Graphitization of carbonaceous matter during metamorphism with references to carbonate and pelitic rocks of contact and regional metamorphisms,Japan

This study is an attempt to correlate the graphitization process of carbonaceous matter during metamorphism with metamorphic grade. Graphitization can be parameterized using crystal structure and chemical and isotopic compositions. The extent of graphitization could be characterized mainly by temperature, duration of metamorphism and rock composition. We compared the graphitization trends for two metamorphic terrains, a contact aureole of the Kasuga area and a regional metamorphic terrain of high-temperature/low pressure type of the Ryoke metamorphic terrain in Northern Kiso area, Central Japan, and for two different lithologies (carbonate and pelite), using X-ray diffractogram, DTA-TG analysis, and chemical and stable isotope analyses. During contact metamorphism, graphitization and carbon isotopic exchange reactions proceeded simultaneously in pelitic and carbonate rocks. The decreases in basal spacing d(002) of the carbonaceous matter in carbonate rocks is greatly accelerated at temperatures higher than about 400° C. Furthermore, carbon isotopic ratios of graphite in carbonate rocks also change to ¹³C-enriched values implying exchange with carbonates. The beginning of this enrichment of ¹³C in the carbonaceous matter coincides with an abrupt increase of the graphitization processes. Carbon isotopic shifting up to 5 in pelites could be observed as metamorphic temperature increased probably by about 400° C. Carbonaceous matter in pelitic rocks is sometimes a mixture of poorly crystallized organic matter and well-crystallized graphite detritus. DTA-TG analysis is an effective tool for the distinction of detrital graphitic material. Two sources for the original carbon isotopic composition of carbonaceous matter in pelites in the Kasuga contact aureole can be distinguished, about-28 and-24 regardless of the presence of detrital graphite, and were mainly controlled by depositional environment of the sediments. Graphitization in limestones and pelitic rocks in regional metamorphism proceeds further than in a contact aureole. In the low-temperature range, the differences in extent of graphitization between the two metamorphic regions is large. However, at temperatures higher than 600° C, the extent of graphitization in both regions is indistinguishable. The degree of graphitization is different in limestones and pelitic rocks from the Ryoke metamorphic terrain. We demonstrate that the graphitization involves a progressive re-construction process of the crystal structure. The sequence of the first appearance of crystal inter planar spacing correlates with the metamorphic grade and indicates the crystal growth of three-dimensional structured graphite.     

Bottom currents in Nankai Trough and Sagami Trough

Mean flows and velocity fluctuations are described from direct measurements of bottom currents made at three stations across Nankai Trough and two stations in Sagami Trough from May 1982 to May 1984. Aanderaa current meters were moored 7 m above the bottom. The observed mean flows indicate a counter-clockwise circulation in Nankai Trough with current speeds of 0.9–2.1 cm sec^–1. The mean flows were larger on the slopes than on the flat bottom of the trough. The mean flows observed in Sagami Trough show an inflow into Sagami Bay which is considered to be a part of the Oyashio undercurrent from the north that flows along the eastern coast of Honshu. Velocity fluctuations with periods greater than 100 hr were less energetic in the troughs than those at a station west of Hachijo-jima Island. A highly energetic fluctuation with a period of 66.7 hr was observed on the northern slope of Sagami Trough in the velocity component parallel to the trough axis. A maximum current speed of 49 cm sec^–1 was observed in Sagami Trough.This study was sponsored by the Ministry of Education, Science and Culture, Japan.     

Measurements of ocean bottom pressure with a quartz sensor

Year long measurements of bottom pressure were made at 2,036 m depth in Sagami Trough, at 2,538 m depth in Suruga Trough, and at 32 m depth in the south of Minami-Daitojima Island. Amplitudes and phase lags of the major constituents of tides were estimated by the response method, and they were compared with the observational results at several tide stations operated by the Japan Meteorological Agency. A comparison with Schwiderski's global models for the eight tidal constituents showed that the amplitudes were in good accordance to one another within 3 cm, and that the differences of phase lags were less than 15°. The largest portion of the variations of the bottom pressure was caused by the tides: the variance of the major eight constituents was more than 98.5% as large as the total variance. The measurements show that tidal waves can be recorded offshore with a sufficient accuracy by the quartz sensors. Drifts of indication of the pressure gauges were significant and they prevented detection of a long-term variation which might be caused by fluctuations of the ocean currents or by the eddies.     

Slab rollback and microcontinent subduction in the evolution of the Zambales Ophiolite Complex(Philippines):A review

New radiolarian ages show that the island arc-related Acoje block of the Zambales Ophiolite Complex is possibly of Late Jurassic to Early Cretaceous age.Radiometric dating of its plutonic and volcanichypabyssal rocks yielded middle Eocene ages.On the other hand,the paleontological dating of the sedimentary carapace of the transitional mid-ocean ridge-island arc affiliated Coto block of the ophiolite complex,together with isotopic age datings of its dikes and mafic cumulate rocks,also yielded Eocene ages.This offers the possibility that the Zambales Ophiolite Complex could have:(1)evolved from a Mesozoic arc(Acoje block)that split to form a Cenozoic back-arc basin(Coto block),(2)through faulting,structurally juxtaposed a Mesozoic oceanic crust with a younger Cenozoic lithospheric fragment or(3)through the interplay of slab rollback,slab break-off and,at a later time,collision with a microcontinent fragment,caused the formation of an island arc-related ophiolite block(Acoje)that migrated trench-ward resulting into the generation of a back-arc basin(Coto block)with a limited subduction signature.This Meso-Cenozoic ophiolite complex is compared with the other oceanic lithosphere fragments along the western seaboard of the Philippines in the context of their evolution in terms of their recognized environments of generation.     

Direct correlation of radiolarian <Emphasis Type="Italic">Kilinora spiralis</Emphasis> Zone with the Late Jurassic ammonite faunal succession in the Kurisaka Formation,Kurosegawa Terrane,SW Japan

The last appearance datum of the radiolarian Kilinora spiralis is recorded above the first appearance datum of the ammonite Ataxioceras (A.) kurisakense in the Todoro Section of the Kurisaka Formation, Southern Kurosegawa Terrane, Shikoku, SW Japan. The constraint by ammonite age prolongs the range of the Kilinora spiralis Zone, a remarkable Jurassic radiolarian zone in Japan-NW Pacific region, into the lower Kimmeridgian. The direct correlation of the Kilinora spiralis zone with the Late Jurassic ammonite faunal succession in the Kurisaka Formation will provide a clue to the still pending chronological difference between European and North American radiolarian zones.     

Ore-forming mechanism for the Xiaoxinancha Au-rich Cu deposit in Yanbian,Jilin Province,China: Evidence from noble gas isotope geochemistry of fluid inclusions in minerals

The Xiaoxinancha Au-rich copper deposit is one of important Au-Cu deposits along the continental margin in Eastern China. The deposit consists of two sections: the Beishan mine (North), composed of altered rocks with veinlet-dissemination sulfides and melnicovite-dominated sulfide-quartz veins, and the Nanshan mine (South), composed of pyrrhotite-dominated sulfide-quartz veins and pure sulfide veins. The isotope compositions of noble gases extracted from fluid inclusions in ore minerals, i.e. ratios of 3He/4He, 20Ne/22Ne and40Ar/36Ar are in the ranges of 4.45―0.08 Ra, 10.2―8.8 and 306―430, respectively. Fluid inclusions in minerals from the Nanshan mine have higher 3He/4He and 20Ne/22Ne ratios whereas those from the Beishan mine have lower 3He/4He ratios. The analysis of origin, and evolution of the ore fluids and its relations with the ore-forming stages and the ages of mineralization suggests that the initial hydrothermal fluids probably come from the melts generated by partial melting of oceanic crust with the participation of fluids from the mantle (mantle-plume type)/aesthenosphere. This also corresponds to the continental margin settings during the subduction of Izanagi ocaneic plate towards the palaeo-Asian continent (123―102 Ma). The veinlet-dissemination ore bodies of the Beishan mine were formed through replacement and crystallization of the mixed fluids generated by mixing of the ascending high-temperature boiling fluid with young crustal fluid whereas the melnicovite-dominated sulfide-quartz veins were formed subsequently by filling of the high-temperature ore fluid in fissures. Pyrrhotite-dominated sulfide-quartz veins in the Nanshan mine were formed by filling-deposition-crystallization of the moderate-temperature ore fluids and the pure sulfide veins were formed later by filling-deposition-crystallization of ore substance-rich fluids after boiling of the moderate-temperature ore fluids. The metallogenic dynamic processes can be summarized as: (1) formation of fluidand ore substance-bearing Adakitic magma by degassing, dewatering and partial melting during subduction of the Izanagi plate; (2) separation and formation of ore fluids from the Adakitic magma; and (3) success-sive ascending of the ore fluids and final formation of the Au-rich Cu deposit of veinlet-dissemination and vein types by secondary boiling.     

Application of the Clean Development Mechanism in the Sanitation Sector: “Proof of Concept”

Greenhouse gas emissions from the waste sector account for only 4% of the total production, with wastewater management accounting for accurately 8 to 10% of this contribution. Wastewater disposal and treatment activities, mainly contributes to non‐CO₂ gases such as methane (CH₄) and nitrous oxide (N₂O). Capturing or avoiding these emissions is thus both a concern and an opportunity. The clean development mechanism (CDM) offers an instrument to internalize global climate concerns into the design of wastewater treatment facilities. Properly designed facilities could improve effluent quality and optimize the abatement of greenhouse gas emissions, thus ensuring additional revenues to pay for capital, operation and maintenance costs and possibly justify higher levels of wastewater treatment. This document summarizes the experience of the “Rio Frio CDM project” in Colombia, as an example of what is achievable through the CDM application in wastewater treatment upgrade in developing countries. This document summarizes the scope of the project, the methodology used to establish current greenhouse emissions and future reductions, and the estimated financial results.     

Development of a flood water level estimation method using satellite images and a digital elevation model for the Mekong floodplain

We have developed a flood water level estimation method that only employs satellite images and a DEM. The method involves three steps: (1) discriminating flood areas and identifying clumps of each flood area, (2) extracting the edges of the identified flood area using a buffering technique, and (3) performing spatial interpolation to transform the extracted elevation to flood water levels. We compared the estimated flood water levels with the observed ones. The RMSE using the RADARSAT was 1.99 and 1.30 m at river and floodplain points, respectively, whereas the RMSE using the MODIS was 4.33 and 1.33 m at the river and floodplain points, respectively. Given that most errors are attributed to the DEM, the method exhibited good performance. Furthermore, the method reproduced the flow directions and flood water level changes during the flooding period. Thus, we demonstrated that the characteristics of flood inundation can be understood even when ground observation data cannot be obtained.     

Cosmic‐ray exposure age and heliocentric distance of the parent body of the Rumuruti chondrite PRE 95410

We measured concentrations and isotopic ratios of noble gases in the Rumuruti (R) chondrite Mount Prestrud (PRE) 95410, a regolith breccia exhibiting dark/light structures. The meteorite contains solar and cosmogenic noble gases. Based on the solar and cosmogenic noble gas compositions, we calculated a heliocentric distance of its parent body, a cosmic‐ray exposure age on the parent body regolith (parent body exposure age), and a cosmic‐ray exposure age in interplanetary space (space exposure age) of the meteorite. Assuming a constant solar wind flux, the estimated heliocentric distance was smaller than 1.4 ± 0.3 au, suggesting inward migration from the asteroid belt regions where the parent body formed. The largest known Mars Trojan 5261 Eureka is a potential parent body of PRE 95410. Alternatively, it is possible that the solar wind flux at the time of the parent body exposure was higher by a factor of 2–3 compared to the lunar regolith exposure. In this case, the estimated heliocentric distance is within the asteroid belt region. The parent body exposure age is longer than 19.1 Ma. This result indicates frequent impact events on the parent body like that recorded for other solar‐gas‐rich meteorites. Assuming single‐stage exposure after an ejection event from the parent body, the space exposure age is 11.0 ± 1.1 Ma, which is close to the peak of ~10 Ma in the exposure age distribution for the solar‐gas‐free R chondrites.     

西南日本秋吉带石炭系高山(Ko-yama)灰岩群的褶皱构造

The study area is located in Kawakami-cho, Okayama Prefecture, which is occupied by Lower Carboniferous to Middle Permian Ko-yama Limestone Group (Yokoyama et al., 1979), Permian Yoshii Group (Sano et al., 1987) and Triassic Nariwa Group (Tera-oka, 1959). The Nariwa Group unconformably covers the Paleozoic successions (Otoh, 1985). These succes-sions belong to the Akiyoshi Belt. The Ko-yama Limestone Group is composed mainly of massive limestone, with basic volcanic rocks, acidic tuff and chert. The group was dated by foraminifer and fusu-linid as Lower Carboniferous to Middle Permian (Yo-koyama et al., 1979).