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The impact of pond aquaculture effluents on the distribution and performance of seagrasses was examined in NE Hainan, tropical China. Samples were taken along transects in three back-reef areas with different extent of aquaculture production in their hinterland. High δ15N in seagrass leaves and epiphytes (6–9‰) similar to values in pond effluents documented aquaculture as dominant nitrogen source in the back-reefs with decreasing impact with distance from shore. Seagrass species abundance, shoot density and biomass were lower and concentrations of nutrients, chlorophyll and suspended matter were higher at nearshore sites with high and moderate pond abundance than at the control site. High epiphyte loads and low δ34S in seagrass leaves suggest temporal shading and sulphide poisoning of the nearshore seagrasses. Observed gradients in environmental parameters and seagrass performance indicate that the distance from the pond outlets and size of the adjacent pond agglomeration are major determinants of seagrass degradation.  相似文献   
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Microbial activity, abundance and biomass, and biogeochemical cycling of iron, sulphur and carbon were studied in the extremely acidic (pH 2.5-4.3), meromictic, nutrient-rich pit lake Cueva de la Mora in Spain. The goal was to find out (1) if the relatively high nutrient content influenced plankton abundance in the water column and alkalinity-producing microbial processes in the sediments compared to other acid pit lakes, and (2) if sediments in the shallow, mixed and the deep, stagnant parts of the lake exhibited differences in microbial activities and geochemical sediment composition related to meromixis. We hypothesised that redox cycling was more intense in the mixed part and higher amounts of reduced components would accumulate in the stagnant part. Especially phytoplankton biomass, CO2 production, and sulphate reduction were indeed higher than reported from typical acid pit lakes and were rather within the range of neutral or weakly acidic lakes, which can be attributed to the relatively high nutrient contents of Cueva de la Mora. Even in the monimolimnion, anaerobic processes occurred mainly in the sediments. Sediments from the mixed and stagnant parts of the lake differed markedly in their biogeochemistry. Mixolimnetic sediments showed high iron and sulphate reduction rates, and they appeared to undergo substantial recycling, as supported by reactive Fe, relation between gross sulphate reduction rate and net accumulation of reduced sulphur, and viable counts of iron and sulphur bacteria. Monimolimnetic sediments exhibited lower anaerobic microbial activities, and surprisingly they accumulated more Fe(II) than mixolimnetic sediments, but less reduced sulphur and carbon. This might be explained by a strong separation of the two water bodies, resulting in comparably less input of energy (light) and allochthonous matter into the monimolimnion. Regarding the total extent of alkalinity-generating microbial processes, their net effect is not sufficient to neutralise the lake within decades.  相似文献   
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The accurate estimation of sub‐seafloor resistivity features from marine controlled source electromagnetic data using inverse modelling is hindered due to the limitations of the inversion routines. The most commonly used one‐dimensional inversion techniques for resolving subsurface resistivity structures are gradient‐based methods, namely Occam and Marquardt. The first approach relies on the smoothness of the model and is recommended when there are no sharp resistivity boundaries. The Marquardt routine is relevant for many electromagnetic applications with sharp resistivity contrasts but subject to the appropriate choice of a starting model. In this paper, we explore the ability of different 1D inversion schemes to derive sub‐seafloor resistivity structures from time domain marine controlled source electromagnetic data measured along an 8‐km‐long profile in the German North Sea. Seismic reflection data reveal a dipping shallow amplitude anomaly that was the target of the controleld source electromagnetic survey. We tested four inversion schemes to find suitable starting models for the final Marquardt inversion. In this respect, as a first scenario, Occam inversion results are considered a starting model for the subsequent Marquardt inversion (Occam–Marquardt). As a second scenario, we employ a global method called Differential Evolution Adaptive Metropolis and sequentially incorporate it with Marquardt inversion. The third approach corresponds to Marquardt inversion introducing lateral constraints. Finally, we include the lateral constraints in Differential Evolution Adaptive Metropolis optimization, and the results are sequentially utilized by Marquardt inversion. Occam–Marquardt may provide accurate estimation of the subsurface features, but it is dependent on the appropriate conversion of different multi‐layered Occam model to an acceptable starting model for Marquardt inversion, which is not straightforward. Employing parameter spaces, the Differential Evolution Adaptive Metropolis approach can be pertinent to determine Marquardt a priori information; nevertheless, the uncertainties in Differential Evolution Adaptive Metropolis optimization will introduce some inaccuracies in Marquardt inversion results. Laterally constrained Marquardt may be promising to resolve sub‐seafloor features, but it is not stable if there are significant lateral changes of the sub‐seafloor structure due to the dependence of the method to the starting model. Including the lateral constraints in Differential Evolution Adaptive Metropolis approach allows for faster convergence of the routine with consistent results, furnishing more accurate estimation of a priori models for the subsequent Marquardt inversion.  相似文献   
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Conflicting sorption coefficients for ortho‐phenylphenol (OPP) have been reported in the literatures, which resulted in the conflicting assessments on OPP mobility in soil. To ascertain the sorption coefficient of OPP, batch experiments were performed based on OECD guideline 106, using three types of soils. Headspace solid‐phase microextraction (HS‐SPME) and GC‐MS were applied to the determination of OPP concentration in the liquid phase. The sorption isotherms obtained for all three soils under equilibrium conditions were described well, assuming linear sorption. The organic carbon normalized distribution coefficients (Koc) ranged from 894 to 1703 L kg?1, which suggested that OPP is moderately mobile in soil. The results also showed that the Koc value of OPP can be predicted precisely from Kow, whereas it was underestimated by one order of magnitude when water solubility is used.  相似文献   
48.
Cyanobacterial dominance in lakes has received much attention in the past because of the great success and frequent bloom formation in lakes of higher trophic levels. In this paper underlying mechanism of cyanobacterial dominance are analyzed and discussed using both original and literature data from various shallow mixed and deep stratifying lakes from temperate and (subtropical regions. Examples include all four ecotypes of cyanobacteria sensu MUR et al. (1993), because their behavior in the water column is entirely different.Colony forming species (Microcystis) are exemplified from the large shallow Lake Taihu, China. Data from a shallow urban lake, Alte Donau in Austria are used to characterize well mixed species (Cylindrospermopsis) while stratifying species (Planktothrix) are analyzed from the deep alpine lake Mondsee. Nitrogen fixing species (Aphanizomenon) are typified from a shallow river-run lake in Germany.Factors causing the dominance of one or the other group are discussed as well as consequences for restoration measures. Existing knowledge on cyanobacterial dominance is summarized.  相似文献   
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To show the relative availability of nitrogen, phosphorus and silica for diatoms as well as non-siliceous algae in phytoplankton communities triangular diagrams are most appropriate. Triangular diagrams for TN-TP-SRSi show the nutrient ratios TN:TP, SRSi:TN and SRSi:TP in proportion to each other at the same time.Comparison of waters, grouped according to their limnological characteristics, indicate that these groups have also different seasonal dynamics of TN, TP and SRSi in proportion to each other. From these groups, which include meso-eutrophic and hypertrophic, shallow and deep, polymictic and dimictic lakes,only the group of "flushed, hypertrophic polymictic lakes" has a high seasonal dynamic of the ratios of all three macronutrients. Moreover the relative availability of TN:TP-ratios changes from > 16:1 in spring to <16:1 in summer. Significant changes in phytoplankton structure are associated with this high dynamic of the nutrient ratios. Considerable changes in the share of cyanobacteria to diatom biomass during summer are synchronised with a powerful modification of the relative availability of TN-TP-SRSi as illustrated by the triangular diagrams.For practical purposes trophic situations are most commonly evaluated from concentrations of a single nutrient or a nutrient ratio, such as N:P. However, a complex assessment would often be more appropriate. In this context triangular diagrams have the benefit of synoptically presenting relative nutrient availability for phytoplankton communities as a whole.  相似文献   
50.
The geologic record supports numerous instances during which continents apparently moved at speeds significantly faster than any of today's tectonic plates. While the time dependence of convective driving forces likely explains some such observations, rapid motions of large continents in particular are often attributed to true polar wander (TPW). In order to gauge the potential for connections between continents, mantle temperature anomalies, and polar motion, we present the first calculations of TPW derived from models that couple mantle convection with multiple, mobile continents. We find that the aggregation and dispersal of supercontinents can lead to two types of TPW, driven either by a well developed hot upwelling axis that creates a stable maximum moment of inertia, or by the homogenization of mantle thermal structure following continent dispersal that leads to destabilization of the principal axis and possible large magnitude polar wander. These supercontinent-modulated thermal heterogeneities drive model TPW events as large as 90° at rates of up to 2.5° Ma 1. Such magnitudes and speeds are greater than those attained in similar models lacking continents, but comparable to those for episodes inferred from paleomagnetic data for some large continents in the past.  相似文献   
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