Characteristics of the ratio of dissolved cadmium to phosphate in subtropical coastal waters of Ishigaki Island,Okinawa, Japan

The ratio of dissolved cadmium (Cd) to phosphate (PO₄) in the subtropical coastal area of Ishigaki Island, Okinawa, Japan, was investigated. Twenty vertical seawater samplings were carried out once a month from May 2008 to January 2010. In order to examine how the Cd/PO₄ ratio in seawater varies with the oceanographic conditions (i.e., the water temperature–salinity characteristics), the water masses at the study sites were classified into two types: group 1 with a water temperature of >25°C and a salinity range of 34.0–34.4, and group 2 with a water temperature of <25°C and a salinity of >34.4. A different phytoplankton assemblage was observed in each water mass defined. Different Cd/PO₄ ratios were obtained for the two water mass types, due to the differences between the types in terms of the environmental conditions such as the water temperature–salinity (T–S) characteristics and phytoplankton assemblages, as well as possible variations in the concentrations of dissolved iron, zinc, manganese, and CO₂ in seawater in each water mass.     

Tectonic evolution along the northernmost border of the Philippine Sea plate since about 1 Ma

Recent structural, tephrochronologic and magnetostratigraphic studies conducted along the northernmost border of the Philippine Sea (PHS) plate enable us to reconstruct the precise tectonic evolution along the convergent boundary between the PHS plate and the Northeast Japan (NEJ) plate or the North American (NAM) plate since about 1 Ma. The authors of the present study split the tectonic evolution into five stages and present the characteristics of each stage. A plate tectonic interpretation is proposed, based upon the tectonic evolution, with special reference to the mode of convergent motion. In brief, our interpretations are as follows: the relative motion between the PHS and the NEJ plates was not recognized geologically within the area studied from about 1.0 to 0.9 Ma (Stage 1), suggesting either none or small influence from the coupling between the two plates during that period of time. Convergence between the PHS and the NEJ plates was possibly in N-S direction from 0.9 to 0.5 Ma (Stage II), and probably north-northwestward since 0.5 Ma (Stages III to V). The mode of the convergent motion was that of buoyant subduction in Stages II and III. The mode changed gradually from buoyant subduction during Stage IV to collision in Stage V (0.07 Ma to the present).     

K-Ar dating studies of Ashigawa and Tokuwa granodiorite bodies and plutonic geochronology in the South Fossa Magna, central Japan

Abstract K-Ar age studies in the Ashigawa and the southern part of the Tokuwa granodioritic bodies, which consist of the southern part of the Kofu plutonic complex, revealed that they formed between 12 and 9 Ma. Quite a narrow range of ages obtained from the Ashigawa southernmost part of the Tokuwa pluton implies that they cooled rapidly. The southern part of the Tokuwa pluton, as a whole, shows a systematic age distribution with a decrease in age to the north. Compilation of currently available plutonic ages in the South Fossa Magna suggests that the plutonic activities occurred three times in this region. Episodic activity like this could be argued in relation to the tectonic development of this region.     

Generation of high resolution sea surface temperature using multi-satellite data for operational oceanography

In the present article, we introduce a high resolution sea surface temperature(SST) product generated daily by Korea Institute of Ocean Science and Technology(KIOST). The SST product is comprised of four sets of data including eight-hour and daily average SST data of 1 km resolution, and is based on the four infrared(IR) satellite SST data acquired by advanced very high resolution radiometer(AVHRR), Moderate Resolution Imaging Spectroradiometer(MODIS), Multifunctional Transport Satellites-2(MTSAT-2) Imager and Meteorological Imager(MI), two microwave radiometer SSTs acquired by Advanced Microwave Scanning Radiometer 2(AMSR2), and Wind SAT with in-situ temperature data. These input satellite and in-situ SST data are merged by using the optimal interpolation(OI) algorithm. The root-mean-square-errors(RMSEs) of satellite and in-situ data are used as a weighting value in the OI algorithm. As a pilot product, four SST data sets were generated daily from January to December 2013. In the comparison between the SSTs measured by moored buoys and the daily mean KIOST SSTs, the estimated RMSE was 0.71°C and the bias value was –0.08°C. The largest RMSE and bias were 0.86 and –0.26°C respectively, observed at a buoy site in the boundary region of warm and cold waters with increased physical variability in the Sea of Japan/East Sea. Other site near the coasts shows a lower RMSE value of 0.60°C than those at the open waters. To investigate the spatial distributions of SST, the Group for High Resolution Sea Surface Temperature(GHRSST) product was used in the comparison of temperature gradients, and it was shown that the KIOST SST product represents well the water mass structures around the Korean Peninsula. The KIOST SST product generated from both satellite and buoy data is expected to make substantial contribution to the Korea Operational Oceanographic System(KOOS) as an input parameter for data assimilation.     

Fluid inclusion and stable isotope (O, H, C, and S) constraints on the genesis of the Serrinha gold deposit, Gurupi Belt, northern Brazil

The Serrinha gold deposit of the Gurupi Belt, northern Brazil, belongs to the class of orogenic gold deposits. The deposit is hosted in highly strained graphitic schist belonging to a Paleoproterozoic (∼2,160 Ma) metavolcano-sedimentary sequence. The ore-zones are up to 11 m thick, parallel to the regional NW–SE schistosity, and characterized by quartz-carbonate-sulfide veinlets and minor disseminations. Textural and structural data indicate that mineralization was syn- to late-tectonic and postmetamorphic. Fluid inclusion studies identified early CO₂ (CH₄-N₂) and CO₂ (CH₄-N₂)-H₂O-NaCl inclusions that show highly variable phase ratios, CO₂ homogenization, and total homogenization temperatures both to liquid and vapor, interpreted as the product of fluid immiscibility under fluctuating pressure conditions, more or less associated with postentrapment modifications. The ore-bearing fluid typically has 18–33mol% of CO₂, up to 4mol% of N₂, and less than 2mol% of CH₄ and displays moderate to high densities with salinity around 4.5wt% NaCl equiv. Mineralization occurred around 310 to 335°C and 1.3 to 3.0 kbar, based on fluid inclusion homogenization temperatures and oxygen isotope thermometry with estimated oxygen fugacity indicating relatively reduced conditions. Stable isotope data on quartz, carbonate, and fluid inclusions suggest that veins formed from fluids with δ¹⁸O_H2O and δD_H2O (310–335°C) values of +6.2 to +8.4‰ and −19 to −80‰, respectively, which might be metamorphic and/or magmatic and/or mantle-derived. The carbon isotope composition (δ¹³C) varies from −14.2 to −15.7‰ in carbonates; it is −17.6‰ in fluid inclusion CO₂ and −23.6‰ in graphite from the host rock. The δ³⁴S values of pyrite are −2.6 to −7.9‰. The strongly to moderately negative carbon isotope composition of the carbonates and inclusion fluid CO₂ reflects variable contribution of organic carbon to an originally heavier fluid (magmatic, metamorphic, or mantle-derived) at the site of deposition and sulfur isotopes indicate some oxidation of the originally reduced fluid. The deposition of gold is interpreted to have occurred mainly in response to phase separation and fluid-rock interactions such as CO₂ removal and desulfidation reactions that provoked variations in the fluid pH and redox conditions.     

Estimation of nearshore groundwater discharge and its potential effects on a fringing coral reef

Radon (²²²Rn) measurements were conducted in Shiraho Reef (Okinawa, Japan) to investigate nearshore submarine groundwater discharge (SGD_nearshore) dynamics. Estimated average groundwater flux was 2-3 cm/h (maximum 7-8 cm/h). End-member radon concentration and gas transfer coefficient were identified as major factors influencing flux estimation accuracy. For the 7-km long reef, SGD_nearshore was 0.39-0.58 m³/s, less than 30% of Todoroki River’s baseflow discharge. SGD_nearshore was spatially and temporally variable, reflecting the strong influence of subsurface geology, tidal pumping, groundwater recharge, and hydraulic gradient. SGD_nearshore elevated nearshore nitrate concentrations (0.8-2.2 mg/l) to half of Todoroki River’s baseflow -N (2-4 mg/L). This increased nearshore Chl-a from 0.5-2 μg/l compared to the typically low Chl-a (<0.1-0.4 μg/l) in the moat. Diatoms and cyanobacteria concentrations exhibited an increasing trend. However, the percentage contributions of diatoms and cyanobacteria significantly decreased and increased, respectively. SGD may significantly induce the proliferation of cyanobacteria in nearshore reef areas.     

Seismic response control using electromagnetic inertial mass dampers

This paper presents a new type of electromagnetic damper with rotating inertial mass that has been developed to control the vibrations of structures subjected to earthquakes. The electromagnetic inertial mass damper (EIMD) consists of a ball screw that converts axial oscillation of the rod end into rotational motion of the internal flywheel and an electric generator that is turned by the rotation of the inner rod. The EIMD is able to generate a large inertial force created by the rotating flywheel and a variable damping force developed by the electric generator. Device performance tests of reduced‐scale and full‐scale EIMDs were undertaken to verify the basic characteristics of the damper and the validity of the derived theoretical formulae. Shaking table tests of a three‐story structure with EIMDs and earthquake response analyses of a building with EIMDs were conducted to demonstrate the seismic response control performance of the EIMD. The EIMD is able to reduce story drifts as well as accelerations and surpasses conventional types of dampers in reducing acceleration responses. Copyright © 2013 John Wiley & Sons, Ltd.     

The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.     

Cohesive zone length of metagabbro at supershear rupture velocity

We investigated the shear strain field ahead of a supershear rupture. The strain array data along the sliding fault surfaces were obtained during the large-scale biaxial friction experiments at the National Research Institute for Earth Science and Disaster Resilience. These friction experiments were done using a pair of meter-scale metagabbro rock specimens whose simulated fault area was 1.5 m?×?0.1 m. A 2.6-MPa normal stress was applied with loading velocity of 0.1 mm/s. Near-fault strain was measured by 32 two-component semiconductor strain gauges installed at an interval of 50 mm and 10 mm off the fault and recorded at an interval of 1 MHz. Many stick-slip events were observed in the experiments. We chose ten unilateral rupture events that propagated with supershear rupture velocity without preceding foreshocks. Focusing on the rupture front, stress concentration was observed and sharp stress drop occurred immediately inside the ruptured area. The temporal variation of strain array data is converted to the spatial variation of strain assuming a constant rupture velocity. We picked up the peak strain and zero-crossing strain locations to measure the cohesive zone length. By compiling the stick-slip event data, the cohesive zone length is about 50 mm although it scattered among the events. We could not see any systematic variation at the location but some dependence on the rupture velocity. The cohesive zone length decreases as the rupture velocity increases, especially larger than \( \sqrt{2} \) times the shear wave velocity. This feature is consistent with the theoretical prediction.