Petrogenesis of the EET 92023 achondrite and implications for early impact events

We report petrology and geochemistry of an achondrite EET 92023 and compare it with normal and anomalous eucrites. EET 92023 is an unbrecciated achondrite and shows a granular texture mainly composed of low‐Ca pyroxene and plagioclase, petrologically similar to normal cumulate eucrites such as Moore County. However, this rock contains a significant amount of kamacite and taenite not common in unbrecciated, crystalline eucrites. EET 92023 contains a significant amount of platinum group elements (PGEs) (ca. 10% of CI), several orders of magnitude higher than those of monomict eucrites. We suggest that the metallic phases carrying PGEs were incorporated by a projectile during or before igneous crystallization and thermal metamorphism. The projectile was likely to be an iron meteorite rather than chondritic materials, as indicated by the lack of olivine and the presence of free silica. Therefore, the oxygen isotopic signature is indigenous, rather than due to contamination of the projectile material with different oxygen isotopic compositions. A significant thermal event involving partial melting and metamorphism after the impact event indicates that EET 92023 records early impact events which took place shortly after the crust formation on a differentiated protoplanet when the crust was still hot.     

Three‐dimensional texture of natural pseudotachylyte: Pseudotachylyte formation mechanism in hydrous accretionary complex

Melt‐origin pseudotachylyte is the most reliable seismogenic fault rock. It is commonly believed that pseudotachylyte generation is rare in the plate subduction zone where interstitial fluids are abundant and can trigger dynamic fault‐weakening mechanisms such as thermal pressurization. Some recent studies, however, have discovered pseudotachylyte‐bearing faults in exhumed ancient accretionary complexes, indicating that frictional melting also occurrs during earthquakes in subduction zones. To clarify the pseudotachylyte generation mechanism and the variation of slip behavior in the plate subduction zone, a pseudotachylyte found in the exhumed fossil accretionary complex (the Shimanto Belt, Nobeoka, Japan) was re‐focused and microscopic and three‐dimensional observations of the pseudotachylyte‐bearing fault were performed based on optical, electron, and X‐ray microscope images. Based on the patterns contained in the fragment, the pseudotachylyte is divided into four domains, although no clear domain boundaries or layering structures are not found. Three‐dimensional observation also suggests that the pseudotachylyte were fragmented or isolated by cataclasite or carbonate breccia. The pseudotachylyte was rather injected into the surrounding carbonate breccia, which is composed of angular fragments of the host rock and a matrix of tiny crystalline carbonate. The pseudotachylyte volume was extracted from the X‐ray microscope image and the heat abundance consumed by the pseudotachylyte generation was estimated at 2.18 MJ/m², which can be supplied during a slip of approximately 0.5 m. These observations and calculations, together with the results of the previous investigations, suggest hydrofracturing and rapid carbonate precipitation that preceded or accompanied the frictional melting. Dynamic hydrofracturing during a slip can be caused by rapid fluid pressurization, and can induce abrupt decrease in fluid pressure while drastically enhancing the shear strength of the shear zone. Consequently, frictional heating would be reactivated and generate the pseudotachylyte. These deformation processes can explain pseudotachylyte generation in hydrous faults with the impermeable wall rock.     

Experimental study on the collisional disruption of porous gypsum spheres

Abstract— In order to study the catastrophic disruption of porous bodies such as asteroids and planetesimals, we conducted several impact experiments using porous gypsum spheres (porosity: 50%). We investigated the fragment mass and velocity of disrupted gypsum spheres over a wide range of specific energies from 3 times 10³ J/kg to 5 times 10⁴ J/kg. We compared the largest fragment mass (m₁/M_t) and the antipodal velocity (V_a) of gypsum with those of non‐porous materials such as basalt and ice. The results showed that the impact strength of gypsum was notably higher than that of the non‐porous bodies; however, the fragment velocity of gypsum was slower than that of the non‐porous bodies. This was because the micro‐pores dispersed in the gypsum spheres caused a rapid attenuation of shock pressure in them. From these results, we expect that the collisional disruption of porous bodies could be significantly different from that of non‐porous bodies.     

A Low-Power High-Resolution Broad-Band Radar Using a Pulse Compression Technique for Meteorological Application

A new high-resolution Ku-band Doppler radar for meteorological applications has been developed. With the new system design, the radar can accurately measure the radar reflectivity factor with 4-m resolution over a range from 40 m to several kilometers for 100-mW power using a pulse compression technique. Details of the system design, signal processing algorithm, and data acquisition procedures are described. To demonstrate the accuracy of the system, the radar reflectivity measurements are compared with the Joss-Waldvogel disdrometer measurements, and fairly good agreement is shown. The ability of the system to capture the backscattered signal and Doppler spectrum from rain volume at low altitude with high resolution is demonstrated for both convective- and stratiform-type rain events.     

Phosphorus sorption from aqueous solution using natural materials

The sorption of phosphorus by using four different natural materials (marble dust, sawdust, soil, and rice husk) was studied by conducting batch tests and kinetic sorption model. The kinetic sorption model based on a pseudo equation was applied to predict the rate constant of sorption. Thorough investigations to understand the mechanism of phosphorus sorption onto the natural materials using kinetic sorption models, pseudo first- and second-order kinetic sorption model showed that the kinetic sorption is consistent with the second-order model, from which it can be inferred that the mechanism of sorption is chemisorption. Batch tests and kinetic sorption model results showed that by using marble dust as sorbent, among other materials, could remove more than 93 % of phosphorus from aqueous solution.     

Fossil fluid reservoir beneath a duplex fault structure within the Central Range of Taiwan: implications for fluid leakage and lubrication during earthquake rupturing process

In order to understand the kinematics which likely facilitated the speedy rupturing process of the 1999 Mw 7.6 Taiwan Chi-Chi earthquake, we examined exposed rocks in the Taiwan Slate belt, where the pressure and temperature conditions most resembled the hypocentre of the Chi-Chi earthquake, i.e. sub-greenschist facies. Field observations and composition analyses of the silicified vein-rich zones beneath the duplex structure suggest that impermeable slate layers may serve as cap rocks for confining deep-seated fluids. These fluids most likely come from the Taiwan metamorphic complex at deeper depths by the dehydration and decarbonation reactions (or partial melting). In addition, the gouge zone of a link fault above the detachment also indicates the presence of overpressured fluids during faulting. It is probable that episodic leakage of the confined fluid reservoirs may provide essential fluids for fault lubrication during earthquake ruptures.     

A comparison of techniques for hydrograph recession analysis

A comparison between commonly used techniques for hydrograph recession analysis, namely the semi‐logarithmic plot of a single recession segment, the master recession and a relatively new approach based on wavelet transform was carried out. These methods were applied to a number of flood hydrograph events of two catchments in West Java, Indonesia. The results show that all the methods tested produce reasonable and comparable results. However, problems arise in the semi‐logarithmic plot and the master recession, i.e. determining the recession parameter K is not an easy task especially where the plotted data on a semi‐logarithmic plot is not a linear but a curved line. On a curved line, the end of direct flow or starting point of baseflow is not clear and it is quite difficult to identify. Hence, the best line as a basis for computing the recession parameter K becomes uncertain. The wavelet transform approach, however, produces promising results and minimizes a number of problems associated with hydrograph recession analysis. The end of direct flow and the location of the baseflow component are easily determined through the wavelet maps. Copyright © 2004 John Wiley & Sons, Ltd.     

Measurements in a heated turbulent wall jet on a concave wall

The paper contains the results of extensive single-point hot-wire and resistance-thermometer measurements in a wall jet on a heated concave wall with an external free stream. It is found that the turbulence in the inner (wall) and outer layers is sensitive to the distortion produced by the curved wall, broadly confirming current views of these effects. The effect on the turbulence of streamline curvature is stabilising in the outer layer, destabilising in the inner. Consequently the point of zero shear stress is closer to the point of maximum mean velocity than in flat and convex wall jets with which these new results are compared. The rate of growth is about 80% of that of the equivalent flat wall flow, and about half that of the convex wall flow. Changes in the wall shear stress and heat flux, which are increased relative to the flat wall flow, are significant but less than the changes in the corresponding convex wall flow. The greatest changes occur in the triple products.List of Symbols c _f skin friction coefficient, 2 _w / U _M ² - q ² u ² +v ²+w ² - R radius of curvature of wall - r radius of curvature - St Stanton number,-q _w /c _p U _M (T –T _w ) - T mean temperature - U streamwise mean velocity - U _J initial wall-jet velocity - U ₁ initial free-stream velocity - U ₀ U _M –U _PW - u, v, w fluctuating velocity components - x, y distances measured along and normal to the wall - y _0.5,y _M wall-jet thicknesses defined in the text - y _S ,y _T wall-jet thicknesses defined in the text - T T _W –T - shear-layer thickness - ₂ momentum thickness - temperature fluctuation - M point of maximum velocity - P potential flow - s point of zero shear stress - W wall value - free stream value     

Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.     

Nutrient and Plankton Dynamics in the NE and NW Gyres of the Subarctic Pacific Ocean

The western subarctic gyre (WSG) and the eastern Alaska Grye (AG) on each side of the subarctic North Pacific, have many similarities. In both gyres, macronutrients are generally high and chl is low, and hence both gyres are High Nitrate, Low Chlorophyll (HNLC) regions. Despite the general similarities between these two gyres, there are many important differences. The time series station established at Stn KNOT on the southwest edge of the WSG and two in situ mesoscale iron enrichment experiments at each of the gyres has provided more information on iron concentrations, the dual role of iron and silicate limitation and seasonal cycles in the gyres. There is more seasonality in many parameters at Stn KNOT than at Stn P. There is an increase in Chl and primary productivity at Stn KNOT in May followed by increased iron limitation in summer. Low DIC:NO₃ ratios and high Si:NO₃ ratios in the WSG, indicate lower calcification and higher diatom production than at Stn P. The sources of iron for these areas are still not clear, but horizontal transport of iron rich coastal water and vertical transport could be important sources at certain times of the year in addition to dust input. Satellite images show that chl-rich coastal waters occasionally extend to the vicinity of Stn KNOT and therefore Stn KNOT may not always represent conditions in the main part of the WSG. This review focuses mainly on a comparison of Stn KNOT and Stn P, two time series stations on the edge of two very large gyres. At present, we have a limited understanding of the temporal and spatial variability within each of these large gyres. This revised version was published online in July 2006 with corrections to the Cover Date.