Planetary X-ray fluorescence analogue laboratory experiments and an elemental abundance algorithm for C1XS

We have conducted laboratory experiments as an analogue to planetary XRF (X-ray fluorescence) missions in order to investigate the role of changing incidence (and phase) angle geometry and sample grain-size on the intensity of XRF from regolith-like samples. Our data provide evidence of a grain-size effect, where XRF line intensity decreases with increasing sample grain-size, as well as an almost ubiquitous increase in XRF line intensity above incidence angles of ∼60°. Data from a lunar regolith simulant are also used to test the accuracy of an XRF abundance algorithm developed at the Rutherford Appleton Laboratory (RAL), which is used to estimate the major element abundance of the lunar surface from Chandrayaan-1 X-ray Spectrometer (C1XS) XRF data. In ideal situations (i.e., when the input spectrum is well defined and the XRF spectrum has a sufficient signal to noise ratio) the algorithm can recover a known rock composition to within 1.0 elemental wt% (1σ).     

Trade-offs of different land and bioenergy policies on the path to achieving climate targets

Many papers have shown that bioenergy and land-use are potentially important elements in a strategy to limit anthropogenic climate change. But, significant expansion of bioenergy production can have a large terrestrial footprint. In this paper, we test the implications for land use, the global energy system, emissions and mitigation costs of meeting a specific climate target, using a single fossil fuel and industrial sector policy instrument, but with five alternative bioenergy and land-use policy architectures. These scenarios are illustrative in nature, and designed to explore trade-offs. We find that the policies we examined have differing effects on the different segments of the economy. Comprehensive land policies can reduce land-use change emissions, increasing allowable emissions in the energy system, but have implications for the cost of food. Bioenergy penalties and constraints, on the other hand, have little effect on food prices, but result in less bioenergy and thus can increase mitigation costs and energy prices.     

Commodifying poverty: gentrification and consumption in Vancouver’s Downtown Eastside

The Downtown Eastside of Vancouver, British Columbia, remains one of the poorest neighborhoods in Canada, yet is also a site of rapid gentrification. Both new and revitalized restaurants have created new spaces of consumption, transforming the neighborhood into a dining destination. Site visits and an analysis of the discourses used in newspaper articles and magazine features, as well as on blogs and in other online spaces, indicate that the presence of poor and marginalized residents of the Downtown Eastside is one of the reasons for some consumers’ decisions to visit new upscale establishments in the area. Analysis of advertisements and other primary documents indicates that the presence of poor and marginalized residents has become a competitive niche for the promotion of distinctive and authentic culinary adventures. This trend toward poverty tourism signals a shift from the simple displacement of low-income residents to a more complex form of gentrification in which residents face spatial management and control while their poverty is commodified.     

Geochemical mapping using stream sediments in west-central Nigeria: Implications for environmental studies and mineral exploration in West Africa

This paper provides an overview of regional geochemical mapping using stream sediments from central and south-western Nigeria. A total of 1569 stream sediment samples were collected and 54 major and trace elements determined by ICP-MS and Au, Pd and Pt by fire assay. Multivariate statistical techniques (e.g., correlation analysis and principal factor analysis) were used to explore the data, following appropriate data transformation, to understand the data structure, investigate underlying processes controlling spatial geochemical variability and identify element associations. Major geochemical variations are controlled by source geology and provenance, as well as chemical weathering and winnowing processes, more subtle variations are a result of land use and contamination from anthropogenic activity.     

Effect of groundwater pH and ionic strength on strontium sorption in aquifer sediments: Implications for Sr mobility at contaminated nuclear sites

Strontium-90 is a beta emitting radionuclide produced during nuclear fission, and is a problem contaminant at many nuclear facilities. Transport of ⁹⁰Sr in groundwaters is primarily controlled by sorption reactions with aquifer sediments. The extent of sorption is controlled by the geochemistry of the groundwater and sediment mineralogy. Here, batch sorption experiments were used to examine the sorption behaviour of ⁹⁰Sr in sediment–water systems representative of the UK Sellafield nuclear site based on groundwater and contaminant fluid compositions. In experiments with low ionic strength groundwaters (<0.01 mol L⁻¹), pH variation is the main control on sorption. The sorption edge for ⁹⁰Sr was observed between pH 4 and 6 with maximum sorption occurring (K_d ∼ 10³ L kg⁻¹) at pH 6–8. At ionic strengths above 10 mmol L⁻¹, and at pH values between 6 and 8, cation exchange processes reduced ⁹⁰Sr uptake to the sediment. This exchange process explains the lower ⁹⁰Sr sorption (K_d ∼ 40 L kg⁻¹) in the presence of artificial Magnox tank liquor (IS = 29 mmol L⁻¹). Strontium K-edge EXAFS spectra collected from sediments incubated with Sr²⁺ in either HCO₃-buffered groundwater or artificial Magnox tank liquor, revealed a coordination environment of ∼9 O atoms at 2.58–2.61 Å after 10 days. This is equivalent to the Sr²⁺ hydration sphere for the aqueous ion and indicates that Sr occurs primarily in outer sphere sorption complexes. No change was observed in the Sr sorption environment with EXAFS analysis after 365 days incubation. Sequential extractions performed on sediments after 365 days also found that ∼80% of solid associated ⁹⁰Sr was exchangeable with 1 M MgCl₂ in all experiments. These results suggest that over long periods, ⁹⁰Sr in contaminated sediments will remain primarily in weakly bound surface complexes. Therefore, if groundwater ionic strength increases (e.g. by saline intrusion related to sea level rise or by design during site remediation) then substantial remobilisation of ⁹⁰Sr is to be expected.     

Community respiration of decomposing plants in Oregon estuarine marshes

Community respiration rates in air and water were measured as indicators of the decomposition rate of dead plant tissue from nine stands of plants in two Oregon estuarine marshes. Respiration rates were low and relatively constant from November to February; during warmer periods several patterns emerged. The highest respiration rates for the most and least active communities differed up to one order of magnitude. The moisture, nitrogen, and crude fibre content, as well as plant shoot and canopy structure, appeared to be important determinants of the respiration rate. Comparisons of aerial and aquatic respiration rates for a single date may be useful for determining the recent moisture history of the tissue. Rates of dead plant community respiration in Pacific North-west marshes equalled and, in one case, exceeded those in the Atlantic South-east.