Seasonal changes in imposex and tissue burden of butyltin compounds in Thais clavigera populations along the coastal area of Mirs Bay, China

We assessed the current status of tributyltin (TBT) contamination of Thais clavigera (Gastropoda) along the coastal area of Mirs Bay, China for the first time. The snail samples were collected from 10 different sites in the summer (June) and winter (December) of 2006, respectively. They were analyzed for imposex status, i.e. relative penis size index (RPSI) and vas deferens sequence index (VDSI), followed by quantification of butyltins in their tissues. Most of the collected females suffered from imposex, but the level of butyltin contamination varied with the distance from Yantian Port, which is currently the fourth busiest container port in the world. The tissue concentration of TBT varied with season. For a particular site, the winter samples in general contained much higher concentration of TBT than the summer samples. RPSI, VDSI and organotin concentrations were higher in T. clavigera collected from sites closer to the Port, such as the Seafood Street and Kat O. Both RPSI and VDSI were positively correlated with the tissue burden of tributyltin. VDSI exhibited little seasonal variability, whereas RPSI showed marked seasonal variability, with lower values in the summer samples. The current results will serve as an important reference for long-term monitoring of butyltin contamination in this area.     

荒漠绿洲湿地土壤水热盐动态过程及其影响机制

以甘肃临泽荒漠绿洲湿地为研究对象,通过对土壤温度、含水量、电导率及蒸散量的野外观测,在植物生长期和冻融期分别深入分析水热盐耦合运移过程及其影响因素,探讨水热梯度对盐分运移及其分布格局的控制作用。结果表明：土壤温度整体呈现出春夏季逐渐升高、秋冬季降低趋势。在冻结期,土壤表现为脱盐状态,表层电导率由2.8 mS·cm^-1降到1.2 mS·cm^-1;而在消融期为积盐状态,表层电导率由1.2 mS·cm^-1升到3.7 mS·cm^-1。在生长期,土壤含水量和电导率波动较为剧烈,表层含水量27%~43%,表层电导率3~5.5 mS·cm^-1,土壤脱盐、积盐反复出现。全年蒸散量总体呈单峰变化趋势,年蒸散量507 mm;土壤电导率与蒸散量呈正比关系,与地下水位呈负相关关系;蒸散发作用是土壤表层积盐的主要驱动力,而地下水波动影响着湿地脱盐、洗盐过程。因此,荒漠绿洲湿地土壤盐分累积过程是水分运移和热量传输过程发生变化的结果。     

Variability in Particle Mixing Rates in Sediments with Polymetallic Nodules in the Equatorial Eastern Pacific as Determined from Measurements of Excess <Superscript>210</Superscript>Pb

Radionuclide activities of ²¹⁰Pb and ²²⁶Ra were measured to determine bioturbation coefficients (D_b) in seven sediment cores from the Korean licensed block for polymetallic nodules in the Clarion–Clipperton Fracture Zone. Variability in D_b is considered in the context of the sedimentological, geochemical, and geotechnical properties of the sediments. D_b values in the studied cores were estimated using a steady-state diffusion model and varied over a wide range from 1.1 to 293 cm²/yr with corresponding mixing depths (L) of 26 to 144 cm. When excepting for spurious results obtained from cores where diffusive mixing does not apply, D_b values range from 1.1 to 9.0 cm²/yr with corresponding mixing depths (L) of 26 to 63 cm. Such wide variability in D_b and L values is exceptional in sites with water depths of ～5000 m and is attributed in this study to an uneven distribution of sediment layers with different shear strengths and total organic carbon (TOC) contents, caused by erosion events. The studied cores can be grouped into two categories based on lithologic associations: layers with high maximum shear strength (MSS) and low TOC content, showing a narrow range of D_b values (1.1–9.0 cm²/yr); and layers with low MSS and high TOC content, yielding much higher D_b values of over 30 cm²/yr. The distribution of different lithologies, and the resultant spatial variability in MSS and labile organic matter content, controls the presence and maximum burrowing depth of infauna by affecting their mobility and the availability of food. This study provides a unique case showing that shear strength, which relates to the degree of sediment consolidation, might be an important factor in controlling rates of bioturbation and sediment mixing depths.     

The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell:

Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag

where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell:

Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag

The results have been fitted to the equations:

lnK^*₁ = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S^0.5 + 0.08468345S − 0.00654208S¹

InK^*₂ = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S^0.5 + 0.1130822S − 0.00846934S^1.5

where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.     

A low level supplementary heating system for free divers

A simple and effective method of heating divers in extreme cold water has been developed. The local heating concept utilizes a uniformly distributed granular mixture of magnesium and iron particles packed in small sachets. Upon activation by sea water, the two metal mixture behaves as a multitude of short-circuited electrolytic cells, producing thermal energy rather than electrical energy. The 45 mm-square sachets may be placed where heating is required on the diver's body, thus giving rise to the term “local heating”, obviously, the heating system requires no pumping device, or distribution network. Heating rate and duration of output of the sachets are controlled by particle size, and mixture ratio of the constituent Mg and Fe particles.This paper described the development, testing and performance of the heating sachets. Results of live tests in different dive situations are also presented and discussed.     

Regulation of Tilapia metallothionein gene expression by heavy metal ions

Tilapia is a common fish species inhabiting inland waters and estuarine regions in Hong Kong and Southeast Asia, and useful for bio-monitoring of metal pollution. Metallothionein (MT) gene expression in fish tissues has been useful to sub-lethal risk assessment as biomarker of exposure to metal ions in fishes inhabiting metal contaminated area. To investigate metal inductions of Tilapia MT gene expression in vivo, Tilapias were injected with different concentrations of heavy metals and tissues were then removed for quantitative PCR assay using mimic PCR methods. All of the metal ions tested (Cu(2+), Cd(2+), Hg(2+), Ni(2+), Pb(2+) and Zn(2+)) were able to induce hepatic MT mRNA levels. Renal MT mRNA levels of Cd(2+) and Zn(2+) treated fish was not induced with significant fold induction, however MT mRNA levels in gills were sensitive to the administrations of these metal ions. These data indicated that Tilapia MT mRNA levels in gills and liver are sensitive biomarker of exposure to various metal ions.     

Distribution of deep near-inertial waves observed in the Kuroshio Extension

The distribution of deep near-inertial waves (NIWs) is investigated using data mainly from an array of 46 near-bottom acoustic current meter sensors spanning a 600 km × 600 km region as part of the Kuroshio Extension System Study during 2004–2006. The deep NIW distribution is interpreted in the context of both upper-layer and near-bottom mapped circulations. The wintertime-mean mixed-layer NIW energy input, modeled from observed wind stress, has the same range of values north and south of the Kuroshio Extension in this region. Yet, the wintertime-mean deep NIW energy distribution reveals a sharp factor-of-5 decrease from north to south of the Kuroshio jet. This direct observational evidence shows that the Kuroshio Extension blocks the equatorward propagation of NIWs. The NIW energy that does reach the sea floor within the subset of wintertime observations in the subtropical gyre arrives with patchy spatial and temporal distribution. Elevated NIW energy in deep water is associated with anticyclones in the deep barotropic flow and unassociated with upper layer eddies.     

某农药化工企业密集区地下水污染评价

通过分析研究某农药化工企业密集区地下水水质及污染状况,按照国家有关标准,采用单指标评价法和内梅罗指数法对地下水的质量进行评价。评价结果显示：该区域地下水水质普遍较差,大部分为Ⅳ类及Ⅴ类水质,已不适于饮用。然后对该区域地下水污染进行评价,结果显示地下水有机和无机污染严重,并形成了以某农药化工企业为污染源并沿岩溶地下水流向的一个卤代烃类有机物污染羽,这表明造成该研究区岩溶地下水污染的主要污染源为某农药化工企业。最后根据评价结果,提出相应的控制地下水污染的建议和措施,为该地区制定地下水开发利用规划提供科学依据。     

Subliquidus glass-glass immiscibility along the albite-diopside join

A calorimetric study has shown that glasses along the albite-diopside join in the system albiteanorthite-diopside have positive enthalpies of mixing. Thermodynamic calculations based on these data describe a nearly symmetric, metastable, subliquidus irascibility gap along the join with a critical temperature at 910 K. The existence of the miscibility gap was tested experimentally by annealing an Ab₅₀Di₅₀ glass at 748 K and 823 K. Annealed glasses were examined by optical microscopy and by scanning and transmission electron microscopy. The glasses showed morphological and chemical features consistent with unmixing of two glass phases. The apparent mechanism of phase separation involves initial spinodal decomposition followed by coarsening to produce 0.1 μm–0.3 μm spherical glass phases.