Distinctive erosional and depositional structures formed at a canyon mouth: A lower Pleistocene deep‐water succession in the Kazusa forearc basin on the Boso Peninsula,Japan

The canyon mouth is an important component of submarine‐fan systems and is thought to play a significant role in the transformation of turbidity currents. However, the depositional and erosional structures that characterize canyon mouths have received less attention than other components of submarine‐fan systems. This study investigates the facies organization and geometry of turbidites that are interpreted to have developed at a canyon mouth in the early Pleistocene Kazusa forearc basin on the Boso Peninsula, Japan. The canyon‐mouth deposits have the following distinctive features: (i) The turbidite succession is thinner than both the canyon‐fill and submarine‐fan successions and is represented by amalgamation of sandstones and pebbly sandstones as a result of bypassing of turbidity currents. (ii) Sandstone beds and bedsets show an overall lenticular geometry and are commonly overlain by mud drapes, which are massive and contain fewer bioturbation structures than do the hemipelagic muddy deposits. (iii) The mud drapes have a microstructure characterized by aggregates of clay particles, which show features similar to those of fluid‐mud deposits, and are interpreted to represent deposition from fluid mud developed from turbidity current clouds. (iv) Large‐scale erosional surfaces are infilled with thick‐bedded to very thick‐bedded turbidites, which show lithofacies quite similar to those of the surrounding deposits, and are considered to be equivalent to scours. (v) Concave‐up erosional surfaces, some of which face in the upslope direction, are overlain by backset bedding, which is associated with many mud clasts. (vi) Tractional structures, some of which are equivalent to coarse‐grained sediment waves, were also developed, and were overlain locally by mud drapes, in association with mud drape‐filled scours, cut and fill structures and backset bedding. The combination of these outcrop‐scale erosional and depositional structures, together with the microstructure of the mud drapes, can be used to identify canyon‐mouth deposits in ancient deep‐water successions.     

A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data

Arsenic(III) adsorption reactions are thought to play a critical role in the mobility of arsenic in the environment. It is the nature of the As(III) surface species that must be known on a wide variety of minerals and over a range of pH, ionic strength and surface coverage in order to be able to predict adsorption behavior. EXAFS and XANES spectroscopic studies have identified bidentate, binuclear inner-sphere surface species and/or an outer-sphere species, but only a few oxides have been examined. These results need to be integrated with a predictive surface complexation model in order to ascertain the environmental conditions under which the different surface species may be important on a wide range of solids. In the present study, the surface species information from XAFS and XANES studies has been built into a recent extension of the triple-layer model (ETLM) for the formation of inner-sphere complexes of anions that takes into account the electrostatics of water dipole desorption during ligand exchange reactions. The ETLM has been applied to regress surface titration, proton coadsorption, and As(III) adsorption data over extensive ranges of pH, ionic strength, electrolyte type and surface coverage for magnetite, goethite, gibbsite, amorphous hydrous alumina, hydrous ferric oxide (HFO), ferrihydrite, and amorphous iron oxide. Two principal reactions forming inner- and outer-sphere As(III) surface species,

     

Heat flow and thickness of the oceanic lithosphere

Existing thermal models of the oceanic lithosphere predict too sharp an increase of heat flow towards the ridge axis. A new mathematical model of a thickening lithosphere is presented. The temperature distribution is computed by the use of observed surface heat flow as a boundary condition. If observed heat flow values represent flow of heat from the mantle, the model predicts a rather rapid growth of the lithosphere within the first 30 m.y. and a nearly steady state after 100 m.y. Heat flow from the asthenosphere to the lithosphere shows a minimum near the ridge axis, suggesting a down-going convective flow in the asthenosphere at both sides of a spreading center.     

Experimental and analytical studies on earthquake resisting behaviour of confined concrete block masonry structures

To improve the seismic performance of masonry structures, confined masonry that improves the seismic resistance of masonry structures by the confining effect of surrounding bond beams and tie columns is constructed. This study investigated the earthquake resisting behaviour of confined masonry structures that are being studied and constructed in China. The structural system consists of unreinforced block masonry walls with surrounding reinforced concrete bond beams and tie columns. The characteristics of the structure include: (1) damage to blocks is reduced and brittle failure is avoided by the comparatively lower strength of the joint mortar than that of the blocks, (2) the masonry walls and surrounding reinforced concrete bond beams and tie columns are securely jointed by the shear keys of the tie columns. In this study, wall specimens made of concrete blocks were tested under a cyclic lateral load and simulated by a rigid body spring model that models non‐linear behaviour by rigid bodies and boundary springs. The results of studies outline the resisting mechanism, indicating that a rigid body spring model is considered appropriate for analysing this type of structure. Copyright © 2006 John Wiley & Sons, Ltd.     

Cross-Validation of Open-Path and Closed-Path Eddy-Covariance Techniques for Observing Methane Fluxes

Methane ( ${\mathrm {CH}}_{4}$ ) fluxes observed with the eddy-covariance technique using an open-path ${\mathrm {CH}}_{4}$ analyzer and a closed-path ${\mathrm {CH}}_{4}$ analyzer in a rice paddy field were evaluated with an emphasis on the flux correction methodology. A comparison of the fluxes obtained by the analyzers revealed that both the open-path and closed-path techniques were reliable, provided that appropriate corrections were applied. For the open-path approach, the influence of fluctuations in air density and the line shape variation in laser absorption spectroscopy (hereafter, spectroscopic effect) was significant, and the relative importance of these corrections would increase when observing small ${\mathrm {CH}}_{4}$ fluxes. A new procedure proposed by Li-Cor Inc. enabled us to accurately adjust for these effects. The high-frequency loss of the open-path ${\mathrm {CH}}_{4}$ analyzer was relatively large (11 % of the uncorrected covariance) at an observation height of 2.5 m above the canopy owing to its longer physical path length, and this correction should be carefully applied before correcting for the influence of fluctuations in air density and the spectroscopic effect. Uncorrected ${\mathrm {CH}}_{4}$ fluxes observed with the closed-path analyzer were substantially underestimated (37 %) due to high-frequency loss because an undersized pump was used in the observation. Both the bandpass and transfer function approaches successfully corrected this flux loss. Careful determination of the bandpass frequency range or the transfer function and the cospectral model is required for the accurate calculation of ${\mathrm {CH}}_{4}$ fluxes with the closed-path technique.     

Super-deep CTD measurements in the Izu-Ogasawara trench and a comparison of geostrophic shears with direct measurements

CTD (Conductivity-Temperature-Depth) data at five stations across the Izu-Ogasawara Trench at 34°N were examined. Geostrophic velocity was in accordance with the directly measured currents. Above the trench floor, potential temperature increased at a rate of 0.6 m°C/1000 db from 8000 db to 9417 db, and salinity increased from 8300 db to the bottom. Potential density was almost constant at 7100–8700 db, and it increased to the bottom. Above the eastern and western flanks, inversion of potential density was indicated in the bottom layers with an increase of potential temperature and a decrease of salinity, suggesting geothermal heating and outflow of ground water.     

Acid‐susceptive material as a host phase of argon‐rich noble gas in the carbonaceous chondrite Ningqiang

Abstract— A fine‐grained dark inclusion in the Ningqiang carbonaceous chondrite consists of relatively pristine solar nebular materials and has high concentrations of heavy primordial rare gases. Trapped 36Ar concentration amounts to 6 times 10^?6 cc STP/g, which is higher than that of Ningqiang host by a factor of three. Light HF‐HCl etching of the dark inclusion removed 86, 73, and 64% of the primordial ³⁶Ar, ⁸⁴Kr, and ¹³²Xe, respectively. Thus, the majority of the noble gases in this inclusion are located in very acid‐susceptive material. Based on the elemental composition, the noble gases lost from the dark inclusion during the acid‐treatments are Ar‐rich, and the noble gases remaining in the inclusion are Q and HL gases. Transmission electron microscopy showed that the acid treatments removed thin Si, Mg, and Fe‐rich amorphous rims present around small olivine and pyroxene grains in the dark inclusion, suggesting that the Ar‐rich gases reside in the amorphous layers. A possible origin of the Ar‐rich gases is the acquisition of noble‐gas ions with a composition fractionated relative to solar abundance favoring the heavy elements by the effect of incomplete ionization under plasma conditions at 8000 K electron temperature.     

Thinning of the near-earth (10∼15 RE) plasma sheet preceding the substorm expansion phase

The timing of the plasma-sheet thinning relative to the onset of the expansion phase of substorms is examined by the analysis of the OGO 5 electron (79 ± 23 keV) and proton (100～150 keV) data with the aid of simultaneous magnetic field observations. It is found that the timing of the thinning is significantly dependent on the distance. At $\text{x}{}^2\text{+ y}{}^2\text{? 15 R}{}_{\mathrm{E}}$ the thinning often starts before the onset, while at $\text{x}{}^2\text{+ y}{}^2\text{? 15 R}{}_{\mathrm{E}}$ it tends to occur after the onset, where x and y refer to solar magnetospheric coordinates. The thinning that precedes the expansion-phase onset has been found to reduce the thickness to ～1 R_E, and further thinning may occur in a spatially limited region. Hence it is conceivable that the formation of the neutral line characterizing the substorm expansion phase is the consequence of the thinning of the plasma sheet in the near-Earth region.     

Emission-line profiles from self-gravitating toroids around black holes

We have computed line profiles from self-gravitating toroids around black holes. The specific angular momentum of the toroids is assumed to be constant in space. The images of the toroids show peculiar features in the far sides of the black holes. Concerning the line profiles, the red wing extends to the very low frequency region because the location of the inner edge is rather near the event horizon of the black hole and consequently the velocity of the inner edges of the toroids can be greater than that of the Kepler discs.