Soil hydrophobic effects on infiltration and catchment runoff

After dry summers or drought, eucalypt forest soils at two sites in southeastern Australia developed hydrophobic or non-wetting surface characteristics that reduced infiltration, measured using a sprinkling infiltrometer. At one site the development of hydrophobic conditions caused the rainfall to runoff conversion efficiency of a forested catchment to increase from 5 per cent to 15 per cent. Under non-hydrophobic conditions at this site, grassland always generated more runoff than forest. However, one major rainfall-runoff was recorded at a time of highly hydrophobic forest soil conditions and this storm generated greater runoff on the forested catchment than the grassland catchment. At the second site forest soils have naturally highly conductive surface layers because of a dense network of macropores and pathways for preferential flow. Hydrophobic conditions produced by drought caused soil water movement to be confined to only a few of the larger macropores exposed to surface ponded water. Even so, infiltration rates remained relatively high so that the impacts of hydrophobic soils were not translated into increased catchment runoff as at the first site.     

Temperature response to future urbanization and climate change

This study examines the impact of future urban expansion on local near-surface temperature for Sydney (Australia) using a future climate scenario (A2). The Weather Research and Forecasting model was used to simulate the present (1990–2009) and future (2040–2059) climates of the region at 2-km spatial resolution. The standard land use of the model was replaced with a more accurate dataset that covers the Sydney area. The future simulation incorporates the projected changes in the urban area of Sydney to account for the expected urban expansion. A comparison between areas with projected land use changes and their surroundings was conducted to evaluate how urbanization and global warming will act together and to ascertain their combined effect on the local climate. The analysis of the temperature changes revealed that future urbanization will strongly affect minimum temperature, whereas little impact was detected for maximum temperature. The minimum temperature changes will be noticeable throughout the year. However, during winter and spring these differences will be particularly large and the increases could be double the increase due to global warming alone at 2050. Results indicated that the changes were mostly due to increased heat capacity of urban structures and reduced evaporation in the city environment.     

Assessing the institutional capacity to adapt to climate change: a case study in the Cambodian health and water sectors

Institutional capacity is an important element for climate change adaptation (CCA) and the development of such capacity is a great challenge in a Least Developed Country like Cambodia where resources are limited. An important first step to increasing capacity is via an understanding of the level of existing capacity; future priorities can then be subsequently identified. This study aimed to assess the capacity of organizations to implement climate change activities in Cambodia in order to provide such a basis for building capacity. Four elements of capacity were investigated in this research: (1) financial resources, (2) cooperation and coordination of stakeholders, (3) availability and quality of information on vulnerability and adaptation to climate change, and (4) the level of understanding of climate change vulnerability and adaptation. The data were collected through semistructured interviews with a wide range of government and non-government informants across a number of sectors. Results of the study showed that informants perceived capacity for CCA to be very constrained, especially in terms of financial resources and cooperation, and addressing these factors was ranked as the highest climate change capacity priority. Institutional capacity constraints were considered to relate more generally to weak governance of CCA. In light of our research findings, the absence of local higher education institutions in CCA activities should be addressed. The support of such institutions would provide an important mechanism to progress both capacity development as well as partnerships and coordination between different types of organizations and relevant sectors.

Policy relevance

Capacity for CCA within Cambodian health and water sectors was perceived to be very constrained across a range of interdependent factors. Increasing funding was ranked as the highest priority for building capacity for CCA; however, governance factors such as ‘improved cooperation’ were also ranked highly. Improving stakeholders' awareness of the availability of adaptation funds and resources, and their responsiveness to funding criteria, is an important implication of our research, as is improving the mobilization of local resources and the private sector. To address the issue of weak cooperation among stakeholders, improving the coordination function of the National Climate Change Committee (NCCC) regarding stakeholder engagement and capacity building is crucial. Ensuring that CCA activities are based on sound information and knowledge from across different disciplines and, importantly, include the perspectives of vulnerable people themselves, ultimately underpins and supports the realization of the above priorities.     

Developing a model of climate change behavior among adolescents

Research on adolescent climate change perceptions has uncovered key insights about how knowledge, concern, and hope might relate to behavior and the potential for educational interventions to influence these factors. However, few of these studies have employed treatment/control designs that might address causality and none have addressed how these factors might interact to influence behavior. We developed a model of behavior change where a climate education treatment impacted knowledge, knowledge impacted hope and concern, and hope and concern together impacted behavior. We empirically tested the utility of this model and the causal relationships within it using a pre/post, treatment/control evaluation of climate education among adolescents in North Carolina, USA (n?=?1041). We found support for a causal relationship between the treatment and gains in knowledge, but not between treatment and behavior. However, we did find support for a path model in which climate change knowledge positively relates to increased climate change concern and hope, and increases in concern and hope predict changes in pro-environmental behavior. Low SES was related to smaller gains in knowledge, concern, and behavior. Our results contribute to a theoretical understanding of climate change behaviors among adolescents and suggest that climate education aiming to change behavior should focus on building hope and concern.     

Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.     

Elemental and mineralogical changes in soils due to bioturbation along an earthworm invasion chronosequence in Northern Minnesota

Minnesota forested soils have evolved without the presence of earthworms since the last glacial retreat. When exotic earthworms arrive, enhanced soil bioturbation often results in dramatic morphological and chemical changes in soils with negative implications for the forests’ sustainability. However, the impacts of earthworm invasion on geochemical processes in soils are not well understood. This study attempts to quantify the role of earthworm invasion in mineral chemical weathering and nutrient dynamics along an earthworm invasion chronosequence in a sugar maple forest in Northern Minnesota. Depth and rates of soil mixing can be tracked with atmospherically derived short lived radioisotopes ²¹⁰Pb and ¹³⁷Cs. Their radioactivities increase in the lower A horizon at the expense of the peak activities near the soil surface, which indicate that soil mixing rate and its depth reach have been enhanced by earthworms. Enhanced soil mixing by earthworms is consistent with the ways that the vertical profiles of elemental and mineralogical compositions were affected by earthworm invasion. Biologically cycled Ca and P have peak concentrations near the soil surface prior to earthworm invasion. However, these peak abundances significantly declined in the earthworm invaded soils presumably due to enhanced soil mixing. It is clear that enhanced soil mixing due to earthworms also profoundly altered the vertical distribution of most mineral species within A horizons. Though the mechanisms are not clear yet, earthworm invasion appears to have contributed to net losses of clay mineral species and opal from the A horizons. As much as earthworms vertically relocated minerals and elements, they also intensify the contacts between organic matter and cations as shown in the increased amount of Ca and Fe in organically complexed and in exchangeable pools. With future studies on soil mixing rates and elemental leaching, this study will quantitatively and mechanically address the role of earthworms in geochemical evolution of soils and forests’ nutrient dynamics.     

Colloidal arsenic composition from abandoned gold mine tailing leachates in Nova Scotia,Canada

Asymmetric-Flow Field-Flow Fractionation (AsFlFFF) coupled to an inductively coupled plasma-mass spectrometer (ICP-MS) was used to determine whether colloidal As exists in mine tailings from abandoned Au mine sites in Nova Scotia. Using this technique, the chemical composition and the size of the colloidal material was determined. Tailings samples were collected from the sites and leachates were analyzed. The resulting fractograms showed the presence of colloidal As. Arsenic co-elutes with Fe and Al suggesting that the As is associated with colloids containing these elements. The colloidal material present in the samples has a calculated median size of 7 nm. The leachates were also analyzed for totalAs, Fe and Al using ICP-MS. The colloidal fraction was determined to account for approximately 20% of the total dissolved As present in these samples. Dissolved As concentrations at the selected mine sites are very high and the arbitrary cutoff for dissolved still incorporates colloidal material. Therefore. it is important to distinguish between truly dissolved and colloidal As as the speciation will affect the toxicity and mobility of As at these locations.     

Silurian and Devonian systems

The Ediacara mineral field is situated 30 km W of Beltana on the western margins of the Flinders Ranges, South Australia, and consists of silver‐lead and copper deposits in lower Cambrian carbonate rocks that contain anomalous base‐metal contents throughout the Adelaide Geosyncline. The lower Cambrian rocks, which consist of the basal Parachilna Formation and overlying Ajax Limestone, rest disconformably on the Precambrian, and at Ediacara occupy a shallow N‐S elongate syncline near the hinge zone of the Adelaide Geosyncline. The main primary ore minerals of the silver‐lead mineralization are galena and pyrite, with very minor chalcopyrite and sphalerite, and rare tetrahedrite and pearceite. The gangue consists mainly of silica (both chalcedony and quartz), with minor dolomite and rare barite. The mineralization is stratabound and occurs in conformable zones, the lowest of which commences about 30–50 m above the base of the Cambrian sequence. The host to the silver‐lead mineralization, the Ajax Limestone, can be subdivided into three units which represent a set of lithologies, structures and organic traces indicative of a shallow near‐shore carbonate environment. The silver‐lead mineralization is mainly present in sandy and laminated dolomites which were deposited in an environment ranging from sub‐tidal to bar and channel and tidal flat, respectively. Four types of mineralization have been recognized; disseminated sulphides of syngenetic and/or diagenetic origin and epigenetic concentrations along stylolites, in veins and as breccia fillings. Post‐depositional solution activity has affected a large proportion of the carbonate sequence. The effects of this activity range from stylolites through stylobreccias to solution collapse breccias. The epigenetic concentrations of mineralizations have apparently been formed by the remobilization of the disseminated sulphides during solution activity. The ore and gangue minerals of the epigenetic mineralization display both euhedral forms and distinct colloform banding, and framboidal textures have also been observed in both pyrite and galena. There is evidence of repeated episodic precipitation and no simple paragenetic sequence can be recognized. Fluid inclusions in silica and dolomite associated with the epigenetic mineralization have homogenization temperatures of 159 to 199°C and freezing temperatures that indicate the fluids to be saline brines containing NaCl with CaCl₂ and/or MgCl₂. Sulphur isotope analyses show a range of 8³⁴S values from ‐12.5 to +8.6 per mil, with no evidence of significant differences between the four types of mineralization. The data suggest deposition of the disseminated sulphides as a result of biological reduction of seawater sulphate in a system partially open with respect to sulphate supply. Subsequent remobilization of sulphides apparently involved little or no sulphur isotope fractionation. The Ediacara silver‐lead deposits have many features in common with Mississippi Valley‐type lead‐zinc deposits and appear to have similarities in terms of genesis, in that the epigenetic mineralization has been formed as a result of post‐depositional solution activity during diagenesis in a sedimentary basin. The scale of transport of the metals deposited as the epigenetic mineralization at Ediacara appears, however, to have been very much less than that of the metals in other Mississippi Valley‐type deposits.     

Towards a more habitable Mars — or — the coming martian spring

Two schemes are presented in which matter is moved closer to Mars so as to increase the equinoctal precession period of Mars. In such a way the Martian springs, during which Mars is habitable in the long winter model of Sagan (1971), could be extended and, in fact, prolonged indefinitely. The schemes involve using solar energy to move the satellite Phobos and/or material from the asteroid belt. Difficulties exist with the proposals but they are presented to stimulate discussion.