A pilot-scale field experiment for the microbial neutralization of a holomictic acidic pit lake

A strategy to neutralize acidic pit lakes was tested in an upscaling process using field mesocosms of 26 to ca. 4500 m³ volume in the acidic pit Mining Lake 111 in Germany. After addition of the substrates Carbokalk and straw a neutral sediment layer formed, in which microbial sulfate and iron reduction as well as sulfide precipitation occurred. The net rate of neutralization was limited by the precipitation of iron sulfides rather than by microbial reactions. Oxidation of H₂S by ferric iron in the anoxic sediment lowered the net sulfate reduction rate. Seasonal fluctuations of iron sulfides in the sediment showed that the reaction products were not necessarily stable. The long-term success of the approach depends on the net partition of the precipitated iron-(mono-/di-) sulfide that is permanently buried in the anoxic sediment. It could be shown by field experiments that the long-term success of the neutralization depends on the spatial scale and duration of the experiments. Volumes from 26 to 4500 m³, exposition times from 4 months to 5 years, and increasingly thick coverings of the sediments with straw, from zero to 40 cm, were used. Net neutralization rates decreased from 41 meq m^− 2 d^− 1 in laboratory microcosms to a mean rate of 2.3 meq m^− 2 d^− 1 in the 4500 m³ field experiment. The results show that the success of the microbial treatment of acid pit lakes lastly depends on the limnological conditions in the lake that cannot be simulated by upscaling of simple laboratory experiments.     

Necessary restructuring or globalization failure? Shifts in regional supplier relations after the merger of the former German Hoechst and French Rhône-Poulenc groups

A large part of the work in economic geography and other social sciences surrounding globalization processes has focused on the prospects of economic growth due to the establishment of global production chains and the rise of new clusters of industrial activity. In recent years, much less attention has been paid to former growth industries and regions that have suffered from the negative consequences of internationalization processes. This paper will explore the cases of two chemical regions, i.e. southern Hessen, Germany and Rhône-Alpes, France. Both regions were forced to undergo drastic restructuring since the mid 1990s due to the merger of the chemical groups Hoechst and Rhône-Poulenc into Aventis. The paper argues that it is beneficial to develop a relational perspective of economic action and interaction in order to better understand these regional transformations and restructuring processes and their consequences. Instead of investigating the development of activities, which became the core operations at Aventis, we will focus on other activities that were considered less important and, consequently, split off. In analyzing the logic of restructuring and the associated changes in regional supplier relations, this paper aims to contribute to a relational understanding of economic globalization and its associated threats to regional development by focusing on agents who are subject to negative restructuring consequences.     

Low impact surface hardness testing (Equotip) on porous surfaces – advances in methodology with implications for rock weathering and stone deterioration research

The Equotip surface hardness tester is becoming a popular method for rock and stone weathering research. In order to improve the reliability of Equotip for on‐site application this study tested four porous limestones under laboratory conditions. The range of stone porosity was chosen to represent likely porosities found in weathered limestones in the field. We consider several key issues: (i) its suitability for soft and porous stones; (ii) the type of probe required for specific on‐site applications; (iii) appropriate (non‐parametrical) statistical methods for Equotip data; (iv) sufficient sampling size. This study shows that the Equotip is suitable for soft and porous rock and stone. From the two tested probes the DL probe has some advantages over the D probe as it correlates slightly better with open porosity and allows for more controlled sampling in recessed areas and rough or curved areas. We show that appropriate sampling sizes and robust non‐parametric methods for subsequent data evaluation can produce meaningful measures of rock surface hardness derived from the Equotip. The novel Hybrid dynamic hardness, a combination of two measuring procedures [single impact method (SIM) and repeated impact method (RIM)], has been adapted and is based on median values to provide a more robust data evaluation. For the tested stones in this study we propose a sample size of 45 readings (for a confidence level of 95%). This approach can certainly be transferred to stone and rock with similar porosities and hardness. Our approach also allows for consistent comparisons to be made across a wide variety of studies in the fields of rock weathering and stone deterioration research. Copyright © 2016 John Wiley & Sons, Ltd.     

The effective stiffness of modern unreinforced masonry walls

Code design of unreinforced masonry (URM) buildings is based on elastic analysis, which requires as input parameter the effective stiffness of URM walls. Eurocode estimates the effective stiffness as 50% of the gross sectional elastic stiffness, but comparisons with experimental results have shown that this may not yield accurate predictions. In this paper, 79 shear‐compression tests of modern URM walls of different masonry typologies from the literature are investigated. It shows that both the initial and the effective stiffness increase with increasing axial load ratio and that the effective‐to‐initial stiffness ratios are approximately 75% rather than the stipulated 50%. An empirical relationship that estimates the E‐modulus as a function of the axial load and the masonry compressive strength is proposed, yielding better estimates of the elastic modulus than the provision in Eurocode 6, which calculates the E‐modulus as a multiple of the compressive strength. For computing the ratio of the effective to initial stiffness, a mechanics‐based formulation is built on a recently developed analytical model for the force‐displacement response of URM walls. The model attributes the loss in stiffness to diagonal cracking and brick crushing, both of which are taken into account using mechanical considerations. The obtained results of the effective‐to‐initial stiffness ratio agree well with the test data. A sensitivity analysis using the validated model shows that the ratio of effective‐to‐initial stiffness is for most axial load ratios and wall geometries around 75%. Therefore, a modification of the fixed ratio of effective‐to‐initial stiffness from 50% to 75% is suggested.     

Loading protocols for European regions of low to moderate seismicity

Existing loading protocols for quasi-static cyclic testing of structures are based on recordings from regions of high seismicity. For regions of low to moderate seismicity they overestimate imposed cumulative damage demands. Since structural capacities are a function of demand, existing loading protocols applied to specimens representative of structures in low to moderate seismicity regions might underestimate structural strength and deformation capacity. To overcome this problem, this paper deals with the development of cyclic loading protocols for European regions of low to moderate seismicity. Cumulative damage demands imposed by a set of 60 ground motion records are evaluated for a wide variety of SDOF systems that reflect the fundamental properties of a large portion of the existing building stock. The ground motions are representative of the seismic hazard level corresponding to a 2 % probability of exceedance in 50 years in a European moderate seismicity region. To meet the calculated cumulative damage demands, loading protocols for different structural types and vibration periods are developed. For comparison, cumulative seismic demands are also calculated for existing protocols and a set of records that was used in a previous study on loading protocols for regions of high seismicity. The median cumulative demands for regions of low to moderate seismicity are significantly less than those of existing protocols and records of high seismicity regions. For regions of low to moderate seismicity the new protocols might therefore result in larger strength and deformation capacities and hence in more cost-effective structural configurations or less expensive retrofit measures.     

Growing Operational Use of FY-3 Data in the ECMWF System

This paper reviews the data quality and impact of observations from the FY-3 satellite series used operationally in the ECMWF system. This includes data from the passive microwave radiometers MWHS-1, MWHS-2 and MWRI, as well as observations from the radio occultation receiver GNOS. Evaluations against background equivalents show that the quality of the observations is broadly comparable to that of similar instruments on other polar-orbiting satellites, even though biases for the passive microwave observations can be somewhat larger and more complex for some channels. An observing system experiment shows that the FY-3 instruments jointly contribute significantly to the forecast skill in the ECMWF system. Positive impact of up to 2% is seen for most variables out to the day-2 forecasts over hemispheric scales, with significant benefits for total column water vapor or for temperature and wind in the stratosphere out to day 4.     

Climate change impacts on global agriculture

Based on predicted changes in the magnitude and distribution of global precipitation, temperature and river flow under the IPCC SRES A1B and A2 scenarios, this study assesses the potential impacts of climate change and CO₂ fertilization on global agriculture. The analysis uses the new version of the GTAP-W model, which distinguishes between rainfed and irrigated agriculture and implements water as an explicit factor of production for irrigated agriculture. Future climate change is likely to modify regional water endowments and soil moisture. As a consequence, the distribution of harvested land will change, modifying production and international trade patterns. The results suggest that a partial analysis of the main factors through which climate change will affect agricultural productivity provide a false appreciation of the nature of changes likely to occur. Our results show that global food production, welfare and GDP fall in the two time periods and SRES scenarios. Higher food prices are expected. No matter which SRES scenario is preferred, we find that the expected losses in welfare are significant. These losses are slightly larger under the SRES A2 scenario for the 2020s and under the SRES A1B scenario for the 2050s. The results show that national welfare is influenced both by regional climate change and climate-induced changes in competitiveness.