The influence of a season of extreme wet weather events on exposure of the World Heritage Area Great Barrier Reef to pesticides

The 2010-2011 wet season was one of extreme weather for the State of Queensland, Australia. Major rivers adjacent to the Great Barrier Reef (GBR) were discharging at rates 1.5 to >3 times higher than their long term median. Exposure to photosystem II herbicides has been routinely monitored over a period of up to 5 years at 12 inshore GBR sites. The influence of this wet season on exposure to photosystem II herbicides was examined in the context of this long-term monitoring record and during flood plume events in specific regions. Median exposures expressed as diuron equivalent concentration were an average factor of 2.3 times higher but mostly not significantly different (p<0.05) to the median for the long-term monitoring record. The herbicides metolachlor and tebuthiuron were frequently detected in flood plume waters at concentrations that reached or exceeded relevant water quality guidelines (by up to 4.5 times).     

Multiwavelength study of Cygnus A – I. Precession and slow jet speeds from radio observations

We study the jet and counterjet of the powerful classical double Fanaroff–Riley type II (FR II) radio galaxy Cygnus A as seen in the 5-, 8- and 15-GHz radio bands using the highest spatial resolution and signal-to-noise ratio archival data available. We demonstrate that the trace of the radio knots that delineate the jet and counterjet deviates from a straight line and that the inner parts can be satisfactorily fitted with the precession model of Hjellming & Johnston. The parameter values of the precession model fits are all plausible although the jet speed is rather low (≲ 0.5 c ) but, on investigation, found to be consistent with a number of other independent estimates of the jet speed in Cygnus A. We compare the masses and precession periods for sources with known precession and find that for the small number of active galactic nuclei with precessing jets the precession periods are significantly longer than those of microquasars.     

Beach Morphodynamics influenced by an ebb‐tidal delta on the north Florida Atlantic coast

Tidal inlets interrupt longshore sediment transport, thereby exerting an influence on adjacent beach morphology. To investigate the details and spatial extent of an inlet's influence, we examine beach topographic change along a 1.5 km coastal reach adjacent to Matanzas Inlet, on the Florida Atlantic coast. Analyses of beach morphology reveal a behavioral change between 0.64 and 0.86 km from the inlet channel centerline, interpreted to represent the spatial extent of inlet influence. Beyond this boundary, the beach is narrow, exhibits a statistically significant inverse correlation of shoreline position with offshore wave conditions, and has a uniform alongshore pattern in temporal behavior, as determined from empirical orthogonal function (EOF) analysis. On the inlet side of the boundary, the beach experiences monotonic widening (with proximity to the inlet), lacks spatial consistency in correlation between shoreline position and wave conditions, and exhibits an irregular pattern in spatial EOF modes. We augment the field observations with numerical modeling that provides calculations of wave setup and nearshore current patterns near the inlet, highlighting the effects of the ebb‐tidal delta on the assailing waves. The modeling results are verified by a natural experiment that occurred during May 2009, when a storm‐produced sedimentary mass accreted to the lower beach, then subsequently split into two oppositely directed waves of sediment that migrated away from the initial accretion site in the subsequent months. Our results suggest that the ebb‐tidal delta produces a pattern of wave setup that creates a pressure gradient driving an alongshore flow that opposes the longshore currents derived from breaking of obliquely oriented incident waves. The resulting recirculation pattern on the margin of the ebb‐tidal delta provides a mechanism through which the inlet influences adjacent barrier island beach morphology. Copyright © 2016 John Wiley & Sons, Ltd.     

Spatio-Temporal Surface Shear-Stress Variability in Live Plant Canopies and Cube Arrays

This study presents spatiotemporally-resolved measurements of surface shear-stress τ _s in live plant canopies and rigid wooden cube arrays to identify the sheltering capability against sediment erosion of these different roughness elements. Live plants have highly irregular structures that can be extremely flexible and porous resulting in considerable changes to the drag and flow regimes relative to rigid imitations mainly used in other wind-tunnel studies. Mean velocity and kinematic Reynolds stress profiles show that well-developed natural boundary layers were generated above the 8 m long wind-tunnel test section covered with the roughness elements at four different roughness densities (λ = 0, 0.017, 0.08, 0.18). Speed-up around the cubes caused higher peak surface shear stress than in experiments with plants at all roughness densities, demonstrating the more effective sheltering ability of the plants. The sheltered areas in the lee of the plants are significantly narrower with higher surface shear stress than those found in the lee of the cubes, and are dependent on the wind speed due to the plants ability to streamline with the flow. This streamlining behaviour results in a decreasing sheltering effect at increasing wind speeds and in lower net turbulence production than in experiments with cubes. Turbulence intensity distributions suggest a suppression of horseshoe vortices in the plant case. Comparison of the surface shear-stress measurements with sediment erosion patterns shows that the fraction of time a threshold skin friction velocity is exceeded can be used to assess erosion of, and deposition on, that surface.     

Magmatism and metamorphism at ca. 1.45 Ga in the northern Gawler Craton: The Australian record of rifting within Nuna (Columbia)

U-Pb monazite and zircon geochronology and calculated metamorphic phase diagrams from drill holes in the northern Gawler Craton, southern Australia, reveal the presence of ca. 1.45 Ga magmatism and metamorphism. Magmatism and granulite facies metamorphism of this age has not previously been recognised in the Gawler Craton. The magmatic rocks have steep LREE-enriched patterns and high Ga/Al values, suggesting they are A-type granites. Calculated metamorphic forward models suggest that this event was associated with high apparent thermal gradients and reached pressures of 3.2 -5.4 kbar and temperatures of 775-815℃. The high apparent thermal gradients may reflect pluton-enhanced metamorphism, consistent with the presence of A-type granites. The recognition of ca. 1.45 Ga tectonism in the northern Gawler Craton is added to a compilation of ca. 1.50 -1.40 Ga magmatism, shear zone reactivation, rift basin development and isotope resetting throughout the South and North Australian Cratons that shows that this event was widespread in eastern Proterozoic Australia. This event is stylistically similar to ca. 1.45 Ga A-type magmatism and high thermal gradient metamorphism in Laurentia in this interval and provides further support for a connection between Australia and Laurentia during the Mesoproterozoic. The tectonic setting of the 1.50-1.40 Ga event is unclear but may record rifting within the Nuna(or Columbia) supercontinent, or a period of intracontinental extension within a long-lived convergent setting.     

Vertical distributions of chlorophyll in deep, warm monomictic lakes

The factors affecting vertical distributions of chlorophyll fluorescence were examined in four temperate, warm monomictic lakes. Each of the lakes (maximum depth >80 m) was sampled over 2 years at intervals from monthly to seasonal. Profiles were taken of chlorophyll fluorescence (as a proxy for algal biomass), temperature and irradiance, as well as integrated samples from the surface mixed layer for chlorophyll a (chl a) and nutrient concentrations in each lake. Depth profiles of chlorophyll fluorescence were also made along transects of the longest axis of each lake. Chlorophyll fluorescence maxima occurred at depths closely correlated with euphotic depth (r ² = 0.67, P < 0.01), which varied with nutrient status of the lakes. While seasonal thermal density stratification is a prerequisite for the existence of a deep chlorophyll maximum (DCM), our study provides evidence that the depth of light penetration largely dictates the DCM depth during stratification. Reduction in water clarity through eutrophication can cause a shift in phytoplankton distributions from a DCM in spring or summer to a surface chlorophyll maximum within the surface mixed layer when the depth of the euphotic zone (z _eu) is consistently shallower than the depth of the surface mixed layer (z _SML). Trophic status has a key role in determining vertical distributions of chlorophyll in the four lakes, but does not appear to disrupt the annual cycle of maximum chlorophyll in winter.     

Managing Ontong Java: Social institutions for production and governance of atoll resources in Solomon Islands

This paper explores the changing nature of social institutions and organizations for resource management on Ontong Java and their central role in maintaining livelihoods. Using detailed field data for three time periods, 1970–72, 1986 and 2006–07, and drawing on earlier secondary data, a longitudinal analysis of changes in governance and livelihoods is undertaken. Increased exploitation of marine resources has widened the resource base and increased people's access to goods and services. Following the ban in 2005 on the bêche-de-mer trade, however, livelihoods have reverted to being more subsistence oriented. For almost two decades after 1978, a communal organization, the Area Council, succeeded in regulating exploitation of the atoll's marine resources to ensure sustainable use, but in the 1990s it collapsed. In addition there was a paralysis of institutions that had once settled land disputes. This failure of atoll governance is a greater threat to future 'sustainability' than the usual processes that are invoked for atolls and small islands generally. As the Solomon Islands state is also failing, we argue that local institutions and organizations have a vital role to play in managing access to resources and the future of livelihoods on Ontong Java atoll.     

Intramolecular carbon isotopic analysis of acetic acid by direct injection of aqueous solution

We report an improved method for determining the intramolecular carbon isotopic composition of acetate using direct injection of aqueous samples. The system builds upon prior work that established pyrolytic conditions for online analysis and represents a significant advance in that it requires minimal preparation for samples containing as little as 1 mM sodium acetate in aqueous solution. The technique is applicable for analysis of oilfield brines, culture samples, biological samples and natural porewaters. We demonstrate its accuracy by use of a stable isotope dilution series. We also show that addition of a base and cryogenic preconcentration may induce an isotopic effect on the carboxyl carbon. This isotopic fractionation does not appear to extend to the measured methyl carbon isotope value although it can significantly alter the measured isotopic composition of the whole molecule. Our preconcentration experiments demonstrate that the method is suitable for carbon isotopic measurements of acetate methyl carbon in natural samples at concentrations as low as 90 μM, considerably broadening potential applications.