An observational aircraft-based study of sea-breeze frontogenesis

In the summer of 1988/89 flights were carried out in the Coorong coastal area of South Australia to investigate sea-breeze fronts. The flights yielded data sets of the structure of the fronts in the cross-frontal direction with a spatial resolution of approximately 3 m. The study is focused on the budgets of sensible and latent heat in the vicinity of the front and on frontogenesis/frontolysis processes which are closely related to budget considerations.The frontogenesis relationships and the budgets were established on a 2 km length scale by low-pass filtering of the space series. As the wind components were measured with high accuracy, all processes which determine frontogenesis could be evaluated and are displayed in x,z-cross-sections: these are the confluence, shear and diabatic effects, all of which play a role in q/x-, q/z-, /x- as well as /z-frontogenesis. A detailed analysis is given for two different states of frontal development. The presented results shed much light on the governing physical processes in the frontal region with strong emphasis on the effects of confluence-generated updrafts, on shear instabilities causing bulges and clefts in the frontal surface as well as producing the elevated frontal head, and on processes related to differential heating and moistening.     

A parameterisation for the threshold shear velocity to initiate deflation of dry and wet sediment

A new parameterisation for the threshold shear velocity to initiate deflation of dry and wet particles is presented. It is based on the balance of moments acting on particles at the instant of particle motion. The model hence includes a term for the aerodynamic forces, including the drag force, the lift force and the aerodynamic-moment force, and a term for the interparticle forces. The effect of gravitation is incorporated in both terms. Rather than using an implicit function for the effect of the aerodynamic forces as reported earlier in literature, a constant aerodynamic coefficient was introduced. From consideration of the van der Waals force between two particles, it was further shown that the effect of the interparticle cohesion force between two dry particles on the deflation threshold should be inversely proportional to the particle diameter squared. The interparticle force was further extended to include wet bonding forces. The latter were considered as the sum of capillary forces and adhesive forces. A model that expresses the capillary force as a function of particle diameter squared and the inverse of capillary potential was deduced from consideration of the well-known model of Fisher and the Young–Laplace equation. The adhesive force was assumed to be equal to tensile strength, and a function which is proportional to particle diameter squared and the inverse of the potential due to adhesive forces was derived. By combining the capillary-force model and the adhesive force model, the interparticle force due to wet bonding was simplified and written as a function of particle diameter squared and the inverse of matric potential. The latter was loglinearly related to the gravimetric moisture content, a relationship that is valid in the low-moisture content range that is important in the light of deflation of sediment by wind. By introducing a correction to force the relationship to converge to zero moisture content at oven dryness, the matric potential–moisture content relationship contained only one unknown model parameter, viz. moisture content at −1.5 MPa. Working out the model led to a rather simple parameterisation containing only three coefficients. Two parameters were incorporated in the term that applies to dry sediment and were determined by using experimental data as reported by Iversen and White [Sedimentology 29 (1982) 111]. The third parameter for the wet-sediment part of the model was determined from wind-tunnel experiments on prewetted sand and sandy loam aggregates. The model was validated using data from wind-tunnel experiments on the same but dry sediment, and on data obtained from simulations with the model of Chepil [Soil Sci. Soc. Am. Proc. 20 (1956) 288]. The experiments showed that soil aggregates should be treated as individual particles with a density equal to their bulk density. Furthermore, it was shown that the surface had to dry to a moisture content of about 75% of the moisture content at −1.5 MPa before deflation became sustained. The threshold shear velocities simulated with our model were found to be in good agreement with own observations and with simulations using Chepil's model.     

Chemistry of the heavily urbanized Bagmati River system in Kathmandu Valley, Nepal: export of organic matter, nutrients, major ions, silica, and metals

Water quality in less-developed countries is often subject to substantial degradation, but is rarely studied in a systematic way. The concentration and flux of major ions, carbon, nitrogen, silicon, and trace metals in the heavily urbanized Bagmati River within Kathmandu Valley, Nepal, are reported. The concentrations of all chemical species increased with distance downstream with the exceptions of protons and nitrate, and showed strong relationships with population density adjacent to the river. Total dissolved nitrogen (TDN), dominated by NH₄, was found in high concentrations along the Bagmati drainage system. The export of dissolved organic carbon (DOC) and TDN were 23 and 33 tons km^?2 year^?1, respectively, at the outlet point of the Kathmandu Valley, much higher than in relatively undeveloped watersheds. The cationic and silica fluxes were 106 and 18 tons km^?2 year^?1 at the outlet of the Bagmati within Kathmandu Valley, and 36 and 32 tons km^?2 year^?1 from the relatively pristine headwater area. The difference between headwaters and the urban site suggests that the apparent weathering flux is three times higher than the actual weathering rate in the heavily urbanized Bagmati basin. Fluxes of cations and silica are above the world average, as well as fluxes from densely populated North American and European watersheds. End-member composition of anthropogenic sources like sewage or agricultural runoff is needed to understand the drivers of this high rate of apparent weathering.     

Chemistry of chromium spinel in high-Mg rocks from the Morungava Intrusion,Cretaceous Paraná Igneous Province,southernmost Brazil

Mineralogy and Petrology - Mafic-ultramafic intrusions within continental flood basalt terrains are frequently associated with Cu-Ni-PGE mineralization. This study aims to constrain the...     

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

Sulfur in presolar silicon carbide grains from asymptotic giant branch stars

We studied 14 presolar SiC mainstream grains for C‐, Si‐, and S‐isotopic compositions and S elemental abundances. Ten grains have low levels of S contamination and CI chondrite‐normalized S/Si ratios between 2 × 10^?5 and 2 × 10^?4. All grains have S‐isotopic compositions compatible within 2σ of solar values. Their mean S isotope composition deviates from solar by at most a few percent, and is consistent with values observed for the carbon star IRC+10216, believed to be a representative source star of the grains, and the interstellar medium. The isotopic data are also consistent with stellar model predictions of low‐mass asymptotic giant branch (AGB) stars. In a δ³³S versus δ³⁴S plot the data fit along a line with a slope of 1.8 ± 0.7, suggesting imprints from galactic chemical evolution. The observed S abundances are lower than expected from equilibrium condensation of CaS in solid solution with SiC under pressure and temperature conditions inferred from the abundances of more refractory elements in SiC. Calcium to S abundance ratios are generally above unity, contrary to expectations for stoichiometric CaS solution in the grains, possibly due to condensation of CaC₂ into SiC. We observed a correlation between Mg and S abundances suggesting solid solution of MgS in SiC. The low abundances of S in mainstream grains support the view that the significantly higher abundances of excess ³²S found in some Type AB SiC grains are the result of in situ decay of radioactive ³²Si from born‐again AGB stars that condensed into AB grains.     

Effect of leaf litter degradation and seasonality on D/H isotope ratios of n-alkane biomarkers

During the last decade, compound-specific hydrogen isotope analysis of plant leaf-wax and sedimentary n-alkyl lipids has become a promising tool for paleohydrological reconstructions. However, with the exception of several previous studies, there is a lack of knowledge regarding possible effects of early diagenesis on the δD values of n-alkanes. We therefore investigated the n-alkane patterns and δD values of long-chain n-alkanes from three different C3 higher plant species (Acer pseudoplatanus L., Fagus sylvatica L. and Sorbus aucuparia L.) that have been degraded in a field leaf litterbag experiment for 27 months.We found that after an initial increase of long-chain n-alkane masses (up to ∼50%), decomposition took place with mean turnover times of 11.7 months. Intermittently, the masses of mid-chain n-alkanes increased significantly during periods of highest total mass losses. Furthermore, initially high odd-over-even predominances (OEP) declined and long-chain n-alkane ratios like n-C₃₁/C₂₇ and n-C₃₁/C₂₉ started to converge to the value of 1. While bulk leaf litter became systematically D-enriched especially during summer seasons (by ∼8‰ on average over 27 months), the δD values of long-chain n-alkanes reveal no systematic overall shifts, but seasonal variations of up to 25‰ (Fagus, n-C₂₇, average ∼13‰).Although a partly contribution by leaf-wax n-alkanes by throughfall cannot be excluded, these findings suggest that a microbial n-alkane pool sensitive to seasonal variations of soil water δD rapidly builds up. We propose a conceptual model based on an isotope mass balance calculation that accounts for the decomposition of plant-derived n-alkanes and the build-up of microbial n-alkanes. Model results are in good agreement with measured n-alkane δD results. Since microbial ‘contamination’ is not necessarily discernible from n-alkane concentration patterns alone, care may have to be taken not to over-interpret δD values of sedimentary n-alkanes. Furthermore, since leaf-water is generally D-enriched compared to soil and lake waters, soil and water microbial n-alkane pools may help explain why soil and sediment n-alkanes are D-depleted compared to leaves.     

Turbulence in Class 0 and I protostellar envelopes

We estimate the levels of turbulence in the envelopes of class 0 and I protostars using a model based on measurements of the peak separation of double-peaked asymmetric line profiles. We use observations of 20 protostars of both class 0 and I taken in the  HCO⁺(J = 3 → 2)  line that show the classic double-peaked profile. We find that some class 0 sources show high levels of turbulence, whilst others demonstrate much lower levels. In class I protostars, we find predominantly low levels of turbulence. The observations are consistent with a scenario in which class 0 protostars form in a variety of environments and subsequently evolve into class I protostars. The data do not appear to be consistent with a recently proposed scenario in which class 0 protostars can only form in extreme environments.     

The most frequent interfaces in olivine aggregates: the GBCD and its importance for grain boundary related processes

Rocks consist of crystal grains separated by grain boundaries that impact the bulk rock properties. Recent studies on metals and ceramics showed that the grain boundary plane orientation is more significant for grain boundary properties than other characteristics such as the sigma value or disorientation (in the Earth’s science community more frequently termed misorientation). We determined the grain boundary character distribution (GBCD) of synthetic and natural polycrystalline olivine, the most abundant mineral of Earth’s upper mantle. We show that grain boundaries of olivine preferentially contain low index planes, in agreement with recent findings on other oxides (e.g. MgO, TiO₂, Al₂O₃ etc.). Furthermore, we find evidence for a preferred orientation relationship of 90° disorientations about the [001] direction forming tilt and twist grain boundaries, as well as a preference for the 60° disorientation about the [100] axis. Our data indicate that the GBCD, which is an intrinsic property of any mineral aggregate, is fundamental for understanding and predicting grain boundary related processes.