Thermal effect of the sea breeze on the structure of the boundary layer and the heat budget over land

The daytime boundary-layer heating process and the air-land heat budget were investigated over the coastal sea-breeze region by means of observations over the Sendai plain in Japan during the summer. In this area, the onset of the sea breeze begins at the coast around 0900 LST, intruding about 35 km inland by late afternoon. The cold sea breeze creates a temperature difference of over 10°C between the coastal and inland areas in the afternoon. On the other hand, warm air advection due to the combination of the counter-sea breeze and land-to-sea synoptic wind occurs in the layer above the cold sea breeze in the coastal region. Owing to this local warm air advection, there is no significant difference in the daytime heating rate over the entire atmospheric boundary layer between the coastal and inland areas. The sensible heat flux from the land surface gradually decreases as distance from the coastline increases, being mainly attributed to the cold sea breeze. The daytime mean cold air advection due to the sea breeze is estimated asQ _adv ^local =–29 W m^–2 averaged over the sea breeze region (035 km from the coastline). This value is 17% of the surface sensible heat fluxH over the same region. The results of a two-dimensional numerical model show that the value ofQ _adv ^local /H is strongly affected by the upper-level synoptic wind direction. The absolute value ofQ _adv ^local /H becomes smaller when the synoptic wind has the opposite direction of the sea breeze. This condition occurred during the observations used in the present study.     

Comparison of extractability of Cd, Cu, Pb and Zn with sequential extraction in contaminated and non-contaminated soils

Various extraction procedures were employed for measuring extractable concentrations of potential toxic elements in soil. The extractability of Cd, Cu, Pb and Zn in four contaminated and four non-contaminated soils of Japan, was compared by single extraction (CaCl₂, DTPA, NH₄Cl, 0.1 M HCl and 1 M HCl ) and sequential extraction procedures [(six operationally defined chemical phases, viz. water soluble (Fl), exchangeable (F2), carbonate (F3), oxide (F4), organic (F5) and residual (F6) fractions)]. Extractability of metals from soils samples varied depending on metals and/or extradants used. Among the extradants, 1 M HCl extracted the largest proportion of Cd (79 to 96% of total), Cu (61 to 83%), Pb (51 to 99%) and Zn (23 to 52%) from soils followed by 0.1 M HCl, NH₄Cl, DTPA and CaCl₂. In all the extradants, the proportion of extractability of metals was higher in the contaminated soils than the non-contaminated soils. Regardless of soils and extradants, relative extractability was higher for Cd as compared to other three metals. The use of 1 M HCl may be recommended for first-level screening of soil contamination with heavy metals. The other four weak extradants are believed to provide a better assessment of bioavailable/mobile metals content in soils than 1 M HCl extradant. However, 0.1 M HCl mobilized all four metals irrespective of soil types, therefore, might be the best choice if only one extradant is to be used. The sequential extraction procedures showed 22 to 64% of total Cd was in the mobile fraction (sum of Fl to F3), while the corresponding values for Cu, Pb and Zn in this fractions were 2 to 23% suggesting higher mobility of Cd than other three metals. The single extraction procedures are simple and easy to perform and obtained results are comparable with sequential extraction procedure.     

Age of glacial and periglacial landforms in northern Hokkaido, Japan, using OSL dating of fine grain quartz

The timing of glacial advances, periglacial phenomena, and the ages of two marker tephras in northern Hokkaido were estimated by OSL dating. It appears that the glacier of Yamunai 2 stage on Rishiri Island expanded between 24 and 15 ka. In northern Hokkaido, OSL ages indicate ice wedge formation during the period 24–18 ka. These results indicate that both the glacial advance and the development of ice wedges were synchronous phenomena relating to the Last Glacial Maximum.     

The Influence Of Urban Canopy Configuration On Urban Albedo

We propose a calculation method for shortwave radiation flux and longwave radiation flux within the urban canopy and investigate the influence of urban canopy configuration on net radiation flux. In the assumed urban configuration, buildings of equal size are arranged in a regular lattice within the urban canopy. The net shortwave radiation flux and longwave radiation flux within the urban canopy were calculated by the photon tracking method based on the Monte Carlo method. The albedo value obtained by this method shows close agreement with experimental data, and the average sky view factor shows almost perfect agreement with the theoretical value. Moreover, we calculated the urban albedo for the urban canopy configuration including roads and building height distribution.%Moreover, we calculated net radiation within the urban canopy in %consideration of roads and building height distribution.We found that the sky view factor of the ground surface is high when building coverage is low, building height is low, open space by roads exists, and building height is non-uniform. Moreover, we found that the albedo value is high when building height is small, open space by roads is wide, and building height is uniform. The albedo value was found to vary in a complicated manner with change in building coverage.     

Geochemistry of hydroxy acids in sediments—I. Some freshwater and brackish water lakes in Japan

Series of α, β, ω and (ω-1) hydroxy fatty acids (FAOHs) were determined in several freshwater and brackish water lacustrine sediments in Japan. Analytical procedure used was digestion of the solvent-extracted sediment with HF/HCl followed by solvent and saponification extraction of the residue. Abundances of α/β and ω-FAOH determined by this procedure were 2–3 times higher than those obtained by single alkaline saponification and of the same order with those provided by HCl hydrolysis. Major portion of α/β-FAOH was obtained by solvent extraction of the acid-treated sediments, while subsequent alkaline saponification was needed for the majority of ω-FAOH to be recovered. Thus determined FAOHs comprised 33–61% (Av. = 42%) of the “bound” acid constituents in the lacustrine surface sediments. The α/β and ω-FAOH composition was principally the same among the samples examined, except for relative proportions of the iso to anteiso C₁₅ and C₁₇ ß(α)-FAOH, which showed significant variations in the ranges of 0.30–1.1 and 0.46–1.5, respectively. In the holomictic lakes, the ratios together with the same ratios of the “bound” branched monocarboxylic acids tended to decrease with increasing water depth of the lakes, suggesting that the ratios may indicate an extent of the early diagenetic alteration of the bacteria-derived lipids either in water column or in surface sediment.     

A 4th order fabric tensor approach applied to granular media

In this paper, we propose a micromechanical approach of the behavior of granular media, which takes into account the anisotropy by means of a fourth order fabric tensor. The proposed approach is implemented in an homogenization scheme based on Voigt and Reuss localization assumption. The fabric tensor-based approach is then combined with a new kinematic localization rule and yields a general homogenization scheme for anisotropic granular media.     

Development of density measurement for metals at high pressures and high temperatures using X-ray absorption imaging combined with externally heated diamond anvil cell

A technique for density measurement under high pressure and high temperature was developed using the X-ray absorption imaging method combined with an externally heated diamond anvil cell. The densities of solid and liquid In were measured in the pressure and temperature ranges of 3.2–18.6 GPa and 294–719 K. The densities obtained through the X-ray absorption imaging method were in good agreement (less than 2.0% difference) with those obtained through X-ray diffraction. Based on the measured density, the isothermal bulk modulus of solid In is determined as 48.0 ± 1.1?40.9 ± 0.8 GPa at 500 K, assuming K′ = 4 to 6. The compression curve of liquid In approaches that of solid In at higher pressures and does not cross over the solid compression curve in the measurement range. The present technique enables us to determine the densities of both solids and liquids precisely in a wide pressure and temperature range.     

Wind Fields over Funka Bay and Their Effect on Water Circulation in the Bay

Horizontal wind fields over Funka Bay during cold air outbreaks were simulated using a 3-D meso-scale atmospheric model. The simulated wind fields over the bay have a positive curl in the north and a negative curl in the south. These wind fields were used to simulate the current in Funka Bay using a barotropic ocean model. The simulated current pattern was composed of two vortices—one with anti-clockwise vorticity in the north and the other with clockwise vorticity in the south—and was in the opposite direction to that simulated by the uniform wind fields. This is because the wind stress curl effect on the vorticity production in Funka Bay opposes and overwhelms the bathymetry torque effect during cold air outbreaks. These results show that the non-uniformity of the wind fields caused by the land topography around a shallow lake or bay cannot be neglected in simulating its currents.     

Improving GPS positioning estimates during extreme weather situations by the help of fine-mesh numerical weather models

Space geodetic applications require to model troposphere delays as good as possible in order to achieve highly accurate positioning estimates. However, these models are not capable to consider complex refractivity fields which are likely to occur during extreme weather situations like typhoons, storms, heavy rain-fall, etc. Thus it has been investigated how positioning results can be improved if information from numerical weather models is taken into account. It will be demonstrated that positioning errors can be significantly reduced by the usage of ray-traced slant delays. Therefore, meso-scale and fine-mesh numerical weather models are utilized and their impact on the positioning results will be measured. The approach has been evaluated during a typhoon passage using global positioning service (GPS) observations of 72 receivers located around Tokyo, proving the usefulness of ray-traced slant delays for positioning applications. Thereby, it is possible reduce virtual station movements as well as improve station height repeatabilities by up to 30% w.r.t. standard processing techniques. Additionally the advantages and caveats of numerical weather models will be discussed and it will be shown how fine-mesh numerical weather models, which are restricted in their spatial extent, have to be handled in order to provide useful corrections.     

Iron-water reaction at high pressure and temperature, and hydrogen transport into the core

We observed a direct reaction of metallic iron with water to form iron hydride and iron oxide, 3Fe + H₂O–>2FeH_x + FeO, at pressures from 6 GPa to 84 GPa and temperatures above 1,000 K in diamond anvil cell (DAC). Iron hydride is dhcpFeH_x or -FeH_x, and iron oxide has the rhombohedral or B1 structure at pressures at least up to 37 GPa. The formation of an assembly composed of dhcpFeH_x and FeO with the B8 structure was observed at 84 GPa. In primordial Earth, water formed by dehydration of the low temperature primitive materials reacts with metallic iron in the high temperature component to form iron hydride FeH_x and iron oxide FeO. The former would be incorporated in the iron forming the core. Thus hydrogen could be an important element of the Earths core. This reaction would be essential for transport of hydrogen into the core in the accretion stage of the Earth.