Alteration processes recorded by back-arc mantle peridotites from oceanic core complexes,Shikoku Basin,Philippine Sea

We determined the mineralogical and petrological characteristics of ultramafic rocks dredged from two oceanic core complexes: the Mado Megamullion and 23°30′N non-transform offset massif, which are located within the Shikoku back-arc basin in the Philippine Sea. The ultramafic rocks are strongly serpentinized, but can be classified as harzburgite/lherzolite or dunite, based on relict primary minerals and their pseudomorphs. Strongly elongated pyroxene porphyroclasts with undulatory extinction indicate high-temperature (≥700 °C) strain localization on a detachment fault within the upper mantle at depths below the brittle–viscous transition. During exhumation, the peridotites underwent impregnation by magmatic or hydrothermal fluids, lizardite/chrysotile serpentinization at ≤300 °C, antigorite crystallization, and silica metasomatism that formed talc. These features indicate that the detachment fault zones formed a fluid pathway and facilitated a range of fluid–peridotite interactions.     

Laboratory experiments and thermal calculations for the development of a next-generation glacier-ice exploration system: Development of an electro-thermal drilling device

A next-generation drilling system, equipped with a thermal drilling device, is proposed for glacier ice. The system is designed to penetrate glacier ice via melting of the ice and continuously analyze melt-water in a contamination-free sonde. This new type of drilling system is expected to provide analysis data in less time and at less cost than existing systems. Because of the limited number of parameters that can be measured, the proposed system will not take the place of conventional drilling systems that are used to obtain ice cores; however, it will provide a useful method for quickly and simply investigating glacier ice.An electro-thermal drilling device is one of the most important elements needed to develop the proposed system. To estimate the thermal supply required to reach a target depth in a reasonable time, laboratory experiments were conducted using ice blocks and a small sonde equipped solely with heaters. Thermal calculations were then performed under a limited range of conditions. The experiments were undertaken to investigate the effects of the shape and material of the drill head and heater temperature on the rate of penetration into the ice. Additional thermal calculations were then performed based on the experimental results.According to the simple thermal calculations, if the thermal loss that occurs while heat is transferred from the heater to ice (in melting the ice) is assumed to be 50%, the total thermal supply required for heaters in the sonde and cable is as follows: (i) 4.8 kW (sonde) plus 0 W (cable) to penetrate to 300 m depth over 10 days into temperate glacier ice for which the temperature is 0 °C at all depths and to maintain a water layer along 300 m of cable; (ii) 10 kW (sonde) plus 19–32 kW (cable) to penetrate to 1000 m depth over 1 month into cold glacier ice for which the temperature is −25 °C at the surface and 0 °C at 1000 m depth and to maintain a water layer along 1000 m of cable; and (iii) 19 kW (sonde) plus 140–235 kW (cable) to penetrate to 3000 m depth over 2 months into an ice sheet for which the temperature is −55 °C at the surface and 0 °C at 3000 m depth and to maintain a water layer along 3000 m of cable. The thermal supply required for the cable is strongly affected by the thickness of the water layer, cable diameter, and the horizontal distance from the ice wall at which the ice temperature was maintained at its initial temperature. A large thermal supply is required to heat 3000 m of cable in an ice sheet (scenario (iii) above), but penetration into glacier ice (scenarios (i) and (ii) above) could be realistic with the use of a currently employed generator.     

Chlorophyll distribution and photosynthetic activity in the north and equatorial Pacific Ocean along 155°W

The distribution of chlorophylla and photosynthetic characterestics of phytoplankters were investigated along 155°W between 50°N and 15°S during the KH-69-4 cruise of the R. V. Hakuh Maru (Aug. 12–Nov. 13, 1969). High concentrations of chlorophylla (more than 0.2 mg Chla/m³) were observed above the depths of 150 m at all stations except in 17°N, 5°S and 15°S. North of 20°N, the depths of chlorophyll accumulation shifted from near the surface to 50–100 m with southwards. In the equatorial region, chlorophyll accumulation centered at a depth of about 70 m and ranged vertically between 10 and 150 m. In all cases in the present study area, chlorophyll accumulation occurred within the euphotic zone (above the depth corresponding to 1% of the surface illumination), and except in the subarctic and some equatorial waters, this was usually prevalent in the lower half of the euphotic zone.The photosynthetic activities (initial slope of P vs I curve) of samples from the depths of chlorophyll accumulation were similar to, or lower than, those of shallow samples from the depths of upper half of the euphotic zone. At the depths of chlorophyll accumulation, calculatedin situ photosynthesis was high in the central Pacific and equatorial waters but low in the subarctic waters.     

Two-Dimensional Variational Analysis of Near-Surface Moisture from Simulated Radar Refractivity-Related Phase Change Observations

Because they are most sensitive to atmospheric moisture content, radar refractivity observations can provide high-resolution information about the highly variable low-level moisture field. In this study, simulated radar refractivity-related phase-change data were created using a radar simulator from realistic highresolution model simulation data for a dryline case. These data were analyzed using the 2DVAR system developed specifically for the phase-change data. Two sets of experiments with the simulated observations were performed, one assuming a uniform target spacing of 250 m and one assuming nonuniform spacing between 250 m to 4 km. Several sources of observation error were considered, and their impacts were examined. They included errors due to ground target position uncertainty, typical random errors associated with radar measurements, and gross error due to phase wrapping. Without any additional information, the 2DVAR system was incapable of dealing with phase-wrapped data directly. When there was no phase wrapping in the data, the 2DVAR produced excellent analyses, even in the presence of both position uncertainty and random radar measurement errors. When a separate pre-processing step was applied to unwrap the phase-wrapped data, quality moisture analyses were again obtained, although the analyses were smoother due to the reduced effective resolution of the observations by interpolation and smoothing involved in the unwrapping procedure. The unwrapping procedure was effective even when significant differences existed between the analyzed state and the state at a reference time. The results affirm the promise of using radar refractivity phase-change measurements for near-surface moisture analysis.     

Compressibility of strontium orthophosphate Sr<Subscript>3</Subscript>(PO<Subscript>4</Subscript>)<Subscript>2</Subscript> at high pressure

High pressure in situ synchrotron X-ray diffraction experiment of strontium orthophosphate Sr₃(PO₄)₂ has been carried out to 20.0 GPa at room temperature using multianvil apparatus. Fitting a third-order Birch–Murnaghan equation of state to the P–V data yields a volume of V ₀ = 498.0 ± 0.1 Å³, an isothermal bulk modulus of K _T  = 89.5 ± 1.7 GPa, and first pressure derivative of K _T ′ = 6.57 ± 0.34. If K _T ′ is fixed at 4, K _T is obtained as 104.4 ± 1.2 GPa. Analysis of axial compressible modulus shows that the a-axis (K _a  = 79.6 ± 3.2 GPa) is more compressible than the c-axis (K _c  = 116.4 ± 4.3 GPa). Based on the high pressure Raman spectroscopic results, the mode Grüneisen parameters are determined and the average mode Grüneisen parameter of PO₄ vibrations of Sr₃(PO₄)₂ is calculated to be 0.30(2).     

Evaluation of Containment Performance from Viewpoints of Diffusion and Dispersion for Impervious Structures at Coastal Landfill Sites

The containment performance of impervious structures is considered the most important performance, which the toxic substances are enclosed in coastal landfill sites. The containment performance is evaluated generally by the hydraulic conductivity and the thickness of impervious structures to focus on an advection. However, the leakage of toxic substances is affected by a diffusion and a dispersion. The diffusion and the dispersion are considered to be easily distinguished on the impervious structure which has the low-hydraulic conductivity. Such phenomena should be considered due to evaluate the containment performance. This is because to improve the containment performance and comprehend leakage of the toxic substances. The containment performance is evaluated from the viewpoint of the diffusion and the dispersion in this research. Concretely, the influence which the toxic substances leaks from impervious structures on the diffusion and the dispersion is evaluated by the infiltration and advection–dispersion analysis on steel-made side impervious walls. In other word, The relation between the leaking amount of toxic substances and coefficient of molecular diffusion, the relation between the travel time or the flow velocity and the leaking amount and the change in the water-level difference are considered respectively. So, the leaking amount which is influenced by a diffusion and a dispersion is considered. Consideration about to secure the containment performance of impervious structure which is restrained leakage by a diffusion and a dispersion.     

Sedimentary serpentinite and chaotic units of the lower Great Valley Group forearc basin deposits,California: updates on distribution and characteristics

ABSTRACT

Sedimentary serpentinite and related siliciclastic-matrix mélanges in the latest Jurassic to Lower Cretaceous lower Great Valley Group (GVG) forearc basin strata of the California Coast Ranges reach thicknesses of over 1 km and include high-pressure (HP) metamorphic blocks. These units crop out over an area at least 300 km long by 50 km wide. The serpentinite also contains locally abundant blocks of antigorite mylonite. Antigorite mylonite and HP metamorphic blocks were exhumed from depth prior to deposition in the unmetamorphosed GVG, but the antigorite mylonite may be mistaken for metamorphosed serpentinite matrix in localities with limited exposure. These olistostrome horizons can be distinguished from intact slabs of serpentinized peridotite associated with the Coast Range Ophiolite (CRO) or serpentinite mélanges of the Franciscan subduction complex (FC) on the basis of internal sedimentary textures (absent in CRO), mixing/interbedding with unmetamorphosed siliciclastic matrix and blocks (differs from CRO and FC), and preserved basal sedimentary contacts over volcanic rocks of the CRO or shale, sandstone, and conglomerate of the GVG (differs from CRO and FC). Even in the relatively well-characterized Palaeo trench–forearc region of the California Coast Ranges the GVG deposits are difficult to distinguish from similar units in the FC and CRO. In typical orogenic belts that exhibit greater post-subduction disruption, distinguishing forearc basin olistostrome deposits, subduction complex, and opholite mantle sections is much more difficult. Forearc basin olistostromal deposits have probably been misidentified as one of the other trench–forearc lithologic associations. Such errors may lead to erroneous interpretations of the nature of large-scale material and fluid pathways in trench–forearc systems, as well as misinterpretations of tectonic processes associated with HP metamorphism and exhumation of the resultant rocks.     

Pressure dependence of electrical conductivity of (Mg,Fe)SiO<Subscript>3</Subscript> ilmenite

The electrical conductivity of (Mg_0.93Fe_0.07)SiO₃ ilmenite was measured at temperatures of 500–1,200 K and pressures of 25–35 GPa in a Kawai-type multi-anvil apparatus equipped with sintered diamond anvils. In order to verify the reliability of this study, the electrical conductivity of (Mg_0.93Fe_0.07)SiO₃ perovskite was also measured at temperatures of 500–1,400 K and pressures of 30–35 GPa. The pressure calibration was carried out using in situ X-ray diffraction of MgO as pressure marker. The oxidation conditions of the samples were controlled by the Fe disk. The activation energy at zero pressure and activation volume for ilmenite are 0.82(6) eV and −1.5(2) cm³/mol, respectively. Those for perovskite were 0.5(1) eV and −0.4(4) cm³/mol, respectively, which are in agreement with the experimental results reported previously. It is concluded that ilmenite conductivity has a large pressure dependence in the investigated P–T range.