Thunderstorm-associated responses in the vertical motion of the mid-latitude F-region ionosphere

Mid-latitude Digisonde Doppler velocities, auroral electrojet (AE) indices and cloud-to-ground (CG) lightning strokes during August 2003–2004 were used to study the perturbations in the F-region vertical drift associated with terrestrial thunderstorms. A superposed epoch analysis (SEA) showed that the F-region vertical drifts V_z had a net descent of ～0.6 m s^?1 peaking ～3 h after lightning. Stronger downward perturbations of up to ～0.9 m s^?1 were observed in the afternoon on the day prior to lightning days. The perturbations were less significant on the day after and insignificant during the remaining intervals up to 144 h on either side of the lightning. The stronger responses on the day before are consistent with causality because the lightning times were merely proxies for the physical mechanisms involved. The actual causes are unclear, but we discuss the possible roles of lightning-induced ionisation enhancements, intense electric fields penetrating upward from electrified clouds, and atmospheric gravity waves (AGWs) radiated from thunderstorms or from the accompanying tropospheric fronts. There is no doubt that the behaviour of the mid-latitude F-region is controlled by the thermospheric winds and the solar wind-magnetosphere electrical generators, but our results suggest that electrified clouds also account for a significant, albeit relatively small component of the ionospheric variability.     

Happy Jack Uraninite: A New Reference Material for High Spatial Resolution Analysis of U‐Rich Matrices

There is currently a lack of well‐characterised matrix‐matched reference materials (RMs) for forensic analysis of U‐rich materials at high spatial resolution. This study reports a detailed characterisation of uraninite (nominally UO_2+x) from the Happy Jack Mine (UT, USA). The Happy Jack uraninite can be used as a RM for the determination of rare earth element (REE) mass fractions in nuclear materials, which provide critical information for source attribution purposes. This investigation includes powder X‐ray diffraction (pXRD) data, as well as major, minor and trace element abundances determined using a variety of micro‐analytical techniques. The chemical signature of the uraninite was investigated at the macro (cm)‐scale with micro‐X‐ray fluorescence (µXRF) mapping and at high spatial resolution (tens of micrometre scale) using electron probe microanalysis (EPMA) and laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) analyses. Based on EPMA results, the uraninite is characterised by homogeneous UO₂ and CaO contents of 91.57 ± 1.49% m/m (2s uncertainty) and 2.70 ± 0.38% m/m (2s), respectively. Therefore, CaO abundances were used as the internal standard when conducting LA‐ICP‐MS analyses. Overall, the major element and REE compositions are homogeneous at both the centimetre and micrometre scales, allowing this material to be used as a RM for high spatial resolution analysis of U‐rich samples.     

A diatom-based Holocene record of human impact from a coastal environment: Tuckean Swamp, eastern Australia

Diatom-based paleolimnological studies are being increasingly used to track anthropogenic change in estuaries. Little is known, however, about the direction and nature of long-term environmental changes in Australian estuaries. In this study, shifts in diatom assemblages preserved in a ²¹⁰Pb and C¹⁴ AMS dated sediment core from Tuckean Swamp were analysed to determine environmental changes that had taken place as a result of changing land-use practices. Prior to European impact, the diatom assemblage remained relatively stable and was dominated by Actinocyclus normanii and Diploneis smithii. An increasing dominance of Cyclotella meneghiniana correlates well with changed land use activities in the catchment area and indicates an increase of freshwater influence in the swamp’s environment. A major shift in species composition began ∼1970, Eunotia flexuosa becoming dominant. The assemblage shifts recorded at this site appear to be consistent with environmental changes triggered by human activities such as vegetation clearance, drainage and the construction of a barrage. This study demonstrates the use of paleolimnoology in an estuarine environment to provide pre-impact data necessary for management of the aquatic environment.     

Groundwater Governance in a Water‐Starved Country: Public Policy,Farmers' Perceptions,and Drivers of Tubewell Adoption in Balochistan,Pakistan

Pakistan faces the challenge of developing sustainable groundwater policies with the main focus on groundwater management rather than groundwater development and with appropriate governance arrangement to ensure benefits continue into the future. This article investigates groundwater policy, farmers' perceptions, and drivers of tubewell (groundwater bore) adoption and proposes possible pathways for improved groundwater management for Balochistan, Pakistan. Historical groundwater policies were mainly aimed at increasing agricultural production and reducing poverty, without consideration of adverse impact on groundwater availability. These groundwater policies and governance arrangements have resulted in a massive decline in groundwater tables. Tubewell owners' rankings of the drivers of groundwater decline suggest that rapid and widespread installation of tubewells, together with uncontrolled extraction due to lack of property rights, electricity subsidy policies, and ineffective governance, are key causes of groundwater decline in Balochistan. An empirical “tubewell adoption” model confirmed that the electricity subsidy significantly influenced tubewell adoption decisions. The article proposes a more rational electricity subsidy policy for sustaining groundwater levels in the short‐run. However, in the long run a more comprehensive sustainable groundwater management policy, with strong institutional support and involvement of all stakeholders, is needed.     

Larval fish abundance and physical forcing in the Gulf of Alaska, 1981–2003

The present study investigates ecological patterns and relationships to environmental variables among a time-series of larval fish species abundance from late spring surveys (1981–2003) in the northwest Gulf of Alaska (GOA). Links between interannual variation in species abundance and the physical environment were explored using generalized additive modeling (GAM). Trends in larval abundance and connections with physical variables displayed patterns that indicate unique and complex responses among species to environmental forcing during the larval period. In particular, the observed patterns suggest that ontogenetic-specific responses, representing sub-intervals of early life, are important. In addition, a notable degree of synchrony in larval abundance trends, and similarity in links with physical variables, were observed among species with common early life history patterns. The deepwater spawners, northern lampfish, arrowtooth flounder, and Pacific halibut, were most abundant in the study area during the 1990s, in association with enhanced wind-driven onshore and alongshore transport. Years of high abundance for Pacific cod, walleye pollock, and northern rock sole were associated with cooler winters and enhanced alongshore winds during spring. High larval abundance for spring–summer spawning rockfish species and southern rock sole seemed to be favored by warmer spring temperatures later in the time-series. This apparent exposure–response coupling seems to be connected to both local-scale and basin-scale environmental signals, to varying degrees depending on specific early life history characteristics. Understanding such ecological connections contributes to the evaluation of vulnerability and resilience among GOA species’ early life history patterns to fluctuating climate and oceanographic conditions. This investigation also provides crucial information for the identification of “environmental indicators” that may have a broad-spectrum effect on multiple species early life history stages, as well as those that may be more species-specific in exerting control on early life history survival. Of particular interest was the emergence of the EP–NP (East Pacific–North Pacific) teleconnection index as the top-ranked variable in the GAM models exploring the connections between late spring larval abundance and the physical environment. The EP–NP index represents an important and often primary mode of spring–summer atmospheric variability in the northeast Pacific, with a strong expression in the GOA, and its connection with species in this study implies that it may be a climate mode of significant ecological importance.     

Changes in the carbonate component of recent sediments with depth: a guide to paleoenvironmental interpretation

Changes in the relative proportions of forams, nannofossils, < 63 μ and > 63 μ carbonate mineral particles within the total carbonate fraction of Recent continental-shelf, continental-slope and oceanic sediments are demonstrated. The relative proportions of these size fractions and microfossils are used to categorise the Recent sediments from the different morphological areas. These categorisations can be applied to older sediments to assess their position of formation relative to the ancient continental-shelf, continental-slope and oceanic areas. Equivalent depths cannot be inferred.     

Equatorial influence of QuikSCAT winds in an isopycnal ocean model compared to NCEP2 winds

An ocean model was used to examine whether the scatterometer winds can improve the model performance both dynamically and thermodynamically. Comparisons were done using QuikSCAT and NCEP2 winds for both the mean and variability from 2000 to 2004. The comparisons showed that the model forced by QuikSCAT winds gives more realistic mean SST, 20 °C isotherm depth (Z20), and latent heat flux than NCEP2 winds do. Sensitivity experiments indicated that QuikSCAT mean wind stress is important for the improved mean SST, Z20, and latent heat release to the atmosphere in the eastern Pacific. QuikSCAT wind speed, through its effect on the turbulent heat fluxes, is most important for the mean SST in the western Pacific. Finally, there were comparable correlations with observations of both SST and Z20 on the intra-seasonal time scale between the model forced with QuikSCAT winds and the model forced with NCEP2 winds.     

Transient and quasi-steady-state dissolution of biotite at 22-25°C in high pH, sodium, nitrate, and aluminate solutions

Biotite dissolution under conditions of high pH and high aluminum, sodium, and nitrate concentrations analogous to those found in tank wastes at the Hanford Site was investigated using continuously stirred flow-through reactors at 22 to 25 °C. Experiments were designed to simulate tank leaks into the Hanford vadose zone where Fe(II) from biotite is the dominant reducing agent available to immobilize certain contaminants. Both non-steady-state and steady-state dissolution kinetics were quantified; interest in non-steady-state kinetics derives from the inherently transitory nature of tank leaks. Biotite was conditioned in pH 8 solutions to simulate the alkaline environment of the Hanford sediment, and then reacted in pH 10-14 solutions, some including 0.055 M Al(NO₃)₃ and/or 2 M or 6 M NaNO₃. Initial dissolution transients (intervals of rapid release rates that decay to slower steady-state rates) showed fast preferential release of K followed by near-stoichiometric release of Si, Al, and Mg, and slower release of Fe. Each increase in pH resulted in a second transient with the greatest amounts of Si, Al, and K released at pH 14, followed by pHs 13, 12, 11, and 10. Fe release also was highest at pH 14, but unchanging at pHs 10-13 within experimental error. Transient releases at high pH are attributed to dissolution of amphoteric secondary phases such as ferrihydrite that are inferred from saturation calculations and solid analyses to form during the conditioning interval. Transient release of Si was inhibited by the presence of 0.055 M Al(NO₃)₃; the effects of Al(NO₃)₃ and NaNO₃ on the release rates of Al, Fe, Mg, and K were variable and generally outweighed by the effect of pH. Quasi-steady-state release rates were slowest at pH 11-12 (10^−12.2 mol biotite m⁻² s⁻¹ for Si) and increased in either direction in pH away from this minimum (to 10^−11.5 at pHs 8 and 14 for Si). Fe release rates at high pH were sufficient to account for observed Cr(VI) reduction at Hanford. The net release rates of the major framework cations, from which the biotite dissolution rate is inferred, may reflect the precipitation of secondary phases or the alteration of biotite to vermiculite. The most extensive solid-phase alterations were observed in Na-enriched solutions.     

The partitioning of trace transition elements in crystal structures: a provocative review with applications to mantle geochemistry

Interrelationships between chemical compositions and crystal structures of minerals pioneered by Goldschmidt have been overlooked by modern geochemists. While analytical techniques and data for trace elements have become more sophisticated, progress has been slow in relating abundance data of individual elements to their relative enrichments in specific sites in mineral structures. The concept of diadochy has degenerated into an analytical relationship between major and trace elements, instead of its original crystallographic basis of replacement of one atom by another at a specific site in a crystal structure. Future interpretations of trace element data must consider the partitioning of atoms between different coordination sites in multisite mineral structures.The well-known partitioning of nickel and chromium into the earliest minerals during magmatic crystallization is extended to magma evolution in the mantle. The strong preference of Ni²⁺ and Cr³⁺ for octahedral sites in minerals leads to their enrichment in certain Iherzolites which are refractory residua during partial fusion of the mantle.