Depositional ramps: asymmetrical distribution structure in the Ata pyroclastic flow deposit,Japan

The asymmetrical distribution of the welded Ata large-scale pyroclastic flow deposit in Southern Kyushu, Japan was identified. This distribution pattern was defined as depositional ramps. Depositional ramps can be identified in valleys wider than 1 km and become smaller-scale with increasing distance from the source. Upslope directions of depositional ramps are generally radially away from the source caldera, suggesting that the structure was formed by the flow of pyroclastic material radially away from the source. The original depositional surface was reconstructed based on field mapping and density measurements of the pyroclastic flow deposit. Depositional ramps having a dip angle of more than 9° were reconstructed on the vent-facing slopes of the topography underlying the valley-filling deposits in the area within 10 km of the caldera rim. Such a dip angle is much larger than previously described dip angles. The size and gradient of the depositional ramps decreases with increasing distance from the source. Depositional ramps are recognized commonly in densely welded pyroclastic flow deposits. A high emplacement temperature is required to form the depositional ramps. This suggests that the pyroclastic flow was transported as a dense, fluidized layer to minimize heat loss.     

Pyrite of distinctive isotopic composition from the Hemlo deposit: A potential tool to identify this type of gold mineralization in Archean terrain

Most sulphides from various rock types and mineralization of Archean age exhibit sulphur isotope values (δ³⁴S) near 0‰. This is due to a general absence of conditions suitable for the oxidation-reduction reactions essential for isotopic fractionation. However, some important occurrences of Archean Au mineralization do display significant variations in δ³⁴S). One such occurrence with unusual isotopic compositions is the Hemlo gold deposit: pyrite from the ore typically has δ³⁴S < −6‰ to a minimum value of −17.5‰ The isotopic composition of the pyrite is correlated with the content of Au, indicating that they are genetically related.The sulphur isotope data suggest that sulphur compounds experienced redox reactions in the hydrothermal system at Hemlo and that sulphate was present prior to the Au mineralization. This sulphate may be of exogenic origin from a restricted basin, or of endogenic origin from magmatic-hydrothermal fluids. Other characteristic features of the deposit, such as enrichment in Sb, Tl and Hg, may also be explained by ore deposition under moderately oxidizing conditions.Distinctive δ³⁴S values were also observed in pyrite from Au mineralization at Heron Bay, 30 km west of Hemlo, and from baritic strata 21 to 27 km west and on approximate strike from Hemlo. These occurrences also represent sulphate-bearing hydrothermal systems and, as such, give distant information on the unusual environment of the mineralization at Hemlo. Since the isotopes of sulphur are sensitive to oxidation conditions they may be used to identify hydrothermal activities characteristic of this type of Au mineralization and to explore for other unusual areas of sulphate accumulation in Archean terrains.     

Ocean acidification and photic‐zone anoxia at the Toarcian Oceanic Anoxic Event: Insights from the Adriatic Carbonate Platform

Severe global climate change led to the deterioration of environmental conditions in the oceans during the Toarcian Stage of the Jurassic. Carbonate platforms of the Western Tethys Ocean exposed in Alpine Tethyan mountain ranges today offer insight into this period of environmental upheaval. In addition to informing understanding of climate change in deep time, the effect of ancient carbon cycle perturbations on carbonate platforms has important implications for anthropogenic climate change; the patterns of early Toarcian environmental deterioration are similar to those occurring in modern oceans. This study focuses on the record of the early Toarcian Oceanic Anoxic Event (ca 183.1 Ma) in outcrops of the north‐west Adriatic Carbonate Platform in Slovenia. Amidst environmental deterioration, the north‐west Adriatic Platform abruptly transitioned from a healthy, shallow‐water environment with diverse metazoan ecosystems to a partially drowned setting with low diversity biota and diminished sedimentation. An organic carbon‐isotope excursion of ?2.2‰ reflects the massive injection of CO₂ into the ocean‐atmosphere system and marks the stratigraphic position of the Toarcian Oceanic Anoxic Event. A prominent dissolution horizon and suppressed carbonate deposition on the platform are interpreted to reflect transient shoaling of the carbonate compensation depth to unprecedentedly shallow levels as the dramatic influx of CO₂ overwhelmed the ocean’s buffering capacity, causing ocean acidification. Trace metal geochemistry and palaeoecology highlight water column deoxygenation, including the development of photic‐zone anoxia, preceding and during the Toarcian Oceanic Anoxic Event. Ocean acidification and reduced oxygen levels likely had a profoundly negative effect on carbonate‐producing biota and growth of the Adriatic Platform. These effects are consistent with the approximate doubling of the concentration of CO₂ in the ocean‐atmosphere system from pre‐event levels, which has previously been linked to a volcanic triggering mechanism. Mercury enrichments discovered in this study support a temporal and genetic link between volcanism, the Toarcian Oceanic Anoxic Event and the carbonate crisis.     

Simultaneous seeing measurement through the Subaru Telescope in the visible and near-infrared bands for the wavelength dependence evaluation

Stellar images have been obtained under natural seeing at visible and near-infrared wavelengths simultaneously through the Subaru Telescope at Mauna Kea. The image quality is evaluated by the full-width at the half-maximum (FWHM) of the stellar images. The observed ratio of FWHM in the V-band to the K-band is 1.54 ± 0.17 on average. The ratio shows tendency to decrease toward bad seeing as expected from the outer scale influence, though the number of the samples is still limited. The ratio is important for simulations to evaluate the performance of a ground-layer adaptive optics system at near-infrared wavelengths based on optical seeing statistics. The observed optical seeing is also compared with outside seeing to estimate the dome seeing of the Subaru Telescope.     

Intergranular trace elements in mantle xenoliths from Russian Far East: Example for mantle metasomatism by hydrous melt

Based on both major and trace element chemistry, the occurrence of the intergranular component in mantle-derived xenoliths from far eastern Russia has been constrained. Whole-rock trace element measurements of one xenolith show apparent negative anomalies in Ce, Th, and high field strength elements on normalized trace element patterns. The trace element pattern of the whole rock differs from those of constituent minerals, indicating that the anomalies in the whole rock are attributable to the presence of an intergranular component. That assumption was confirmed using in situ analysis of trace elements in the intergranular substance and melt inclusion using laser ablation inductively coupled plasma–mass spectrometry. Both the intergranular component and the melt inclusions have identical trace element patterns, which mean that these materials are a cognate metasomatizing agent. The anomalies are regarded as mantle metasomatism related to an aqueous fluid. Hydrous minerals were observed on the wall of the melt inclusions using micro-Raman spectroscopy, indicating that the melt inclusions contained a large amount of water. Thus, this study reveals a trace element composition of a hydrous metasomatizing agent in the mantle.     

Compression mechanism and amorphization of portlandite, Ca(OH)2: structural refinement under pressure

In order to investigate compression mechanism and the pressure-induced amorphization of portlandite, Ca(OH)₂, the crystal structure has been refined up to 9.7?GPa using Rietveld analysis. Angular-dispersive synchrotron X-ray powder diffraction experiments were performed using a diamond anvil cell and an imaging plate at BL-18C in the Photon Factory at KEK, Japan. Compression behavior is highly anisotropic and the c axis is approximately 2.5 times as compressible as the a axis (β_a=0.004, β_c=0.011?GPa^?1). Because the refined fractional coordinate, z, of the O atom increases linearly with pressure, compression along the c axis is due to the shortening of the interlayer spacing. The compression mechanism shows no change up to the amorphization pressure and is basically the same as that of brucite, Mg(OH)₂, observed below 10 GPa. The octahedral regularity of CaO₆ approaches a regular configuration with pressure. The interlayer O…O distance is expected to be about 2.75 Å at the amorphization pressure and should affect hydrogen bonding.     

Coordinated mineralogical and isotopic analyses of a cosmic symplectite discovered in a comet 81P/Wild 2 sample

We have discovered in a Stardust mission terminal particle a unique mineralogical assemblage of symplectically intergrown pentlandite ((Fe,Ni)₉S₈) and nanocrystalline maghemite (γ‐Fe₂O₃). Mineralogically similar cosmic symplectites (COS) have only been found in the primitive carbonaceous chondrite Acfer 094 and are believed to have formed by aqueous alteration. The O and S isotopic compositions of the Wild 2 COS are indistinguishable from terrestrial values. The metal and sulfide precursors were thus oxidized by an isotopically equilibrated aqueous reservoir either inside the snow line, in the Wild 2 comet, or in a larger Kuiper Belt object. Close association of the Stardust COS with a Kool mineral assemblage (kosmochloric Ca‐rich pyroxene, FeO‐rich olivine, and albite) that likely originated in the solar nebula suggests the COS precursors also had a nebular origin and were transported from the inner solar system to the comet‐forming region after they were altered.     

Contribution of mafic melt to porphyry copper mineralization: evidence from Mount Pinatubo, Philippines, and Bingham Canyon, Utah, USA

Mount Pinatubo in the Philippines, known for its cataclysmic eruption in 1991, hosts several porphyry copper deposits and active geothermal systems. An underlying mafic melt supplied much of the sulphur for the dacitic magma and its injection into the dacitic magma chamber triggered the eruption. The eruption caused purging of the sulphur-rich fluid from the dacite to the atmosphere and extensive fracturing. Similar events took place at Bingham Canyon, Utah, site of the largest copper and gold deposit in North America at 38 Ma. The Bingham Canyon mineralization took place beneath an active stratovolcano and pyroclastic flows contemporaneous with the mineralization show evidence for magma mingling. Ascent of mafic melt supplied sulphur and chalcophile elements to the felsic magma, which consolidated to form the Bingham stock and its underlying magma chamber. Injections of the mafic melt caused periodic eruptions of felsic magma to form the stratovolcano and deposition of sulphide minerals in highly fractured rocks in and around the stock.     

Spatial distribution of organic matter in the Bells CM2 chondrite using near‐field infrared microspectroscopy

Abstract– Distributions of organic functional groups as well as inorganic features were analyzed in the Bells (CM2) carbonaceous chondrite using near‐field infrared (NFIR) spectroscopy. NFIR spectroscopy has recently been developed to enable infrared spectral mapping beyond the optical diffraction limit of conventional Fourier transform infrared microspectroscopy. NFIR spectral mapping of the Bells 300 nm thick sections on Al plates for 7.5 × 7.5 μm² areas showed some C‐H‐rich areas which were considered to represent the organic‐rich areas. Heterogeneous distributions of organic matter as well as those of inorganic phases such as silicates (Si‐O) were observed with 1 μm spatial resolution. The NFIR mappings of aliphatic C‐H (2960 and 2930 cm^?1) and structural OH (3650 cm^?1) confirm that organic matter is associated with phyllosilicates as previously suggested. The NFIR mapping method can provide 1 μm spatial distribution of organic functional groups and their association with minerals. High local sensitivity of NFIR enables us to find organic‐rich areas and to characterize them by their aliphatic CH₂/CH₃ ratios. The aliphatic CH₂/CH₃ ratio of Bells is slightly higher than Murchison, similar to Orgueil, and lower than literature values of IDPs and cometary dust particles.