Geochemical changes during neutralisation of acid mine drainage in a dynamic mountain stream, New Zealand

The Mangatini Stream drains a coal mining area in the mountains of northwestern South Island of New Zealand. Abundant rainfall on pyritic rocks yields acid mine drainage (AMD) to the stream, which flows through a steep gorge at discharges that rapidly increase from <1 to >100 m³/s during frequent rain events. The AMD is treated with finely ground limestone, which is discharged as a slurry at a point in the middle of the gorge. The limestone slurry mixes and reacts with the AMD during flow ∼4 km downstream over ∼12 h. Neutralisation reactions increase stream pH from near 3 (untreated Mangatini Stream water impacted by AMD) to 5–6 in the first 250 m downstream, although mixing is commonly incomplete in this zone. Large stream discharge volumes in rain events dilute the neutralising material input, thus driving the pH back towards 4 downstream of treatment. More complete neutralisation is achieved 4 km downstream, even in major rain events, and pH can rise to >7. Partial neutralisation is sufficient to remove most of the dissolved Fe(III) (typically ∼30 mg/L) from the Mangatini Stream in the first 10 m, and remaining dissolved Fe is essentially all Fe(II), which decreases over time as it oxidises and precipitates. Dissolved Al in the Mangatini Stream (typically ∼50 mg/L) decreases steadily downstream over ∼100 m in the limestone mixing zone. Precipitated Fe and Al form amorphous oxyhydroxides that are transported as suspended solids and deposited on the stream bed with excess limestone in zones of low flow velocity. Dissolved Zn is removed from solution by adsorption to Fe oxyhydroxide when pH reaches ∼5, but dissolved Ni remains in solution despite the neutralisation process. Gypsum precipitation occurs throughout the limestone mixing zone, resulting in at least 30% decrease in dissolved . Minor ettringite forms in the first 100 m, but then probably redissolves. The limestone dosing system is an effective method of neutralising the effects of AMD and removing most dissolved metals in a steep mountain stream with frequent rain events where this dynamic environment places many constraints on treatment options.     

Fault zone hydrogeology in arid environments: The origin of cold springs in the Wadi Araba Basin,Egypt

The role of faults in controlling groundwater flow in the Sahara and most of the hyper-arid deserts is poorly understood due to scarcity of hydrological data. The Wadi Araba Basin (WAB), in the Eastern Sahara, is highly affected by folds and faults associated with Senonian tectonics and Paleogene rifting. Using the WAB as a test site, satellite imagery, aeromagnetic maps, field observations, isotopic and geochemical data were examined to unravel the structural control on groundwater flow dynamics in the Sahara. Analysis of satellite imagery indicated that springs occur along structurally controlled scarps. Isotopic data suggested that cold springs in the WAB showed a striking similarity with the Sinai Nubian aquifer system (NAS) water and the thermal springs along the Gulf of Suez (e.g., δ¹⁸O = −8.01‰ to −5.24‰ and δD = −53.09‰ to −31.12‰) demonstrating similar recharge sources. The findings advocated that cold springs in the WAB represent a natural discharge from a previously undefined aquifer in the Eastern Desert of Egypt rather than infiltrated precipitation over the plateaus surrounding the WAB or through hydrologic windows from deep crystalline basement flow. A complex role of the geological structures was inferred including: (1) channelling of the groundwater flow along low-angle faults, (2) compartmentalization of the groundwater flow upslope from high-angle faults, and (3) reduction of the depth to the main aquifer in a breached anticline setting, which resulted in cold spring discharge temperatures (13–22°C). Our findings emphasize on the complex role of faults and folds in controlling groundwater flow, which should be taken into consideration in future examination of aquifer response to climate variability in the Sahara and similar deserts worldwide.     

The Arctic’s rapidly shrinking sea ice cover: a research synthesis

The sequence of extreme September sea ice extent minima over the past decade suggests acceleration in the response of the Arctic sea ice cover to external forcing, hastening the ongoing transition towards a seasonally open Arctic Ocean. This reflects several mutually supporting processes. Because of the extensive open water in recent Septembers, ice cover in the following spring is increasingly dominated by thin, first-year ice (ice formed during the previous autumn and winter) that is vulnerable to melting out in summer. Thinner ice in spring in turn fosters a stronger summer ice-albedo feedback through earlier formation of open water areas. A thin ice cover is also more vulnerable to strong summer retreat under anomalous atmospheric forcing. Finally, general warming of the Arctic has reduced the likelihood of cold years that could bring about temporary recovery of the ice cover. Events leading to the September ice extent minima of recent years exemplify these processes.     

Microbial remains in some earliest Earth rocks: Comparison with a potential modern analogue

Carbonaceous matter (CM) from ca. 3.5 Ga hydrothermal black cherts of the Pilbara Craton of Western Australia and the Barberton Greenstone Belt of South Africa yielded transmission electron microscopy (TEM) images that are suggestive of microbial remains and possible remnants of microbial cell walls. These are compared to a potential modern analogue, the hyperthermophilic Methanocaldococcus jannaschii, derived from an active seafloor hydrothermal environment and cultured under similar conditions. A striking resemblance to the early Archaean forms was evident in wall structure and thermal degradation mode. Cell disintegration of the cultures occurred at 100 °C marking the limits of life. Complete disintegration, deformation and shrinkage occurred at 132 °C. A multidisciplinary approach to the characterisation of the CM was undertaken using organic petrology, TEM coupled with electron dispersive spectral analysis (EDS), high resolution TEM (HRTEM) to determine molecular ordering, and elemental and carbon isotope geochemistry. Reflectance measurements of the CM to determine thermal stress yielded a range of values corresponding to several populations, and pointing to different sources and processes. The δ¹³C values of Dresser Formation CM (−36.5 to −32.1‰) are negatively correlated with TOC (0.13–0.75%) and positively correlated with C/N ratio (134–569), which is interpreted to reflect the relative abundance of high R_o/oxidised/recycled CM and preferential loss of ¹²C and N during thermal maturation. TEM observations, inferred carbon isotopic heterogeneity and isotope fractionations of −27 to −32‰ are consistent with the activity of chemosynthetic microbes in a seafloor hydrothermal system where rapid silicification at relatively low temperature preserved the CM.     

Botryococcus—A planktonic green alga, the source of petroleum through the ages: Transmission electron microscopical studies of oil shales and petroleum source rocks

The hydrocarbon secreting alga Botryococcus has been identified in organic remains of sediments ranging from Precambrian to Recent, and is believed to have been a major source material for petroleum generation throughout the geological time. In some petroleum source rocks of Lower Palaeozoic and Precambrian age, identification of the alga is only possible by electron microscopy. Transmission electron microscopy (TEM) has been used in the present study to identify microstructures of the algal remains in a range of oil shales and petroleum source rocks. It has been established that Botryococcus is the predominant alga in the Kukersite oil shale of Estonia. Similarly, the alga has been shown to be a major contributor to petroleum source rocks in Cambrian and Precambrian sedimentary basins in Australia. TEM has been applied to observations of Botryococcus in torbanites and to products from simulated maturation experiments on torbanite. A comparison with algal remains from Cambrian and Precambrian sediments ranging from undermature to overmature, enabled the distinction of organic matter in various stages of oil generation. Maturation/thermal effects on alginite have been established by reflectance and fluorescence, and compared with experimental results.     

North Sea near-surface wind climate and its relation to the large-scale circulation patterns

The North Sea 10-m wind speed (WS10) climate is compared and related to circulation patterns based on the sea level pressure (SLP) extracted from three reanalysis and one high-resolution model dataset. The mean magnitude and the trends of WS10 depend considerably on the selected reanalysis. The variability of WS10 among the three reanalysis datasets is highly correlated in the recent period (1980–2000) but less so in the past period (1960–1980). The WS10 over the North Sea is well represented by the relatively low reanalysis resolution when compared to the high-resolution WS10 model data partially owing to the high spatial correlation of WS10. Exceptions are observed only at the coastal areas. The dominant mode of WS10 explains coherent variability of WS10 over the North Sea and is related to a SLP pattern similar to the North Atlantic oscillation (NAO). The increase of the magnitude of the dominant WS10 pattern is related to the increase of the magnitude of the NAO-like SLP pattern from 1960s to mid-1990s. The second dominant WS10 pattern—a dipole in WS10 to the north and south of Great Britain—is related to the differences in SLP between Scandinavia and Iceland. The relation between the second WS10 and SLP patterns is more prominent in the recent period. The extreme WS10 in the German Bight is related to the low SLP over Scandinavia. The extreme WS10 is strongly increasing from the early 1980s to the beginning of 1990s, which is not observed in the corresponding SLP time series over Scandinavia.     

Conjoint analysis of small‐boat recreational fishers in New Zealand

Conjoint analysis is a useful technique to assist recreational managers formulate policy, and develop strategies to efficiently and effectively distribute resources. Accurate estimates of the value of natural resources remain challenging, despite the development of a number of decision analysis techniques. This recreation geography study uses conjoint analysis to examine the relative importance of attributes associated with small‐boat recreational fishing experiences and demonstrates the value of conjoint analysis as a non‐market valuation tool. We found that the choices associated with companionship are the most important factors of recreational fishing and more tangible attributes such as the quality of launch facilities and catch probability are the least important factors.     

Delineating extent and magnitude of river flooding to lakes across a northern delta using water isotope tracers

Hydrological monitoring in complex, dynamic northern floodplain landscapes is challenging, but increasingly important as a consequence of multiple stressors. The Peace-Athabasca Delta in northern Alberta, Canada, is a Ramsar Wetland of International Importance reliant on episodic river ice-jam flood events to recharge abundant perched lakes and wetlands. Improved and systematic monitoring of landscape-scale hydrological connectivity among freshwater ecosystems (rivers, channels, wetlands, and lakes) is needed to guide stewardship decisions in the face of climate change and upstream industrial development. Here, we use water isotope compositions, supplemented by measurements of specific conductivity and field observations, from 68 lakes and 9 river sites in May 2018 to delineate the extent and magnitude of spring ice-jam induced flooding along the Peace and Athabasca rivers. Lake-specific estimates of input water isotope composition (δ_I) were modelled after accounting for influence of evaporative isotopic enrichment. Then, using the distinct isotopic signature of input water sources, we develop a set of binary mixing models and estimate the proportion of input to flooded lakes attributable to river floodwater and precipitation (snow or rain). This approach allowed identification of areas and magnitude of flooding that were not captured by other methods, including direct observations from flyovers, and to demarcate flow pathways in the delta. We demonstrate water isotope tracers as an efficient and effective monitoring tool for delineating spatial extent and magnitude of an important hydrological process and elucidating connectivity in the Peace-Athabasca Delta, an approach that can be readily adopted at other floodplain landscapes.