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11.
Persistent halogenated compounds in black guillemots (Cepphus grylle) from Greenland--levels, compound patterns and spatial trends 总被引:1,自引:0,他引:1
Twenty-seven black guillemot eggs and 39 livers were analysed for polychlorinated biphenyls (PCBs), chlorinated pesticides including chlordane-related compounds and toxaphene, and polybrominated diphenylethers (PBDEs). The samples were collected at Qeqertarsuaq (Godhavn, West Greenland) and Ittoqqortoormiit (Scoresbysund, East Greenland). The concentrations of halogenated organic compounds in samples from East Greenland were somewhat higher than the corresponding concentrations from West Greenland. Differences in compound patterns were found between West and East Greenland, with higher percentages of the heavier PCB molecules, p,p(')-DDE and alpha-HCH in the samples from Ittoqqortoormiit. Similarly, different levels and different compositions were observed for eggs and livers. The eggs had generally higher concentrations of all compounds as well as higher percentages of CHB-50, CHB-62 and alpha-HCH than liver samples from the same area. Dividing the liver samples into age groups revealed increasing concentrations with age. 相似文献
12.
Analytical and empirical models for predicting the drift capacity of modern unreinforced masonry walls 下载免费PDF全文
Displacement‐based seismic assessment of buildings containing unreinforced masonry (URM) walls requires as input, among others, estimates of the in‐plane drift capacity at the considered limit states. Current codes assess the drift capacity of URM walls by means of empirical models with most codes relating the drift capacity to the failure mode and wall slenderness. Comparisons with experimental results show that such relationships result in large scatter and usually do not provide satisfactory predictions. The objective of this paper is to determine trends in drift capacities of modern URM walls from 61 experimental tests and to investigate whether analytical models could lead to more reliable estimates of the displacement capacity than the currently used empirical models. A recently developed analytical model for the prediction of the ultimate drift capacity for both shear and flexure controlled URM walls is introduced and simplified into an equation that is suitable for code implementation. The approach follows the idea of plastic hinge models for reinforced concrete or steel structures. It explicitly considers the influence of crushing due to flexural or shear failure in URM walls and takes into account the effect of kinematic and static boundary conditions on the drift capacity. Finally, the performance of the analytical model is benchmarked against the test data and other empirical formulations. It shows that it yields significantly better estimates than empirical models in current codes. The paper concludes with an investigation of the sensitivity of the ultimate drift capacity to the wall geometry, static, and kinematic boundary conditions. 相似文献
13.
Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg KDOC and lg KOW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δDOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand. 相似文献
14.
Mid‐rise to high‐rise buildings in seismic areas are often braced by slender reinforced concrete (RC) walls, which are interconnected by RC floor diaphragms. In design, it is typically assumed that the lateral forces are distributed in proportion to the wall's elastic stiffness. Pushover analyses of systems comprising walls of different lengths have, however, shown that large compatibility forces can develop between them, which should be considered in design, but the analyses have also shown that the magnitude of the computed forces is very sensitive to the modelling assumptions. Using the results of a complex shell element model as benchmark, different simple hand‐calculation methods and inelastic beam element models are assessed and improved to yield reliable estimates of the base shear distribution among the individual walls comprising the interconnected wall system. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
15.
In this receiver function study, we investigate the structure of the crust beneath six seismic broadband stations close to
the Sunda Arc formed by subduction of the Indo-Australian under the Sunda plate. We apply three different methods to analyse
receiver functions at single stations. A recently developed algorithm determines absolute shear-wave velocities from observed
frequency-dependent apparent incidence angles of P waves. Using waveform inversion of receiver functions and a modified Zhu
and Kanamori algorithm, properties of discontinuities such as depth, velocity contrast, and sharpness are determined. The
combination of the methods leads to robust results. The approach is validated by synthetic tests. Stations located on Malaysia
show high-shear-wave velocities (V
S) near the surface in the range of 3.4–3.6 km s − 1 attributed to crystalline rocks and 3.6–4.0 km s − 1 in the lower crust. Upper and lower crust are clearly separated, the Moho is found at normal depths of 30–34 km where it
forms a sharp discontinuity at station KUM or a gradient at stations IPM and KOM. For stations close to the subduction zone
(BSI, GSI and PSI) complexity within the crust is high. Near the surface low V
S of 2.6–2.9 km s − 1 indicate sediment layers. High V
S of 4.2 km s − 1 are found at depth greater than 6 and 2 km at BSI and PSI, respectively. There, the Moho is located at 37 and 40 km depth.
At station GSI, situated closest to the trench, the subducting slab is imaged as a north-east dipping structure separated
from the sediment layer by a 10 km wide gradient in V
S between 10 and 20 km depth. Within the subducting slab V
S ≈ 4.7 km s − 1. At station BSI, the subducting slab is found at depth between 90 and 110 km dipping 20° ± 8° in approximately N 60° E. A
velocity increase in similar depth is indicated at station PSI, however no evidence for a dipping layer is found. 相似文献
16.
Crab larval dispersal and, thus, adult population size can be influenced by oceanographic conditions, especially in highly dynamic and variable environments such as high-latitude estuaries. This study's primary goal was to understand larval timing, abundance, and distribution in relation to oceanographic effects between the more estuarine inner and more oceanic outer part of the subarctic estuary of Kachemak Bay (south-central Alaska, USA). Temperature and salinity measurements and plankton tows were taken along the boundary between the two bay parts from 31 March to 28 October 2008 on spring and neap tides. Summer water flow and stratification in Kachemak Bay were chiefly buoyancy driven, and predominant flow patterns were not affected by the large tidal range in the region. Larvae of seven brachyuran species were found over the sampling period, with seasonally different peak abundances. Larval spatial distribution patterns, presence of most larval stages for each species, and their seasonal timing and persistence within the water column suggest that most species are locally transported within or close to Kachemak Bay. The larval assemblage was correlated with seasonal changes in water temperature, and peak abundances of some species coincided with spring tides and/or frontal systems between the in- and outflow regions of the bay. The strong influence of freshwater on the local circulation pattern in the summer indicates that larval transport will likely be strongly affected by future changes in glacial melt and precipitation. 相似文献
17.
This article presents a new mechanical model for the non‐linear force–displacement response of unreinforced masonry (URM) walls developing a flexural rocking mode including their displacement capacity. The model is based on the plane‐section hypothesis and a constitutive law for the masonry with zero tensile strength and linear elastic behaviour in compression. It is assumed that only the compressed part of the wall contributes to the stiffness of the wall and therefore the model accounts for a softening of the response due the reduction of the effective area. Stress conditions for limit states are proposed that characterise the flexural failure. The new model allows therefore linking local performance levels to global displacement capacities. The limit states criteria describe the behaviour of modern URM walls with cement mortar of normal thickness and clay bricks. The model is validated through comparison of local and global engineering demand parameters with experimental results. It provides good prediction of the effective stiffness, the force capacity and the displacement capacity of URM walls at different limit states. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
18.
Niels BORMANN David DUNCAN Stephen ENGLISH Sean HEALY Katrin LONITZ Keyi CHEN Heather LAWRENCE Qifeng LU 《大气科学进展》2021,38(8):1285-1298
This paper reviews the data quality and impact of observations from the FY-3 satellite series used operationally in the ECMWF system. This includes data from the passive microwave radiometers MWHS-1, MWHS-2 and MWRI, as well as observations from the radio occultation receiver GNOS. Evaluations against background equivalents show that the quality of the observations is broadly comparable to that of similar instruments on other polar-orbiting satellites, even though biases for the passive microwave observations can be somewhat larger and more complex for some channels. An observing system experiment shows that the FY-3 instruments jointly contribute significantly to the forecast skill in the ECMWF system. Positive impact of up to 2% is seen for most variables out to the day-2 forecasts over hemispheric scales, with significant benefits for total column water vapor or for temperature and wind in the stratosphere out to day 4. 相似文献
19.
The San Martín shield volcano, located in the Los Tuxtlas Volcanic Field, has experienced effusive shield-building activity, as well as explosive eruptions, as evidenced by direct observations during the last eruption in 1793. The threat to the surrounding villages consists principally of lahars, especially because of the tropical climate in the region. Ash fallout and lava flows represent additional hazards. In addition, the surrounding Quaternary monogenetic field includes more than 300 scoria cones and about 40 explosion craters (mainly maars) that also represent a hazard source. In the present study we constructed hazard maps using field data, orthophotos, spatial analysis, and specialized software (LAHARZ and HAZMAP) to deliminate lahar inundation zones, areas that could potentially be affected by ash fallout (including the evaluation of houses prone to roof collapse due to ash load), and the most susceptible areas for hosting future monogenetic vent formation. 相似文献
20.
Katrin Fleischbein Wolfgang Wilcke Rainer Goller Jens Boy Carlos Valarezo Wolfgang Zech Klaus Knoblich 《水文研究》2005,19(7):1355-1371
Rainfall interception in forests is influenced by properties of the canopy that tend to vary over small distances. Our objectives were: (i) to determine the variables needed to model the interception loss of the canopy of a lower montane forest in south Ecuador, i.e. the storage capacity of the leaves S and of the trunks and branches St, and the fractions of direct throughfall p and stemflow pt; (ii) to assess the influence of canopy density and epiphyte coverage of trees on the interception of rainfall and subsequent evaporation losses. The study site was located on the eastern slope of the eastern cordillera in the south Ecuadorian Andes at 1900–2000 m above sea level. We monitored incident rainfall, throughfall, and stemflow between April 1998 and April 2001. In 2001, the leaf area index (LAI), inferred from light transmission, and epiphyte coverage was determined. The mean annual incident rainfall at three gauging stations ranged between 2319 and 2561 mm. The mean annual interception loss at five study transects in the forest varied between 591 and 1321 mm, i.e. between 25 and 52% of the incident rainfall. Mean S was estimated at 1·91 mm for relatively dry weeks with a regression model and at 2·46 mm for all weeks with the analytical Gash model; the respective estimates of mean St were 0·04 mm and 0·09 mm, of mean p were 0·42 and 0·63, and of mean pt were 0·003 and 0·012. The LAI ranged from 5·19 to 9·32. Epiphytes, mostly bryophytes, covered up to 80% of the trunk and branch surfaces. The fraction of direct throughfall p and the LAI correlated significantly with interception loss (Pearson's correlation coefficient r = −0·77 and 0·35 respectively, n = 40). Bryophyte and lichen coverage tended to decrease St and vascular epiphytes tended to increase it, although there was no significant correlation between epiphyte coverage and interception loss. Our results demonstrate that canopy density influences interception loss but only explains part of the total variation in interception loss. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献