The behaviour of dissolved arsenic in the estuary of the River Beaulieu

The chemical forms and distribution of dissolved arsenic species in the estuary of the River Beaulieu (Hampshire, U.K.) are reported. ‘Inorganic arsenic (V)’ in both the marine and riverine estuary inputs are in true solution, passing through ultrafiltration membranes having a nominal molecular weight cut-off of 500 daltons. Extensive removal of dissolved ‘inorganic arsenic (V)’ is apparent from the distribution of arsenic in the estuary, with laboratory mixing experiments indicating that removal is favoured in the low salinity region. ‘Inorganic arsenic (III)’ and methylated arsenic species account for up to 41% and 70% of the dissolved arsenic, respectively, but are only found during the warmer months when water temperatures exceed ca. 12°C.     

Coral recruitment onto an experimental pulverised fuel ash-concrete artificial reef

An experimental artificial reef was deployed in December 1993 at Hoi Ha Wan Marine Park, Hong Kong. This is the first study documenting natural scleractinian coral recruitment onto a stabilised pulverised fuel ash (PFA)-concrete artificial reef. Visible recruits were first recorded 9-10 months after the placement of reef blocks, i.e., in the autumn of 1994. Two scleractinians, Oulastrea crispata and Culicia japonica, were recruited. The recruit density of the former was much greater than the latter. The spatial recruitment pattern of the corals was observed to be affected by the orientation of the attaching surface. O. crispata settled predominantly on the undersides of the reef blocks. There was an edge effect on O. crispata recruitment. C. japonica, however, had a preference for exposed surfaces. O. crispata did not show a preference for block composition whereas C. japonica favoured blocks with high (75% by volume) PFA levels. This shows that PFA-concrete is a potential substratum for artificial reef construction, especially when such reefs aim at rehabilitating corals.     

Microbial ecology of the stratified water column of the Black Sea as revealed by a comprehensive biomarker study

The stratified water column of the Black Sea is partitioned into oxic, suboxic, and euxinic zones, each characterized by different biogeochemical processes and by distinct microbial communities. In 2003, we collected particulate matter by large volume in situ filtration at the highest resolution to date for lipid biomarker analysis and bacterioplankton for enumeration of major prokaryotic groups. Abundances of several prokaryotic groups were estimated using CARD-FISH probes specific for Bacteria, Archaea (Crenarchaeota and Euryarchaeota), epsilonproteobacteria (mainly sulfide oxidizers) and sulfate reducing bacteria. We also measured a wide range of bacterial and archaeal lipid biomarkers. Depth distributions of diagnostic biomarkers are matched with zonation of microbial processes, including aerobic bacterial oxidation of methane, oxidation of ammonium by bacteria and archaea, metal reduction, and sulfide oxidation at the chemocline, and bacterial sulfate reduction and anaerobic oxidation of methane by archaea in the anoxic zone. Cell densities for archaea and sulfate reducing bacteria are estimated based on water column biomarker concentrations and compared with CARD-FISH results.     

Joint NANCAY RADIOHELIOGRAPH AND LASCO OBSERVATIONS OF CORONAL MASS EJECTIONS – II. The 9 July 1996 Event

The development of a coronal mass ejection on 9 July 1996 has been analyzed by comparing the observations of the LASCO/SOHO coronagraphs with those of the Nancay radioheliograph. The spatial and temporal evolution of the associated radioburst is complex and involves a long-duration continuum. The analysis of the time sequence of the radio continuum reveals the existence of distinct phases associated with distinct reconnection processes and magnetic restructuring of the corona. Electrons are accelerated in association with these reconnection processes. An excellent spatial association is found between the position and extension of the radio source and the CME seen by LASCO. Furthermore, it is shown that the topology and evolution of the source of the radio continuum involve successive interactions between two systems of loops. These successive interactions lead to magnetic reconnection, then to a large scale coronal restructuring. Thus electrons of coronal origin may have access to the interplanetary medium in a large range of heliographic latitudes as revealed by the Ulysses observations.     

Post-Palaeozoic evolution of weathered landsurfaces in Uganda by tectonically controlled deep weathering and stripping

A model for the evolution of weathered landsurfaces in Uganda is developed using available geotectonic, climatic, sedimentological and chronological data. The model demonstrates the pivotal role of tectonic uplift in inducing cycles of stripping, and tectonic quiescence for cycles of deep weathering. It is able to account for the development of key landforms, such as inselbergs and duricrust-capped plateaux, which previous hypotheses of landscape evolution that are based on climatic or eustatic controls are unable to explain. Development of the Ugandan landscape is traced back to the Permian. Following late Palaeozoic glaciation, a trend towards warmer and more humid climates through the Mesozoic enabled deep weathering of the Jurassic/mid-Cretaceous surface in Uganda during a period of prolonged tectonic quiescence. Uplift associated with the opening South Atlantic Ocean terminated this cycle and instigated a cycle of stripping between the mid-Cretaceous and early Miocene. Deep weathering on the succeeding Miocene to recent (African) surface has occurred from Miocene to present but has been interrupted in the areas adjacent to the western rift where development of a new drainage base level has prompted cycles of stripping in the Miocene and Pleistocene.     

Atmospheric effects in the remote sensing of phytoplankton pigments

We investigate the accuracy with which relevant atmospheric parameters must be estimated to derive phytoplankton pigment concentrations (chlorophyll a plus phaeophytin a ) of a given accuracy from measurements of the ocean's apparent spectral radiance at satellite altitudes. The analysis is limited to an instrument having the characteristics of the Coastal Zone Color Scanner scheduled to orbit the Earth on NIMBUS-G. A phytoplankton pigment algorithm is developed which relates the pigment concentration (C) to the three ratios of upwelling radiance just beneath the sea surface which can be formed from the wavelengths () 440, 520 and 550 nm. The pigment algorithm explains from 94 to 98% of the variance in log₁₀ C over three orders of magnitude in pigment concentration. This is combined with solutions to the radiative transfer equation to simulate the ocean's apparent spectral radiance at satellite altitudes as a function of C and the optical properties of the aerosol, the optical depth of which is assumed to be proportioned to ^-n . A specific atmospheric correction algorithm, based on the assumption that the ocean is totally absorbing at 670 nm, is then applied to the simulated spectral radiance, from which the pigment concentration is derived. Comparison between the true and derived values of C show that: (1) n is considerably more important than the actual aerosol optical thickness; (2) for C 0299-1 0.2 g l^-1 acceptable concentrations can be determined as long as n is not overestimated; (3) as C increases, the accuracy with which n must be estimated, for a given relative accuracy in C, also increases; and (4) for C greater than about 0.5 g 1^-1, the radiance at 440 nm becomes essentially useless in determining C. The computations also suggest that if separate pigment algorithms are used for C 1gl^-1 and C 1 gl^-1, accuracies considerably better than ±± in log C can be obtained for C 1 g l^-1 with only a coarse estimate of n, while for C 10 gl^-1, this accuracy can be achieved only with very good estimates of n.Contribution No. 387 from the NOAA/ERL Pacific Environmental Laboratory.On leave from Department of Physics, University of Miami, Coral Gables, Florida.     

Climatological aspects of the tropical convective boundary layer

The characteristics of a boundary layer depend both on conditions at the surface and in the interior of the medium. In the undisturbed tropics, the latter are largely determined by subsidence and by infrared radiational cooling. One-dimensional models are used to establish relationships between the inversion height, subsidence, upper-air humidity and sea-surface temperature. In particular, it is shown that a universally colder tropical ocean would probably be covered by more extensive clouds.Contribution No. 1700 Rosenstiel School of Marine and Atmospheric Science, University of Miami.