Yellow fluorescence from baghdadite and synthetic Ca3(Zr,Ti)Si2O9

Baghdadite from Fuka, Okayama Prefecture, Japan shows a bright yellow fluorescence under UV (Hg 253.7 nm) excitation. The photoluminescence (PL) spectrum at 300 K consists of one large band near 580 nm and two small UV bands at 318 and 397 nm. The optical excitation spectrum of the bright yellow fluorescence consists of two bands near 220 and 250 nm. The temperature dependence of the PL intensity exhibits linear thermal quenching. To reveal the origin of the bright yellow fluorescence from baghdadite, powder Ca₃(Zr,Ti)Si₂O₉ crystals are synthesized. Synthetic Ca₃(Zr,Ti)Si₂O₉ shows luminescence spectra similar to those of baghdadite, and the intensity of the yellow fluorescence is markedly increased by titanium addition. The origin of the bright yellow fluorescence from baghdadite is ascribed to the existence of titanium.     

Phase disturbance of 100-kHz groundwaves by a circular island in the open sea

The hyperbolic position fixing of ships by the Decca navigation system utilizes groundwave propagation. But the hyperbolic pattern will be disturbed by an isolated island. The instantaneous phase velocity and the bearing error are calculated from the equiphase lines near the island. It is found numerically and experimentally that the hyperbolic pattern is bent towards the island that is situated on the baseline between the master station and the slave one.     

The role of pore water in the mechanical behavior of unsaturated soils

Deformation and failure of soils are governed by the stresses acting on the soil skeleton. The isotropic stress acting on the soil skeleton can be divided into two components. One is the stress component which is transmitted through the soil skeleton. This skeleton stress is influenced by the pore water (bulk water) in the soil. The other is the internal stress component which does not contribute to equilibrium with a given external force. The internal stress is induced by the capillary tension of meniscus water clinging to the contact point of soil particles and acts so as to connect the soil particles tightly. Therefore, in modeling the stress and strain relations for unsaturated soils, it is of much importance to quantitatively evaluate how the pore water exists in the soil. This paper discusses the role of pore water on the mechanical behaviour of the soil. In particular, the significance of the water retention curve is emphasized from a mechanical viewpoint. Essential features required in modeling of the constitutive relations for unsaturated soils are discussed and presented.     

Spatial variation in organic matter utilization by benthic communities from Yura River–Estuary to offshore of Tango Sea,Japan

We investigated the distribution of δ¹³C and δ¹⁵N of organic matter among benthic communities from the upper estuary of Yura River to offshore of Tango Sea, Japan, to determine spatial variation in utilization of organic matter by benthic communities. The δ¹³C values of benthic animals ranged from −27 to −15‰ in the upper estuary, −21 to −15‰ in the lower estuary, −20 to −16‰ in the shallow coast (5–10 m depths), −18 to −16‰ in the deep coast (30–60 m depths) and −19 to −15‰ in offshore (100–150 m depths) stations. Adapting the dual isotope values to mixing models, we estimated the relative contributions of potential food sources to the benthos diet. Phytoplankton and macroalgae that intruded the estuary in summer were utilized as alternative food aside from the terrestrial-origin organic matter assimilated by the estuarine benthic consumers. Resuspended benthic microalgae were important source of energy in the shallow coastal stations, while abundant supply of phytodetritus fueled the deep coastal and offshore benthic food webs. Spatial difference in the diet of benthic communities depends largely on the shifts in the primary carbon source. Thus, benthic communities are important link of autochthonous/allochthonous production and secondary production in the continuous river–estuary–marine system.     

Variation of the partial pressure of CO2 in surface water from Kuroshio to Oyashio and the relation between environmental factors and the partial pressure at 144°E off Sanriku, northwestern North Pacific in May, 1997

Partial pressure of CO₂ in surface sea water (pCO₂) was measured continuously off Sanriku in May, 1997 by a new pCO₂ measurement system. We have examined the relation of pCO₂ to physical factors such as temperature, salinity and density, chemical and biological factors such as nutrients and carbonate system and chlorophylla. In the Kuroshio region pCO₂ was not correlated to physical, chemical and biological factors in the range of 260 to 290 μatom. In transition water (Tr1) between Kuroshio and the Oyashio second branch, pCO₂ was weakly correlated to physical factors and strongly correlated to nutrients. In transition water (Tr2) between the Oyashio first and second branches, pCO₂ was highly correlated to temperature (SD: 10.9 μatom) and salinity (SD: 8.6 μatom) and also to nutrients. In transition water (Tr1+Tr2), pCO₂ was highly multivariately correlated to temperature (T), salinity (S), chlorophylla (CH) (or nitrate+nitrite (N)) as follows, pCO₂(μatom)= 10.8×T(°C)+27.7×S+2.57CH(μg/1) −769, R²= 0.86, SD = 20.9, or pCO₂(μatom)= 3.9×T(°C)+25.5×S+16.0NO₃(μM) −686, R²= 0.99, SD = 6.4. Moreover, pCO₂ was predicted by only two factors, one physical (S) and the other chemical/biological (N) as follows: pCO₂ (μatom)=32.8×S+19.4N−908, R²=0.97, SD=8.4. The pH measured at 25°C was well correlated with normalized pCO₂ at a fixed temperature. In the Oyashio region pCO₂ was decreased to 160 μatom, probably because of spring bloom, but was not correlated linearly to chlorophylla. The results obtained showed the possibility of estimating pCO₂ of the Oyashio and transition regions in May by satellite remote sensing of SST, but the problem of estimation of pCO₂ in Kuroshio water remains to be solved.     

The Structure of Young Stellar Jets and Winds Revealed by High Resolution [Fe II] λ1.644μm Line Observations

We present high angular resolution spectra taken along the jets from L1551 IRS 5 and DG Tau obtained with the Subaru Telescope. The position-velocity diagrams of the [Fe II] λ 1.644 μmemission line revealed remarkably similar characteristics for the two sources, showing two distinct velocity components separated from each other in both velocity and space with the entire emission range blueshifted with respect to the stellar velocity. The high velocity component (HVC) has a velocity of –200 ––300 km s^-1 with a narrow line width, while the low velocity component (LVC) is around –100 km s^-1 exhibitinig a broad line width. The HVC is located farther away from the origin and is more extended than the LVC. Our results suggest that the HVC is a well-collimated jet originating from the region close to the star, while the LVC is a widely-opened wind accelerated in the region near the inner edge of the accretion disk.     

Position determination at sea using low-frequency radio waves--The effect of a nearby mountain

Measurements of direction-finding (DF) error in position determination based on low-frequency (LF) radio waves were made at sea employing the Decca navigation system. The measured DF error is found to be large when a mountain is nearby. Assuming the mountain to be a hemisphere with complex dielectric constant, we evaluate DF error using electrostatic theory. Analytical predictions of the expected position error caused by the mountain's presence are qualitatively in fairly good agreement with measured values. In connection with this, fluctuations of the electric field intensities are also described.     

Kinetics of nitrate and ammonium uptake by the natural populations of marine phytoplankton in the surface water of the Oyashio region during spring and summer

Journal of Oceanography -     

Observation of cosmic soft X-rays

Cosmic soft X-rays in the energy range between 0.14 and 7 keV were observed with thin polypropylene window proportional counters on board a sounding rocket. The field of view crossed the galactic plane in the Cygnus-Cassiopeia region at a large angle and reached the galactic latitudes of –55° and +30°. Referring also to the result with Be window counters, we obtained the energy spectrum of Cyg XR-2, the flux from the Cas A region and the distribution of the intensity of diffuse X-rays over the scanned region. The turn-over of the Cyg XR-2 spectrum at about 1 keV indicates that the distance of the Cyg XR-2 source lies between 600 and 800 pc, if the turn-over is due entirely to interstellar absorption. The flux from the Cas A region is obtained as 0.23±0.05 photons cm^–2 sec^–1 in the energy range between 1.1 and 4.1 keV. The intensity of diffuse soft X-rays depends on the galactic latitude more weakly than expected from the interstellar absorption of extragalactic X-rays and shows asymmetry with respect to the galactic equator, thus suggesting a contribution of galactic X-rays. The spectrum of extragalactic X-rays is approximately represented by a power lawE ^–1.8.