Climate or development: is ODA diverted from its original purpose?

We analyze the interaction of climate and development policy that has taken place since the early 1990s. Increasing dissatisfaction about the results of traditional development cooperation and the appeal of climate policy as a new policy field led to a rapid reorientation of aid flows. At the turn of the century, over 7% of aid flows were spent on greenhouse gas emissions mitigation. However, the contribution of emissions mitigation projects to the central development objective of poverty reduction as specified in the Millennium Development Goals is limited and other project types are likely to be much more effective. Adaptation to climate change can be expected to have higher synergies with poverty alleviation than mitigation, primarily through its impact on health, the conservation of arable land and the protection against natural disasters. An analysis of the Clean Development Mechanism shows that projects addressing the poor directly are very rare; even small renewable energy projects in rural areas tend to benefit rich farmers and the urban population. Use of development aid for CDM projects and / or their preparation via capacity building is thus clearly not warranted. We further analyze whether the use of development aid for climate policy could be justified as a countermeasure against the emission increase related to successful development itself. However, countries that are achieving an improvement of human development from a low level are unlikely to increase their energy consumption substantially. Only at a level where the middle class expands rapidly, energy consumption and greenhouse gas emissions soar. Thus targeting middle class energy consumption by appliance efficiency standards and public transport-friendly urban planning are the most effective measures to address developing country emissions. Rural renewable energy provision in poor countries has a much higher impact on poverty, but a much lower impact on greenhouse gas emissions. We conclude that while there are valid reasons for long-term collaboration with emerging economies on greenhouse gas mitigation, there should be a separate budget line for such activities to avoid “obfuscation” of a decline of resources aimed at poverty alleviation. Nevertheless, mitigation will remain attractive for donors because it ensures quick disbursements and relatively simple measures of success. Moreover, mitigation activities in developing countries provide politicians in industrialized countries with a welcome strategy to divert the attention of their constituencies from the lack of success in reducing greenhouse gas emissions domestically.     

Magnetic signature of hydrocarbon-contaminated soils and sediments at the former oil field H?nigsen, Germany

Magnetic properties of hydrocarbon (HC) containing soils and sediments from two sites (Site A and B) of the former oil-field H?nigsen were analyzed in order to determine whether magnetic methods can be employed to delineate HC contamination of soils and sediments. Magnetic parameters such as magnetic susceptibility and induced isothermal remanent magnetizations, as well as soil and sediment properties such as pH, iron content and water content, HC content and most probable number counts of iron-metabolizing microorganisms were determined. The magnetic concentration-dependent parameters for HC contaminated samples were 25 times higher in soils from Site A than in sediment samples from Site B. However, at Site B the magnetic susceptibility was still four times higher in comparison to lithologically similar non-contaminated sediment samples from a third Site C. Newly formed magnetite containing mainly single domain particles was responsible for the magnetic enhancement, whereas superparamagnetic grains represented only a minor component. Site A had an acidic pH compared to neutral pH at Site B, and a higher crystalline and bioavailable total iron content. Nevertheless, Site B samples contained significant numbers of both iron(II)-oxidizing and iron(III)-reducing microorganisms indicating that microbial iron cycling might have taken place at this site and potentially played a role for iron mineral transformation, including magnetite (trans)formation. The content of total non-polar hydrocarbons (TNPH) at Site A was one order of magnitude higher than at Site B. Only at Site A magnetic susceptibility correlated well with TNPH. Our results demonstrate that HC contaminated samples had an enhanced magnetite content compared to non-contaminated soils and sediments. Therefore, magnetic methods may provide a quick and cost-effective way to assess HC contamination in soils and sediments. However, more field sites and laboratory investigations are needed to reveal the complex nature of the processes involved.     

Atmospheric Chemistry in Giant Planets, Brown Dwarfs, and Low-Mass Dwarf Stars: I. Carbon, Nitrogen, and Oxygen

The chemical species containing carbon, nitrogen, and oxygen in atmospheres of giant planets, brown dwarfs (T and L dwarfs), and low-mass stars (M dwarfs) are identified as part of a comprehensive set of thermochemical equilibrium and kinetic calculations for all elements. The calculations cover a wide temperature and pressure range in the upper portions of giant planetary and T-, L-, and M-dwarf atmospheres. Emphasis is placed on the major gases CH₄, CO, NH₃, N₂, and H₂O but other less abundant gases are included. The results presented are independent of particular model atmospheres, and can be used to constrain model atmosphere temperatures and pressures from observations of different gases. The influence of metallicity on the speciation of these key elements under pressure-temperature (P-T) conditions relevant to low-mass object atmospheres is discussed. The results of the thermochemical equilibrium computations indicate that several compounds may be useful to establish temperature or pressure scales for giant planet, brown dwarf, or dwarf star atmospheres. We find that ethane and methanol abundance are useful temperature probes in giant planets and methane dwarfs such as Gl 229B, and that CO₂ can serve as a temperature probe in more massive objects. Imidogen (NH) abundances are a unique pressure-independent temperature probe for all objects. Total pressure probes for warmer brown dwarfs and M dwarfs are HCN, HCNO, and CH₂O. No temperature-independent probes for the total pressure in giant planets or T-dwarf atmospheres are identified among the more abundant C, N, and O bearing gases investigated here.     

Formation of the Wiesloch Mississippi Valley-type Zn-Pb-Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany

The Mississippi Valley-type (MVT) Zn–Pb–Ag deposit in the Wiesloch area, Southwest Germany, is controlled by graben-related faults of the Upper Rhinegraben. Mineralization occurs as vein fillings and irregular replacement ore bodies consisting of sphalerite, banded sphalerite, galena, pyrite, sulfosalts (jordanite and geocronite), barite, and calcite in the Middle Triassic carbonate host rock. Combining paragenetic information, fluid inclusion investigations, stable isotope and mineral chemistry with thermodynamic modeling, we have derived a model for the formation of the Wiesloch deposit. This model involves fluid mixing between ascending hot brines (originating in the crystalline basement) with sedimentary formation waters. The ascending brines originally had a near-neutral pH (around 6) and intermediate oxidation state, reflecting equilibrium with granites and gneisses in the basement. During fluid ascent and cooling, the pH of the brine shifted towards more acidic (around 4) and the oxidation state increased to conditions above the hematite-magnetite buffer. These chemical characteristics contrast strongly with those of the pore and fracture fluid residing in the limestone aquifer, which had a pH between 8 and 9 in equilibrium with calcite and was rather reduced due to the presence of organic matter in the limestone. Mixing between these two fluids resulted in a strong decrease in the solubility of silver-bearing sphalerite and galena, and calcite. Besides Wiesloch, several Pb–Zn deposits are known along the Upper Rhinegraben, including hydrothermal vein-type deposits like Badenweiler and the Michael mine near Lahr. They all share the same fluid origin and formation process and only differ in details of their host rock and fluid cooling paths. The mechanism of fluid mixing also seems to be responsible for the formation of other MVT deposits in Europe (e.g., Réocin, Northern Spain; Trèves, Southern France; and Cracow-Silesia, Poland), which show notable similarities in terms of their age, mineralogy. and mineral chemistry to the MVT deposit near Wiesloch.     

Effects of the herbicide diuron on the early life history stages of coral

The effects of the herbicide diuron on the early life history stages of broadcast spawning and brooding corals were examined in laboratory experiments. Fertilisation of Acropora millepora and Montipora aequituberculata oocytes were not inhibited at diuron concentrations of up to 1000 microg l(-1). Metamorphosis of symbiont-free A. millepora larvae was only significantly inhibited at 300 microg l(-1) diuron. Pocillopora damicornis larvae, which contain symbiotic dinoflagellates, were able to undergo metamorphosis after 24 h exposure to diuron at 1000 microg l(-1). Two-week old P. damicornis recruits on the other hand were as susceptible to diuron as adult colonies, with expulsion of symbiotic dinoflagellates (bleaching) evident at 10 microg l(-1) diuron after 96 h exposure. Reversible metamorphosis was observed at high diuron concentrations, with fully bleached polyps escaping from their skeletons. Pulse amplitude modulation (PAM) chlorophyll fluorescence techniques demonstrated a reduction in photosynthetic efficiency (Delta F/F(m)') in illuminated P. damicornis recruits after a 2 h exposure to 1 microg l(-1) diuron. The dark-adapted quantum yields (F(v)/F(m)) also declined, indicating chronic photoinhibition and damage to photosystem II.     

Pyritization processes and greigite formation in the advancing sulfidization front in the upper Pleistocene sediments of the Black Sea

Pyritization in late Pleistocene sediments of the Black Sea is driven by sulfide formed during anaerobic methane oxidation. A sulfidization front is formed by the opposing gradients of sulfide and dissolved iron. The sulfidization processes are controlled by the diffusion flux of sulfide from above and by the solid reactive iron content. Two processes of diffusion-limited pyrite formation were identified. The first process includes pyrite precipitation with the accumulation of iron sulfide precursors with the average chemical composition of FeS_n (n = 1.10-1.29), including greigite. Elemental sulfur and polysulfides, formed from H₂S by a reductive dissolution of Fe(III)-containing minerals, serve as intermediates to convert iron sulfides into pyrite. In the second process, a “direct” pyrite precipitation occurs through prolonged exposure of iron-containing minerals to dissolved sulfide. Methane-driven sulfate reduction at depth causes a progressive formation of pyrite with a δ³⁴S of up to +15.0‰. The S-isotopic composition of FeS₂ evolves due to contributions of different sulfur pools formed at different times. Steady-state model calculations for the advancement of the sulfidization front showed that the process started at the Pleistocene/Holocene transition between 6360 and 11 600 yr BP. Our study highlights the importance of anaerobic methane oxidation in generating and maintaining S-enriched layers in marine sediments and has paleoenvironmental implications.     

A meteorological study of Dry-fallout of radioactive debris

Summary A general expression is derived for the intensity of dryfallout based on time variations of beta-activity in surface air, due to worldwide tropospheric distribution of debris from nuclear testings. Model assumptions are outlined for the consideration of large-scale effects of horizontal divergence of air flow, and small-scale effects of eddy diffusion. The parameterization is based on the concept of geostrophic drag coefficients and atmospheric boundary layer theory. The model is completed by a two-parameter representation of tropospheric profiles of beta activity. Case studies of dry-fallout in 1962 and 1963 at three stations of the United States Public Health Service (USPHS) network are discussed. Dry-fallout rates per day are found to be approximately 10% of average wet-fallout rates of the same period. The average residence time of debris in the troposphere is estimated to be about 65 days if dry-fallout would be the only cleansing process.

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Zusammenfassung Für die Intensität von radioaktivem Ausfall wird eine allgemeine Formel abgeleitet. Sie beruht auf der beobachteten zeitlichen Veränderung der bodennahen Konzentration radioaktiver Beta-Teilchen, die als Abfallprodukte der Kernwaffenversuche weltweite Verteilung erfuhren. Das theoretische Modell zur Berechnung von Trockenausfall erfordert gewisse Annahmen zur Berücksichtigung von 1. großräumigen Effekten der horizontalen Divergenz der Luftströmung und 2. kleinräumigen Turbulenzeinflüssen. Diese Effekte werden durch Parameter der horizontalen Luftdruckverteilung berücksichtigt, die auf dem Konzept des geostrophischen Widerstandsbeiwertes und der atmosphärischen Grenzschichttheorie beruhen. Das Modell ist durch zwei weitere Parameter vervollständigt, welche das troposphärische Profil der Beta-Aktivität repräsentieren. Beispiele von Trockenausfall in den Jahren 1962 und 1963 werden für drei Stationen des Beobachtungsnetzes des United States Public Health Service diskutiert. Es ergab sich, daß Trockenausfall pro Tag etwa 10% des Ausfalles durch Niederschlag (pro Regentag) für den gleichen Zeitabschnitt ausmacht. Ferner wird abgeschätzt, daß die Verweilzeit der radioaktiven Teilchen in der Troposphäre im Durchschnitt 65 Tage beträgt, wenn Trockenausfall der alleinige Reinigungsprozeß ist.

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Résumé On développe ici une formule générale permettant le calcul de l'intensité des retombées radio-actives. Cette formule est fondée sur la variation de la concentration au voisinage du sol des particules radio-actives béta, disséminées dans l'atmosphère entière à la suite d'essais d'armes nucléaires. Le modèle théorique permettant de représenter la sédimentation en atmosphère sèche nécessite certaines suppositions afin de tenir compte d'une part des effets à grandes dimensions de la divergence horizontale des courants aériens et d'autre part des effets de la turbulence à petites dimensions. On tient compte de ces effets au moyen de paramètres de la répartition horizontale de la pression, paramètres basés sur le coefficient de la résistance géostrophique et sur la théorie des couches limites atmosphériques. Ce modèle est complété par deux paramètres supplémentaires qui représentent le profil troposphérique de l'activité béta. Comme exemple, on discute les quantités de retombées recueillies à trois stations du «United States Public Health Service» durant les années 1962 et 1963. Le résultat en est que la sédimentation à sec par jour représente environ le 10% des retombées entraînées par les précipitations durant la même période. On estime en outre que les particules se maintiennent en moyenne durant 65 jours dans la troposphère si la sédimentation se fait uniquement sans le concours de précipitations.

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The research reported was supported, in part, by the National Science Foundation, Grant No. GP-444.     

First health and pollution study on harbor seals (Phoca vitulina) living in the German Elbe estuary

The Elbe is one of the major rivers releasing pollutants into the coastal areas of the German North Sea. Its estuary represents the habitat of a small population of harbor seals (Phoca vitulina). Only little is known about the health status and contamination levels of these seals. Therefore, a first-ever seal catch was organized next to the islands of Neuwerk and Scharhörn in the region of the Hamburg Wadden Sea National Park. The investigations included a broad set of health parameters and the analysis of metals and organic pollutants in blood samples. Compared to animals of other Wadden Sea areas, the seals showed higher γ-globulin levels, suggesting higher concentrations of pathogens in this near-urban area, elevated concentrations for several metals in particular for V, Sn, Pb, and Sr, and comparable ranges for chlorinated organic contaminants, except for elevated levels of hexachlorobenzene, which indicates characteristic inputs from the Elbe.