Diets of eight fish species from the upper slope off the Wairarapa coast,North Island,New Zealand,with notes on the diets of others

The diets of eight demersal fish species from the upper continental slope (c. 24CM‐50 m) were determined from samples taken during late January and early February 2004, off the Wairarapa coast, North Island, New Zealand. Diets were from a combination of benthopelagic and benthic sources, with most species exhibiting ontogenetic shifts in diet, in that larger‐bodied food (fish and/or natant decapod prawns) was more important in the diets of larger fish. Javelinfish (Lepidorhynchus denticulatus), silver roughy (Hoplostethus mediterraneus), and capro dory (Capromimus abbreviatus) had predominantly benthopelagic diets, whereas the diets of sea perch (Helicolenus percoides), Bollons’ rattail (Caelorinchus bollonsi), two‐banded rattail (C. biclinozonalis), and silverside (Argentina elongata) were predominantly benthic, with the crab Carcinoplax victoriensis an important food item. The diet of Oliver's rattail (C. oliverianus) was a mix of benthopelagic and benthic organisms. Generally, levels of dietary overlap between the eight species were low. Overall, the diets of these fish probably reflect regional and seasonal levels of food availability. Notes on food observed in the stomachs of a further 18 species, for which there were fewer than 10 stomach samples per species are also provided.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Chemical contamination of a coral reef by the grounding of a cruise ship in Bermuda

Bulk metal analyses of surficial sediments collected around the Norwegian Crown cruise ship grounding site in Bermuda indicated significant but localized contamination of reef sediments by copper and zinc, caused by the stripping of the tri-butyltin (TBT)-free antifouling (AF) paint (Intersmooth 460) from the underside of the hull. Highest copper and zinc values were found in heavily compacted and red-pigmented sediments inside the impact scar and were comparable to levels found close to slip ways of local boat yards where AF paints from hull stripping and cleaning processes are washed into the sea. The re-distribution of AF contaminated sediments by storms and deposition on nearby reefs constitutes a significant ecological risk that could delay recovery processes and reduce the effectiveness of remediation efforts. Whilst the ecotoxicological effects of AF paint particles interspersed with sediment is unknown, and in need of further study, it is argued that the significance of AF paint contamination of grounding sites has been overlooked.     

Copper speciation survey from UK marinas, harbours and estuaries

The use of copper in antifouling paints has increased in the UK in the last 20 years as TBT and several other organic biocides have been phased out. To assess the probable impact of copper on estuarine systems a survey was undertaken to measure the different fractions of copper present in the water column at current usage. The different fractions measured were; labile copper, (LCu) considered as both the free copper ions and inorganically bound copper, the total dissolved copper (TDCu) present, and the difference between them taken as the organically bound likely non-toxic copper fraction. The survey considered sites with different levels of boat use, namely marinas, harbours and estuaries, differing physical parameters of suspended and dissolved organic matter, different seasons of the year and different depths in the water column all of which control speciation behaviour. Suspended particulate matter (SPM) values were measured at all sites and increased from West to East coast locations (5.7-34.4 mg/l). Dissolved organic matter (DOM) values ranged from 0.58 to 2.2mg/l C. The total dissolved copper concentrations ranged from 0.30 to 6.68 microg/l, with labile fraction ranging from 0.02 to 2.69 microg/l, and most labile copper concentrations below 1 microg/l. None of the yearly mean copper measurements exceeded the 76/464/EEC EQS of 5 microg/l. Of the 306 measurements, only one dissolved copper value in one season was above 5 microg/l. This ratio of labile to total copper was between 10 and 30%. The results from this survey suggest that if toxicity of copper is due to the labile fraction then using the total dissolved copper concentrations as an indicator of impact overestimate the risk by a factor of four times.     

Quantifying strain birefringence halos around inclusions in diamond

The pressure and temperature conditions of formation of natural diamond can be estimated by measuring the residual stress that an inclusion remains under within a diamond. Raman spectroscopy has been the most commonly used technique for determining this stress by utilising pressure-sensitive peak shifts in the Raman spectrum of both the inclusion and the diamond host. Here, we present a new approach to measure the residual stress using quantitative analysis of the birefringence induced in the diamond. As the analysis of stress-induced birefringence is very different from that of normal birefringence, an analytical model is developed that relates the spherical inclusion size, R _i, host diamond thickness, L, and measured value of birefringence at the edge of the inclusion, \Updelta n(R_\texti )_\textav \Updelta n(R_{\text{i}} )_{\text{av}} , to the peak value of birefringence that has been encountered; to first order \Updelta n_\textpk = (3/4)(L/R_\texti )  \Updelta n(R_\texti )_\textav \Updelta n_{\text{pk}} = (3/4)(L/R_{\text{i}} ) \, \Updelta n(R_{\text{i}} )_{\text{av}} . From this birefringence, the remnant pressure (P _i) can be calculated using the photoelastic relationship \Updelta n_\textpk = - (3/4)n³ q_\textiso P_\texti \Updelta n_{\text{pk}} = - (3/4)n^{3} q_{\text{iso}} P_{\text{i}} , where q _iso is a piezo-optical coefficient, which can be assumed to be independent of crystallographic orientation, and n is the refractive index of the diamond. This model has been used in combination with quantitative birefringence analysis with a MetriPol system and compared to the results from both Raman point and 2D mapping analysis for a garnet inclusion in a diamond from the Udachnaya mine (Russia) and coesite inclusions in a diamond from the Finsch mine (South Africa). The birefringence model and analysis gave a remnant pressure of 0.53 ± 0.01 GPa for the garnet inclusion, from which a source pressure was calculated as 5.7 GPa at 1,175°C (temperature obtained from IR analysis of the diamond host). The Raman techniques could not be applied quantitatively to this sample to support the birefringence model; they were, however, applied to the largest coesite inclusion in the Finsch sample. The remnant pressure values obtained were 2.5 ± 0.1 GPa (birefringence), 2.5 ± 0.3 GPa (2D Raman map), and 2.5–2.6 GPa (Raman point analysis from all four inclusions). However, although the remnant pressures from the three methods were self-consistent, they led to anomalously low source pressure of 2.9 GPa at 1,150°C (temperature obtained from IR analysis) raising serious concerns about the use of the coesite-in-diamond geobarometer.     

Nondestructive determination of the physical properties of Antarctic meteorites: Importance for the meteorite—parent body connection

Photogrammetry is a low-cost, nondestructive approach for producing 3-D models of meteorites for the purpose of determining sample bulk density. Coupled with the use of a nondestructive magnetic susceptibility/electrical conductivity field probe, we present measurements for the interrogation of several physical properties, on a set of Antarctic meteorites. Photogrammetry is an effective technique over a range of sample sizes, with meteorite bulk density results that are closely comparable with literature values, determined using Archimedean glass bead or laser scanning techniques. The technique is completely noncontaminating and suitable for the analysis of rare or fragile samples, although there are limitations for analyzing reflective samples. It is also flexible, and, with variations in equipment setup, may be appropriate for samples of a wide range of sizes. X-ray computed tomography analyses of the same meteorite samples yielded slightly different bulk density results, predominantly for samples below 10 g, although the reason for this is unclear. Such analyses are expensive and potentially damaging to certain features of the sample (e.g., organic compounds), but may be useful in expanding the measurements to accommodate an understanding of internal voids within the sample, lending itself to measurement of grain density. Measurements of bulk density are valuable for comparisons with estimates of the bulk densities of asteroids that are suggested as meteorite parent bodies.     

Bio-electricity and land use in the Future Agricultural Resources Model (FARM)

Bio-electricity is an important technology for Energy Modeling Forum (EMF-27) mitigation scenarios, especially with the possibility of negative carbon dioxide emissions when combined with carbon dioxide capture and storage (CCS). With a strong economic foundation, and broad coverage of economic activity, computable general equilibrium models have proven useful for analysis of alternative climate change policies. However, embedding energy technologies in a general equilibrium model is a challenge, especially for a negative emissions technology with joint products of electricity and carbon dioxide storage. We provide a careful implementation of bio-electricity with CCS in a general equilibrium context, and apply it to selected EMF-27 mitigation scenarios through 2100. Representing bio-electricity and its land requirements requires consideration of competing land uses, including crops, pasture, and forests. Land requirements for bio-electricity start at 200 kilohectares per terawatt-hour declining to approximately 70 kilohectares per terwatt-hour by year 2100 in scenarios with high bioenergy potential.     

Sensitivity of a coupled climate model to canopy interception capacity

The canopy interception capacity is a small but key part of the surface hydrology, which affects the amount of water intercepted by vegetation and therefore the partitioning of evaporation and transpiration. However, little research with climate models has been done to understand the effects of a range of possible canopy interception capacity parameter values. This is in part due to the assumption that it does not significantly affect climate. Near global evapotranspiration products now make evaluation of canopy interception capacity parameterisations possible. We use a range of canopy water interception capacity values from the literature to investigate the effect on climate within the climate model HadCM3. We find that the global mean temperature is affected by up to ?0.64 K globally and ?1.9 K regionally. These temperature impacts are predominantly due to changes in the evaporative fraction and top of atmosphere albedo. In the tropics, the variations in evapotranspiration affect precipitation, significantly enhancing rainfall. Comparing the model output to measurements, we find that the default canopy interception capacity parameterisation overestimates canopy interception loss (i.e. canopy evaporation) and underestimates transpiration. Overall, decreasing canopy interception capacity improves the evapotranspiration partitioning in HadCM3, though the measurement literature more strongly supports an increase. The high sensitivity of climate to the parameterisation of canopy interception capacity is partially due to the high number of light rain-days in the climate model that means that interception is overestimated. This work highlights the hitherto underestimated importance of canopy interception capacity in climate model hydroclimatology and the need to acknowledge the role of precipitation representation limitations in determining parameterisations.     

Enhancing the relevance of Shared Socioeconomic Pathways for climate change impacts,adaptation and vulnerability research

This paper discusses the role and relevance of the shared socioeconomic pathways (SSPs) and the new scenarios that combine SSPs with representative concentration pathways (RCPs) for climate change impacts, adaptation, and vulnerability (IAV) research. It first provides an overview of uses of social–environmental scenarios in IAV studies and identifies the main shortcomings of earlier such scenarios. Second, the paper elaborates on two aspects of the SSPs and new scenarios that would improve their usefulness for IAV studies compared to earlier scenario sets: (i) enhancing their applicability while retaining coherence across spatial scales, and (ii) adding indicators of importance for projecting vulnerability. The paper therefore presents an agenda for future research, recommending that SSPs incorporate not only the standard variables of population and gross domestic product, but also indicators such as income distribution, spatial population, human health and governance.