Highly siderophile element abundances and 187Re-187Os systematics in the Tafassasset carbonaceous-like primitive achondrite

Highly siderophile elements (HSE) strongly partition into metal phases over silicate minerals and so offer important constraints on nebular and core formation processes acting on early planetesimals. Abundances of the HSE are also an important tool for constraining relationships between metal-rich meteorites. The first bulk rock and in situ HSE abundance and ¹⁸⁷Re-¹⁸⁷Os data are reported for the ungrouped metal-rich achondrite Tafassasset to examine models of its petrogenesis and origin. Bulk rock and metal grain HSE abundances are elevated at ~2 and ~15 times CI chondrite abundances, respectively, and are largely unfractionated from one another. Metal within Tafassasset is therefore likely to have quenched shortly after partial melting without significant fractional crystallization. Metal grain HSE abundances can be used to calculate a metal fraction of 14 ± 4 wt%, overlapping with the parent bodies of CC iron meteorites, which have also been related to Tafassasset using nucleosynthetic isotope anomalies. Despite such similarities, HSE systematics of bulk rock Tafassasset are not equivalent to any known chondrites, and metal grains do not overlap with iron meteorites or chondrite metal grains, precluding a direct genetic relationship.     

The effect of orbital evolution on the Haumea (2003 EL61) collisional family

The Haumea family is currently the only identified collisional family in the Kuiper belt. We numerically simulate the long-term dynamical evolution of the family to estimate a lower limit of the family’s age and to assess how the population of the family and its dynamical clustering are preserved over Gyr timescales. We find that the family is not younger than 100 Myr, and its age is at least 1 Gyr with 95% confidence. We find that for initial velocity dispersions of 50–400 m s^?1, approximately 20–45% of the family members are lost to close encounters with Neptune after 3.5 Gyr of orbital evolution. We apply these loss rates to two proposed models for the formation of the Haumea family, a graze-and-merge type collision between two similarly sized, differentiated KBOs or the collisional disruption of a satellite orbiting Haumea. For the graze-and-merge collision model, we calculate that >85% of the expected mass in surviving family members within 150 m s^?1 of the collision has been identified, but that one to two times the mass of the known family members remains to be identified at larger velocities. For the satellite-break-up model, we estimate that the currently identified family members account for ～50% of the expected mass of the family. Taking observational incompleteness into account, the observed number of Haumea family members is consistent with either formation scenario at the 1σ level, however both models predict more objects at larger relative velocities (>150 m s^?1) than have been identified.     

Practicing community geography in times of crisis

Community geography emphasizes the centrality of community engagement to socially transformative research. This introduction to a special issue of GeoJournal on community geography outlines how this growing subfield provides a model for collaborative action with the crises of our time, from white supremacy through climate change. As the co-editors of this special issue, we summarize the contents of these 14 articles, grouping them by the shared themes of power, institutional partnerships, pedagogy, and methods.

     

Assessing changes in nutrient status in the Richmond River estuary,Australia, using paleolimnological methods

Eutrophication from nutrient over-enrichment is a serious problem for the coastal zone and the estuarine environment globally. Australian estuaries are generally oligotrophic, but assessing whether they are becoming more eutrophic over time is inhibited by a lack of long-term monitoring data. The Richmond River, Australia, provided an ideal example of an estuary under anthropogenic pressure where the use of paleoecological techniques may potentially be used to reconstruct changes in nutrient status over time. Five cores were extracted from depositional areas in the Richmond River, and subjected to paleo-magnetic profiling and loss-on-ignition testing to ensure the core of greatest integrity was selected for further analytical work. Results from diatom and stable isotope analyses combined with ²¹⁰Pb and AMS ¹⁴C dating show a strong indication that the total phosphorus levels in the Richmond River have fluctuated since 1940. Evidence also suggests that these fluctuations are most likely a function of climate. This study has successfully applied paleolimnological techniques to the estuarine environment to produce information that can be used by environmental managers to aid decision making in relation to nutrient control for the Richmond River. Further work using paleolimnological techniques should be aimed at the extraction of a core containing diatoms that pre-date European settlement and include analyses of specific lipids and fatty acid biomarkers.     

Sources of Terrestrial Organic Carbon in the Mississippi Plume Region: Evidence for the Importance of Coastal Marsh Inputs

High sedimentation rates along river-dominated margins make these systems important repositories for organic carbon derived from both allochthonous and autochthonous sources. Using elemental carbon/nitrogen ratios, molecular biomarker (lignin phenol), and stable carbon isotopic (bulk and compound-specific) analyses, this study examined the sources of organic carbon to the Louisiana shelf within one of the primary dispersive pathways of the Mississippi River. Surface sediment samples were collected from stations across the inner, mid, and outer Louisiana shelf, within the Mississippi River plume region, during two cruises in the spring and fall of 2000. Lignin biomarker data showed spatial patterns in terrestrial source plant materials within the river plume, such that sediments near the mouth of the Mississippi River were comparatively less degraded and richer in C₄ plant carbon than those found at mid-depth regions of the shelf. A molecular and stable isotope-based mixing model defining riverine, marsh, and marine organic carbon suggested that the highest organic carbon inputs to the shelf in spring were from marine sources (55?C61% marine organic carbon), while riverine organic carbon was the highest (63%) in fall, likely due to lower inputs of marine organic carbon at this time compared with the spring season. This model also indicated that marsh inputs, ranging from 19 to 34% and 3?C15% of the organic carbon in spring and fall, respectively, were significantly more important sources of organic carbon on the inner Louisiana shelf than previously suggested. Finally, we propose that the decomposition of terrestrial-derived organic carbon (from the river and local wetlands sources) in mobile muds may serve as a largely unexplored additional source of oxygen-consuming organic carbon in hypoxic bottom waters of the Louisiana shelf.     

Lipid biomarkers of deep-sea hydrothermal vent polychaetes—Alvinella pompejana, A. caudata, Paralvinella grasslei and Hesiolyra bergii

The lipid composition was determined for 5 species of polychaete annelids collected by the Deep Submergence Vehicle ALVIN from high temperature chimneys at the 2500 m depth hydrothermal vent field of the East Pacific Rise. These are the first lipid biomarker analyses reported for these hydrothermal vent polychaetes. Lipid content was low in all samples (1.6–35.9 mg g^–1 wet mass) and was dominated by polar lipid (78–90% of total lipid) with 8–19% sterol (ST), and very low storage lipid (triacylglycerol and wax ester). Total polyunsaturated fatty acids (PUFA) were moderately high (22–31% of total fatty acids (FA)) with extremely low or no docosahexaenoic acid (DHA, 22:6(n-3)). Eicosapentaenoic acid (EPA, 20:5(n-3)) levels were 5–6% in Alvinella pompejana and A. caudata and 10.3–13.7% in an errantiate polychaete (likely Hesionidae) and Hesiolyra bergii. There were greater PUFA and a greater EPA/AA (AA is arachidonic acid, 20:4(n-6)) ratio in the anterior versus the posterior half of A. pompejana, which may correlate to the strong temperature gradient reported in its tube. Total nonmethylene interrupted diunsaturated fatty acids (NMID) were 4–9% of total FA for most polychaete species and included several 20:2 and 22:2 components. The principal monounsaturated fatty acids (MUFA) included 18:1(n-7)c (14–19%), 16:1(n-7)c (2.6–10%) and 20:1(n-11)c (3–7% of total FA). These polychaete species may desaturate and elongate the bacterial-derived 18:1(n-7)c to obtain the essential FA EPA and AA. The major ST in the polychaetes is cholesterol (89–98% of total ST) with less cholesterol in the gut contents of A. pompejana. Other ST included 24-ethylcholesterol (1.5–5% of total ST) with lesser amounts of 24-methylenecholesterol, desmosterol, lathosterol, 24-methylcholesterol, 24-ethylcholesterol, and the stanols dehydrocholestanol and cholestanol. The high ST levels could play a role in thermal adaptation of membranes at the hydrothermal vent environment. Differences in the FA profiles separated the closely related species A. pompejana and A. caudata from Paralvinella grasslei, H. bergii, and the errantiate polychaete (likely Hesionidae).     

Evaluating the meaning of “layer” in the martian north polar layered deposits and the impact on the climate connection

Using data from the High Resolution Imaging Science Experiment (HiRISE) aboard the Mars Reconnaissance Orbiter, we reassess the methods by which layers within the north polar layered deposits (NPLD) can be delineated and their thicknesses measured. Apparent brightness and morphology alone are insufficient for this task; high resolution topographic data are necessary. From these analyses, we find that the visible appearance of layers depends to a large degree on the distribution of younger, mantling deposits (which in turn is partially influenced by inherent layer properties) and on the shape and location of the particular outcrop. This younger mantle partially obscures layer morphology and brightness and is likely a cause of the gradational contacts between individual layers at this scale. High resolution images reveal that there are several layers similar in appearance to the well-known marker bed discovered by Malin, M., Edgett, K., 2001. J. Geophys. Res. 106, 23429-23570. The morphology, thicknesses , and separation distances of these marker beds, as gleaned from a high resolution stereo digital elevation model, lend insight into the connection between stratigraphy and climate.     

Reconnaissance dating: A new radiocarbon method applied to assessing the temporal distribution of Southern Ocean deep-sea corals

We have developed a rapid ‘reconnaissance’ method of preparing graphite for ¹⁴C/¹²C analysis. Carbonate (～15 mg) is combusted using an elemental analyzer and the resulting CO₂ is converted to graphite using a sealed tube zinc reduction method. Over 85% (n=45 replicates on twenty-one individual corals) of reconnaissance ages measured on corals ranging in age from 500 to 33,000 radiocarbon years (Ryr) are within two standard deviations of ages generated using standard hydrolysis methods on the same corals, and all reconnaissance ages are within 300 Ryr of the standard hydrolysis ages. Replicate measurements on three individual aragonitic corals yielded ages of 1076±35 Ryr (standard deviation; n=5), 10,739±47 Ryr (n=8), and 40,146±3500 Ryr (n=9). No systematic biases were found using different cleaning methods or variable sample sizes. Analysis of ¹³C/¹²C was made concurrently with the ¹⁴C/¹²C measurement to correct for natural fractionation and for fractionation during sample processing and analysis. This technique provides a new, rapid method for making accurate, percent-level ¹⁴C/¹²C analyses that may be used to establish the rates and chronology of earth system processes where survey-type modes of age estimation are desirable. For example, applications may include creation of sediment core-top maps, preliminary age models for sediment cores, and growth rate studies of marine organisms such as corals or mollusks. We applied the reconnaissance method to more than 100 solitary deep-sea corals collected in the Drake Passage in the Southern Ocean to investigate their temporal and spatial distribution. The corals used in this study are part of a larger sample set, and the subset that was dated was chosen based on species as opposed to preservation state, so as to exclude obvious temporal biases. Similar to studies in other regions, the distribution of deep-sea corals is not constant through time across the Drake Passage. Most of the corals from the Burdwood Bank (continental shelf of Argentina) have ages ranging between 0 and 2500 calendar years, whereas most of the corals from the Sars Seamount in the Drake Passage have ages between 10,000 and 12,500 calendar years. Such differences may be caused in part by sampling biases, but may also be caused by changes in larval transport, nutrient supply, or other environmental pressures.     

Organic biomarkers to describe the major carbon inputs and cycling of organic matter in the central Great Barrier Reef region

Controversy surrounds the sources and transport of land derived pollutants in the Great Barrier Reef ecosystem because there is insufficient knowledge of the mechanism of movement of organic contaminants and the cycling of organic matter in this dynamic system. Thus a sediment and sediment trap study was used to describe the composition of resuspended and surface sediments in the south central Great Barrier Reef and its lagoon. This region is characterised by strong tides (6–8 m at Mackay) and trade winds regularly about 15–20 knots. A series of organic biomarkers detailed the cyclical processes of sediment resuspension, recolonising with marine algae and bacteria, packaging into zooplankton faecal pellets and resettlement to sediments where the organics undergo further diagenesis. With each cycle the inshore sediments are diluted with CaCO₃ reef sediments and moved further offshore with the strong ebb tide currents. This results in transport of land derived materials offshore and little storage of organic materials in the lagoon or reef sediments. These processes were detailed by inorganic measurements such as %CaCO₃ and Al/Ca ratios, and by the compositions of hydrocarbon, sterol, alcohol, and fatty acid lipid fractions. Persistent contaminants such as coal dust from a coastal loading facility can be detected in high concentration inshore and decreasing out to the shelf break at 180 m approximately 40 nautical miles offshore. The normal processes would likely be amplified during cyclonic and other storms. The lipids show the sources of carbon to include diatoms and other phytoplankton, creanaerchaeota, sulfate reducing and other bacteria, land plants including mangrove leaves, plus coal dust and other petroleum contaminants.