Zircon Hf Isotopic Evidence for Mixing of Crustal and Silicic Mantle-derived Magmas in a Zoned Granite Pluton, Eastern Australia

Zircon Hf isotopic data from a zoned pluton of the Moonbi supersuite,New England batholith, eastern Australia, are consistent withmagma mixing between two silicic melts, each derived from isotopicallydistinct sources. Although zircons from three zones within theWalcha Road pluton give a U–Pb crystallization age of249 ± 3 Ma, zircon populations from each zone have arange in _Hf. Zircons from the mafic hornblende–biotitemonzogranite pluton margin and intermediate zones have _Hf +5to +11, whereas those from the more felsic centre of the plutonhave _Hf +7 to +16, representing a total variation of 11 _Hfunits. The Lu–Hf depleted mantle model ages range from650 to 250 Ma, with the younger zircons present only in thefelsic pluton centre. The variation in _Hf indicates the involvementof silicic melts from at least two sources, one a crustal componentwith a Neoproterozoic model age and the other a primitive mantle-derivedcomponent with model ages similar to the U–Pb crystallizationage of the pluton. The zircons reflect the isotopic compositionsof the different proportions of crustal-derived silicic melt,relative to mantle-derived silicic melt, between melt generationand final pluton construction. The Walcha Road pluton is consideredto have formed by incremental assembly of progressively morefelsic melt batches resulting from mixing, replenishment andcrystal–melt separation, with final pluton constructioninvolving mechanical concentration as zones of crystal mush.The zoned pluton and, more broadly, the Moonbi supersuite provideexamples of magma mixing by which the more silicic units havemore juvenile isotopic compositions as a result of increasingproportions of residual melt from basalt fractionation, relativeto crustal partial melt. KEY WORDS: Australia; granite magma mixing; zircon; zoned pluton; Hf isotopes     

Timing and Extent of Late Quaternary Paleolakes in the Trans-Pecos Closed Basin, West Texas and South-Central New Mexico

The Trans-Pecos Closed Basin is a hydrographically closed region covering 20,000 km²centered on Salt Basin, 160 km east of El Paso, Texas. Geomorphic and limnetic evidence have been used to identify four major highstands for Lake King during the last glacial maximum (LGM). Additional geomorphic features from a second, recently identified, paleolake, Lake Sacramento, have been found in the Beargrass subbasin, a nested subbasin approximately 75 km northwest of Salt Basin. Radiocarbon ages of the organic material in Lake King sediments date four abrupt climate changes and rapid lacustrine transgressions during the LGM with a quasi-periodicity of 2000 yr. Geomorphic evidence in the Beargrass subbasin identifies lake cycles contemporaneous with those in Lake King. The dates for these transgressions correlate with the dates of freshening events identified by researchers in paleolake basins elsewhere in New Mexico. The quasi-periodicity of the events approximates that of Dansgaard–Oeschger events identified from Greenland ice cores. The contemporaneity of the Trans-Pecos transgressions with transgressive events in other basins in the region suggests that paleolakes in the region were in phase with respect to abrupt climate changes during the latter stages of the LGM.     

The Harry Creek Deformed Zone,a retrograde schist zone of the Arunta Block,central Australia

The Harry Creek Deformed Zone, a retrograde schist zone of epidote amphibolite facies grade, which separates the granulite facies Utralanama Block from the amphibolite facies Ankala Block in the southeastern Strangways Range, N.T., is typical of the retrograde schist zones transecting the Arunta Block. Associated with the deformed zone is a small deformed granitic pluton and its various offshoots—the Gumtree Granite Suite—which provides structural and geochrono‐logical evidence that the Harry Creek Deformed Zone has had a polyphase deforma‐tional history. Early movements within the deformed zone pre‐dated intrusion of the Gumtree Granite Suite and resulted in the movement of the Utralanama and Ankala Blocks into their present juxtaposition. Reactivation of much of the zone during the Alice Springs Orogeny brought about the schistose character of the zone and the deformation of the granitic rocks. Further minor reactivation of the zone, subsequent to the main phase of the Alice Springs Orogeny, resulted in limited development of pseudotachylytes.

The age of the granite (990 ± 13 m.y.) gives a minimum age for initiation of the zone, and evidence for the nature of the structures associated with the early movements is presented. It is suggested that the Harry Creek Deformed Zone represents a post‐orogenic wrench fault which has been reactivated. Early movements, which were of a brittle transcurrent nature, brought about major uplift (up to 10 km) to the north, and lateral movements may have been of the order of 60 km in a sinistral sense. Comparison with the Redbank Zone indicates many similarities, suggestive of a similar history.     

Steady critical discharge rates from vertical and horizontal wells in fresh–saline aquifers with sharp interfaces

In this study, the critical (or maximum) discharge rates before saline water enters a well were determined for vertical and horizontal wells in a freshwater aquifer which is separated from a static saline aquifer by a sharp interface. Flow around the well was solved by integration of a point sink solution along the well axis, and both the critical discharge rate and critical interface rise were determined through a comparison of the heads and vertical gradients at the saline–fresh water interface. The rates were determined for vertical and horizontal wells with various lengths and depths for different aquifer salinities. Results were generalized by drawing dimensionless type curves. The results showed that the dimensionless total critical discharge rates are higher for the longer horizontal wells and longer vertical wells with a certain bottom depth, and they almost linearly decrease with well depth at rates of 0.7–0.9. For the dimensionless well length of 0.2, the dimensionless total discharge rate of a horizontal well is about 0.1 more than that of a vertical well with the same length and well-top depth. Also, the critical discharge rates per unit length of well are inversely proportional to well length and remarkably higher for shallower wells. Additionally, the critical pumping rate is proportional to the salinity difference of the aquifers. These results were confirmed by comparison to existing solutions for vertical wells with dimensionless lengths of 0.2, 0.5 and 0.6, and for critical interface rises in the range of 0.75–0.9.     

Geochemistry and Petrogenesis of Intracontinental Basaltic Volcanism on the Northwest Arabian Plate,Gaziantep Basin,Southeast Anatolia,Turkey

Volcanism along the northwest boundary of the Arabian Plate found in the Gaziantep Basin, southeast Turkey, is of Miocene age and is of alkaline and calc-alkaline basic composition. The rare earth element data for both compositional series indicates spinel–peridotite source areas. The rare earth and trace elements of the alkaline lavas originate from a highly primitive and slightly contaminated asthenospheric mantle; those of the calc-alkaline lavas originate from a highly heterogeneous, asthenospheric, and lithospheric mantle source. Partial melting and magmatic differentiation processes played a role in the formation of the petrological features of these volcanics. These rocks form two groups on the basis of their ~(87) Sr/~(86) Sr and ~(143) Nd/~(144) Nd isotopic compositions in addition to their classifications based on their chemical compositions(alkaline and calc-alkaline). These isotopic differences indicate a dissimilar parental magma. Therefore, high Nd isotope samples imply a previously formed and highly primitive mantle whereas low Nd isotope samples may indicate comparable partial melting of an enriched heterogeneous shallow mantle. Other isotopic changes that do not conform to the chemical features of these lavas are partly related to the various tectonic events of the region, such as the Dead Sea Fault System and the Bitlis Suture Zone.     

The 14-year Performance of a Compacted Clay Liner used as Part of a Composite Liner System for a Leachate Lagoon

The migration of contaminants through a 2.9 m thick compacted clay liner (CCL) for a landfill leachate lagoon is examined 14 years after construction. The clay liner formed the lower portion of the composite liner system but the geomembrane (GM) was found to have defects that had allowed leachate to migrate between the GM and CCL. Chloride, sodium, potassium, calcium and magnesium pore water profiles through the CCL are examined. It is shown that chloride migrated approximately 1.7 m into the CCL during the 14 years of the lagoon operation, sodium approximately 1.2 m, and potassium 0.7 m. Diffusion and sorption data from laboratory diffusion testing are utilized in combination with a finite layer contaminant transport model to predict field contaminant migration profiles through the composite liner system and to establish the time of ‘failure’ of the geomembrane at sometime between 0 and 6 years after installation. Relatively high sorptive uptake of potassium by the CCL soil is observed from batch testing and diffusion testing with field data suggesting an even larger amount of sorption. It is hypothesized that organic sludge matter at the base of the lagoon is responsible for potassium uptake from the leachate. This field case highlights the importance of the compacted clay liner as part of the composite liner system in acting as a diffusion barrier during the lifetime of the lagoon as well as using relatively non-conservative contaminants such as chloride and sodium to estimate geomembrane ‘failure’ times     

New evidence for an extended occupation of the Provo shoreline and implications for regional climate change, Pleistocene Lake Bonneville, Utah, USA

Lake Bonneville was a climatically sensitive, closed-basin lake that occupied the eastern Great Basin during the late Pleistocene. Ongoing efforts to refine the record of lake level history are important for deciphering climate conditions in the Bonneville basin and for facilitating correlations with regional and global records of climate change. Radiocarbon data from this and other studies suggest that the lake oscillated at or near the Provo level much longer than depicted by current models of lake level change. Radiocarbon data also suggest that the lake dropped from threshold control much more rapidly than previously supposed. These revisions to the Lake Bonneville hydrograph, coupled with independent evidence of climate change from vegetation and glacial records, have important implications for conditions in the Bonneville basin and during the Pleistocene to Holocene transition.     

Modeling the Potential Effect of Additives on Enhancing the Solubility of Aromatic Solutes Contained in Gasoline

The potential effect of two common gasoline additives, ethanol and methyl tertiary-butyl ether (MTBE), on enhancing the solubility of the aromatic solutes benzene, toluene, ethylbenzene, and o-, m-, and p-xylene, was examined using a computer model, ARSOL. Aqueous solute systems containing cosolvents ethanol and MTBE at 0, 0.1, 1, and 4.3 percent were modeled for both ethanol and MTBE systems. Five- and 10-percent ethanol systems were also modeled. Little solubility enhancement was predicted by modeling at cosolvent levels less than 1 percent. At cosolvent levels greater than 1 percent, predicted solute solubility increased curvilinearly with an increase in percent cosolvent; a 10 percent cosolvent system increased aromatic hydrocarbon solubility by approximately 100 percent. According to the model predictions, MTBE enhanced solute solubility more than ethanol, with enhancement by MTBE being approximately 10 percent greater than enhancement by ethanol at 4.3 percent cosolvent. Other concerns regarding gasoline additives are the observed reduction in partitioning of solutes to soils and sediments and the contamination of water supplies due to the high water solubility of the additives.