔM > 0.20; 694 Ekard, P = 5.925 hr, ΔM = 0.50; 1984 KD, P = 1.97 hr, ΔM = 0.26. The rotational periods reported for asteroid 60 Echo, 116 Sirona, 694 Ekard, and 1984 KD represent completely new results. The synodic rotational period reported for asteroid 1984 KD is tentative and is based largely upon the observations of a single night. The reported synodic periods of the remaining six asteroids are based upon a minimum of 3 nights of photometric observations.     

Some newly discovered coronal emission lines from high altitude infrared observations of the 7 March, 1970, solar eclipse

A survey of the infrared coronal spectrum between 1 and 3 was made from a high altitude aircraft during the 7 March, 1970, solar eclipse. The observations were made with a Fourier transform spectrometer and were confined to the outer chromosphere and inner corona. In addition to well known chromospheric lines of Hi and Hei, nine additional lines were seen. Evidence is presented for the tentative assignment of these lines to forbidden transitions in highly ionized atoms of magnesium, aluminum, silicon, sulphur, and chromium.     

The activity of NaCl in seawater of 10–40‰ salinity and 5–25°C at 1 atmosphere

The activity of NaCl in artificial seawater was measured potentiometrically with Na⁺- and Cl^? -sensitive electrodes. The salinity of the solutions, examined at 25°C, ranged from 10–40‰ salinity. The change in the activity from 5–25°C was measured at 35‰ salinity.The molal mean activity coefficient of NaCl in 35‰ seawater at 25°C is 0.667. The relative partial molal enthalpy of NaCl in 35‰ seawater is ?130 ±50 cal mol^?1. This value is in good agreement with the value measured in pure 0.72 M NaCl.The results were compared with activity coefficients predicted by a specific interaction model and by an ion association model. Good agreement was found in both cases.