Resource Evaluation and Some Genetic Aspects of Indium in the Japanese Ore Deposits

Abstract. There have been two primary sources for industrial indium; one from massive sulfides, while the other is dissemination-veins and skarns, related to felsic igneous rocks. The latter group of the In-bearing deposits is abundant in the Japanese Islands. Indium occurs as In-minerals such as sakuraiite, roquesite, laforetite and many unidentified minerals, but the majority is contained as an impurity in sphalerite, and tin and copper sulfides. Average grades of the ores from which indium has been extracted vary from a few ppm (e.g., Kosaka mine) to more than 300 ppm (Toyoha mine). The amount of indium in all the major basemetal deposits is estimated by analyzing representative samples. The main indium deposits are subvolcanic and tin-poly-metallic vein types. The largest one is Toyoha mine (4,700 tons hi) and the Ashio mine (ca. 1,200 tons In) was found to be the second largest. Many small occurrences, were recognized in the Miocene magnetite-series belt, besides the classic occurrences in the ilmenite-series granitic terrains of SW Japan, including the Ikuno and Akenobe tin(-tungsten) polymetallic veins, located in the northern margin of the late Cretaceous Sanyo ilmenite-series province. Magnetite-series magmas with deep source are necessary to concentrate sulfur in the magma chamber but sedimentary source rocks and their reducing agents are needed to collect and to precipitate indium. The Japanese islands are essentially accretionary terrains intruded by various deep oxidized magmas; thus forming magnetite/ilmenite-series paired belts, which are sometimes mixed. This unique geologic setting may be the most fundamental reason why indium is rich in vein-type deposits of the Japanese Island arcs.     

Relationship Between Solidification Depth of Granitic Rocks and Formation of Hydrothermal Ore Deposits

Chemical analysis of biotite in representative granitic rocks in Japan shows that the total Al (^TAl) content changes with the metal type of the accompanying hydrothermal ore deposits and increases in the following order: Pb‐Zn and Mo deposits < Cu‐Fe and Sn deposits < W deposits < non‐mineralized granitic rocks. The ^TAl content of biotite in granitic rocks may be a useful indicator for distinguishing between mineralized and non‐mineralized granitic rocks. A good positive correlation is seen between the ^TAl content of biotite and the solidification pressure of the granitic rocks estimated by sphalerite and hornblende geobarometers and the mineral assemblages of the surrounding rocks. These facts suggest that the ^TAl content of biotite can be used to estimate the solidification pressure (P) of the granitic rocks. The following empirical equation was obtained: where ^TAl designates the total Al content in biotite on the basis O = 22. According to the obtained biotite geobarometer, it is estimated that Pb‐Zn and Mo deposits were formed at pressures below 1 kb, Cu‐Fe and Sn deposits at 1–2 kb, W deposits at 2–3 kb and non‐mineralized granitic rocks were solidified at pressures above 3 kb.     

Probabilistic disaggregation of a spatial portfolio of exposure for natural hazard risk assessment

In natural hazard risk assessment situations are encountered where information on the portfolio of exposure is only available in a spatially aggregated form, hindering a precise risk assessment. Recourse might be found in the spatial disaggregation of the portfolio of exposure to the resolution of the hazard model. Given the uncertainty inherent to any disaggregation, it is argued that the disaggregation should be performed probabilistically. In this paper, a methodology for probabilistic disaggregation of spatially aggregated values is presented. The methodology is exemplified with the disaggregation of a portfolio of buildings in two communes in Switzerland and the results are compared to sample observations. The relevance of probabilistic disaggregation uncertainty in natural hazard risk assessment is illustrated with the example of a simple flood risk assessment.     

洪湖沉积物的磁性特征及其环境意义

以洪湖沉积物为研究对象,通过对Hh01-2(B)孔岩芯磁参数的测量发现在岩芯所代表的时间段内洪湖沉积物磁化率呈现了明显的四个主阶段变化;频率磁化率变化与磁化率变化具有较好的相关性,亚铁磁性矿物的变化主导了沉积物磁化率的变化.同时结合年代、孢粉分析以及参考相关历史记载资料,发现磁化率高值段对应湖水动力强、湖面较宽、气候较湿润,而磁化率低值段对应湖水动力弱、湖面较小、气候偏干旱.从而得出了洪湖沉积物磁参数曲线波峰和波谷分别对应洪湖在历史上曾经历了扩张和收缩、气候温湿和冷干的旋回.     

http://www.sciencedirect.com/science/article/pii/S1674987112000643

Incipient charnockites represent granulite formation on a mesoscopic scale and have received considerable attention in understanding fluid processes in the deep crust.Here we report new petrological data from an incipient charnockite locality at Rajapalaiyam in the Madurai Block,southern India,and discuss the petrogenesis based on mineral phase equilibrium modeling and pseudosection analysis. Rajapalaiyam is a key locality in southern India from where diagnostic mineral assemblages for ultrahigh-temperature（UHT） metamorphism have been reported.Proximal to the UHT rocks are patches and lenses of charnockite（Kfs + Qtz + Pl + Bt + Opx + Grt + Ilm） occurring within Opx-free Grt-Bt gneiss（Kfs + Pl + Qtz + Bt + Grt + Ilm + Mt） which we report in this study.The application of mineral equilibrium modeling on the charnockitic assemblage in NCKFMASHTO system yields a p-T range of～820℃and～9 kbar.Modeling of the charnockite assemblage in the MnNCKFMASHTO system indicates a slight shift of the equilibrium condition toward lower p and T（～760℃and～7.5 kbar）. which is consistent with the results obtained from geothermobarometry（710—760℃,6.7—7.5 kbar）. but significantly lower than the peak temperatures（>1000℃） recorded from the UHT rocks in this locality,suggesting that charnockitization is a post-peak event.The modeling of T versus molar H₂O content in the rock（M（H₂O）） demonstrates that the Opx-bearing assemblage in charnockite and Opxfree assemblage in Grt-Bt gneiss are both stable at M（H₂O） = 0.3 mol%-0.6 mol%.and there is no significant difference in water activity between the two domains.Our finding is in contrast to the previous petrogenetic model of incipient charnockite formation which envisages lowering of water activity and stabilization of orthopyroxene through breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid.T-X_Fe³⁺（= Fe₂O₃/（FeO + Fe₂O₃） in mole） pseudosections suggest that the oxidation condition of the rocks played a major role on the stability of orthopyroxene:Opx is stable at X_Fe³⁺ <0.03 in charnockite.while Opx-free assemblage in Grt-Bt gneiss is stabilized at X_Fe³⁺ >0.12.Such low oxygen fugacity conditions of X_Fe³⁺ <0.03 in the charnockite compared to Grt-Bt gneiss might be related to the infiltration of a reduced fluid（e.g.,H₂O + CH₄） during the retrograde stage.     

Impact of land-use changes on snow in a forested region with heavy snowfall in Hokkaido,Japan

Abstract

We simulated snow processes in a forested region with heavy snowfall in Japan, and evaluated both the regional-scale snow distribution and the potential impact of land-use changes on the snow cover and water balances over the entire domain. SnowModel reproduced the snow processes at open and forested sites, which were confirmed by snow water equivalent (SWE) measurements at two intensive observation sites and snow depth measurements at the Automated Meteorological Data Acquisition System sites. SnowModel also reproduced the observed snow distribution (from the MODIS snow cover data) over the simulation domain during thaw. The observed SWE was less at the forested site than at the open site. The SnowModel simulations showed that this difference was caused mainly by differences in sublimation. The type of land use changed the maximum SWE, onset and duration of snowmelt, and the daily snowmelt rate due to canopy snow interception.

Citation Suzuki, K., Kodama, Y., Nakai, T., Liston, G. E., Yamamoto, K., Ohata, T., Ishii, Y., Sumida, A., Hara, T. & Ohta, T. (2011) Impact of land-use changes in a forested region with heavy snowfall in Hokkaido, Japan. Hydrol. Sci. J. 56(3), 443–467.     

A simulation study of microstructure evolution inside the shear band in biaxial compression test

We study the development of microstructure inside the shear band in granular media consisting of elliptical‐shaped particles. Plane strain biaxial compression test was simulated using two‐dimensional distinct element method. The generation of large voids and concentration of excessive particle rotation inside a shear band are found in a quite similar manner to those observed in natural soils. Evolution of the microstructure inside and outside the shear band is studied. The magnitude and direction of particle rotation inside the shear band is influenced by orientation of long axes of elliptical particles. Because of such particle rotations inside the shear band, the preferred alignment of particles becomes horizontal in the residual state, which results in a more anisotropic contact normal distribution oriented along the major principal stress axis. Copyright © 2010 John Wiley & Sons, Ltd.     

Degree of impactor fragmentation under collision with a regolith surface—Laboratory impact experiments of rock projectiles

Some meteorites consist of a mix of components of various parent bodies that were presumably brought together by past collisions. Impact experiments have been performed to investigate the degree of target fragmentation during such collisions. However, much less attention has been paid to the fate of the impactors. Here, we report the results of our study of the empirical relationship between the degree of projectile fragmentation and the impact conditions. Millimeter‐sized pyrophyllite and basalt projectiles were impacted onto regolith‐like sand targets and an aluminum target at velocities of up to 960 m s^?1. Experiments using millimeter‐sized pyrophyllite blocks as targets were also conducted to fill the gap between this study and the previous studies of centimeter‐sized rock targets. The catastrophic disruption threshold for a projectile is defined as the energy density at which the mass of the largest fragment is the half of the original mass. The thresholds with the sand target were 4.5 ± 1.1 × 10⁴ and 9.0 ± 1.9 × 10⁴ J kg^?1, for pyrophyllite and basalt projectiles, respectively. These values are two orders of magnitude larger than the threshold for impacts between pyrophyllite projectiles onto aluminum targets, but are qualitatively consistent with the fact that the compressive and tensile strengths of basalt are larger than those of pyrophyllite. The threshold for pyrophyllite projectiles and the aluminum target agrees with the threshold for aluminum projectiles and pyrophyllite targets within the margin of error. Consistent with a previous result, the threshold depended on the size of the rocks with a power of approximately ?0.4 (Housen and Holsapple 1999). Destruction of rock projectiles occurred when the peak pressure was about ten times the tensile strength of the rocks.     

Hydrogeochemical controls and usability of groundwater in the semi-arid Mayo Tsanaga River Basin: far north province,Cameroon

Deuterium, δ ¹⁸O, major ions and dissolved silica in groundwater from semi-arid Mayo-Tsanaga river basin in the Far North Province, Cameroon were used to trace hydrogeochemical processes that control their concentrations and to explore for usability of the water. Electrical conductivity ranges from 57–2,581 μs/cm with alternating low and high values along the hydraulic gradient. Waters from piedmont alluvium show low concentrations in major cations, which peak in Mg within basalt, Na within plain alluvium, and Ca within basalt and the sandy Limani-Yagoua ridge. The initial dominant groundwater composition is CaHCO₃, which did not evolve within the basalt and piedmont alluvium, but evolved to NaHCO₃ in the granite and plain alluvium. The main processes controlling the major ions composition include the following: (1) dissolution of silicates and fluorite; (2) precipitation of fluorite and carbonate; (3) cation exchange of Ca in water for Na in clay; (4) and anthropogenic activities. The δD and δ ¹⁸O ratios vary from −35 to 0.7 and −5.3 to 1.1‰, respectively. The lowest and highest isotope ratios are observed in groundwater within the downstream sandy Limani-Yagoua ridge and the upstream graintes respectively. Variation in isotope ratios depends on altitude effect of −0.48‰ per 100 m between 600 and 850 m asl, and on evaporation, which had insignificant effect on the water salinity. Seventy percent of the groundwater shows poor drinking quality and 90% is suitable for irrigation. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.