Pravčice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering

The dominant factors affecting the development of weathering forms on the Prav?ice Rock Arch (PRA) (Bohemian Switzerland National Park, Czech Republic) are discussed, based on the in situ monitoring of weathering forms, as well as on laboratory studies of materials taken from this site. The in situ monitoring shows the progressive development of distinct weathering forms (delamination of case-hardened rock surfaces, cyclic efflorescence, and granular disintegration of exposed weakly cemented rock mass) in specific portions of the PRA, whose location is controlled by lithology, jointing/local hydrodynamics, and exposure to climatic factors. From the analysis of efflorescence, the dominance of sulphates is evident; particularly of gypsum and alums. However, the synergistic effects of the several salt species (that also include minor nitrates and chlorides) upon the mechanical disintegration of sandstone can be expected.     

The lower boundary of the Adelaide system and older basement relationships in south Australia∗

The stratigraphical problem of defining the lower boundary of the Adelaide System is discussed in relation to the geology of several critical areas in the Adelaide Geosyncline and adjacent shelf‐platform.

The Precambrian stratigraphical succession and geological history is outlined with the aid of Rb/Sr age‐determinations made by Dr W. Compston of the Australian National University.

It is concluded that the lower boundary of the Adelaide System is related to the collapse of older basement positive areas on which a regional erosional surface had developed. This surface is defined by the Callanna Beds, the oldest deposits of Willouran age. Willouran sedimentation began some time between 1,340 m.y. and 1,490 m.y. ago. Erosion of the basement rocks probably occupied a major early part of this time interval.     

Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

Composition and formation conditions of pay zones in the lower Cretaceous Nizhnyaya Kheta and Yakovlevo formations within the Vankor oil-and-gas field (in the Northeast of West Siberia)

Sedimentologic analysis of cores from wells sunk in the Vankor petroleum field allowed refinement of the accumulation conditions producing the sandy strata of the Nizhnyaya Kheta River (Nizhnekhetsky) Formation accumulated in the coastal marine zone and of the Yakovlevo (Yakovlevsky) Formation accumulated under alluvial-deltaic conditions. Petrographic examination of the sandstones added information on the sources, transport, and accumulation conditions of the terrigenous material in the northeastern marginal part of the West Siberian sedimentation basin.     

Effects of sludge pretreatment on sludge reduction in a lab-scale anaerobic/anoxic/oxic system treating domestic wastewater

Excess sludge disposal is one of the serious challenges in biological wastewater treatment. Reduction of sludge production would be an ideal way to solve sludge-associated problems rather than the post-treatment of the sludge produced. In this study, a new wastewater treatment process combining anaerobic/anoxic/oxic system with thermochemical sludge pretreatment was tested in a laboratory scale experiment. In this study, the effects of the sludge pretreatment on the excess sludge production in anaerobic/anoxic/oxic were investigated. The system was operated in two Runs (1 and 2). In Run 1, the system was operated as a reference and in Run 2, a part of the mixed liquid was pretreated thermochemically and was returned to the bioreactor. The average solubilization efficiency of pretreated sludge was found to be about 35 % during the study period of 220 days. Sludge production rate in Run 2 was less than that in Run 1 by about 52 %. Total phosphorous was removed by enhanced biological phosphorous removal with the removal efficiency of 83–87 % and 81–83 % for Run 1 and Run 2, respectively. Total nitrogen removal in Run 2 (79–82 %) was slightly higher than that in Run 1 (68–75 %). The mixed liquor suspended solids/mixed liquor volatile suspended solids ratio was identical after both runs in the range 78–83 %. The effluent water qualities were not significantly affected when operated with thermochemical pretreatment at pH 11 and 60 °C for 3 h during 7 months. From the present study it is concluded that thermochemical sludge pretreatment of anaerobic/anoxic/oxic process plays an important role in reduction of sludge production.     

Chemical evolution and petrogenetic implications of loparite in the layered,agpaitic Lovozero complex,Kola Peninsula,Russia

Summary Lovozero, the largest of the world’s layered peralkaline intrusions, includes gigantic deposits of Nb + REE-loparite ore. Loparite, (Na,Ce,Ca)₂(Ti,Nb)₂O₆, became a cumulus phase after crystallisation of about 35% of the ‘Differentiated Complex’, and its compositional evolution has been investigated through a 2.35 km section of the intrusion. The composition of the cumulus loparite changes systematically upwards through the intrusion with an increase in Na, Sr, Nb and Th and decrease in REE and Ti. This main trend of loparite evolution records differentiation of the peralkaline magma through crystallisation of 1600 m of the intrusion. The formation of the loparite ores was the result of several factors including the chemical evolution of the highly alkaline magma and mechanical accumulation of loparite at the base of a convecting unit. At later stages of evolution, when concentrations of alkalis and volatiles reached very high levels, loparite reacted with the residual melt to form a variety of minerals including barytolamprophyllite, lomonosovite, steenstrupine-(Ce), vuonnemite, nordite, nenadkevichite, REE, Sr-rich apatite, vitusite-(Ce), mosandrite, monazite-(Ce), cerite and Ba, Si-rich belovite. The absence of loparite ore in the “Eudialyte complex” is likely to be a result of the wide crystallisation field of lamprophyllite, which here became a cumulus phase. Received November 6, 2000; revised version accepted January 18, 2001     

REE distribution in the resin-asphaltene fractions as a geochemical criterion for identification of sources of trace elements in oil

This paper reports REE data on resin-asphaltene components of oil from six oil-gas-bearing provinces and on bitumoids from inferred oil-source rocks (domanikites and bazhenites). It was shown that, regardless of geological-tectonic structure of the regions, oil composition, depth of reservoirs, and host lithologies, oil exhibits significant REE fractionation, and, unlike bitumoids, positive Eu anomaly. The (Eu/Sm)_n ratio increases from asphaltenes to resins and further to oils. Based on REE distribution in oil, source rocks, and bitumoids, it was concluded that deep-seated fluids were one of the possible sources that defined the trace element composition of oil.