The vulnerability of karst springs—a case study of the Hubelj spring (SW Slovenia)

The hydraulic behaviour of the karst aquifer in the Hubelj spring catchment area (SW Slovenia) was studied by using an indirect research method based on natural tracers. The variations of natural tracers (in precipitation and in groundwater) during the storm event made possible the separation of the Hubelj spring storm hydrograph by the three-component separation technique. The results produced information on the aquifer recharge, storage and discharge processes, as well as on the mechanisms that affected them. They verified the so-called epikarst hypothesis presuming that an important part of a karst aquifer recharge reaches rapidly and intensively from the epikarst zone. It was demonstrated that epikarst water could occupy up to 50% of the spring discharge during precipitation events. This phenomenon could have important consequences on protection and management of the problems of karst aquifers, including engineering problems in karst areas. With this respect the results could give way to new engineering ideas.     

P–T evolution and reaction textures in retrogressed eclogites from Svetlik, the Moldanubian Zone (Czech Republic)

Summary Lenses and pods of mafic rocks from the Monotonous Unit near Svetlik are characterized by eclogite facies mineral assemblages; however some inclusion patterns (oriented quartz rods in clinopyroxene and cuboids of disordered graphite in garnet) that are usually known from ultra-high pressure rocks were also observed in one sample. Conventional thermobarometry yielded maximum P–T conditions of 2.0–2.5 GPa and 750 °C. Decompression and heating at amphibolite and granulite facies conditions resulted in the formation of at least five distinct types of symplectites. These include symplectitic intergrowth of ilmenite and clinopyroxene after titanite, described here for the first time from the Moldanubian Zone. In addition, symplectites of plagioclase and biotite with accessory amounts of spinel after tabular pseudomorphs (after phengite?) are also reported here. Mass balance relations indicate that symplectites of diopside + plagioclase after omphacite and plagioclase + spinel (sapphirine) after kyanite + garnet, formed by nearly isochemical reactions. All other symplectite-forming reactions were allochemical and were accelerated by the presence of fluid in the primary phases. Preserved zoning pattern in garnet with high compositional gradient in some samples suggests that the rocks were affected briefly by granulite facies overprint.     

Reconstructing hydrological variability from testate amoebae analysis in Carpathian peatlands

Peatlands offer the potential for high resolution records of water balance over Holocene timescales, yet this potential is under-exploited in many areas of the world. Within Europe, peatlands are mostly confined to areas north of 55° N, but several areas of southern and eastern Europe contain small peatlands which may be suitable for palaeoclimatic reconstruction. In this paper we test the potential of peatlands in the Carpathian region for deriving quantified estimates of water table changes using testate amoebae analysis. A training set for palaeohydrological reconstruction from testate amoebae assemblages was obtained by collecting surface samples from 13 peatlands, including 9 from Hungary and 4 from Transylvania (Romania). Using a simple measure of mean annual water tables estimated from staining of PVC tape, we found that some peatlands were heavily influenced by runoff and groundwater, and were therefore not suitable as modern analogues of ombrotrophic climatically sensitive sites. The relationship between the testate amoebae assemblages in the modern samples and the environmental variables was explored using CCA. The CCA biplot showed that the most important variables are depth to water table and moisture content, confirming that hydrology is a key control on taxon distribution. pH was a secondary gradient. A transfer function for % moisture and depth to water table was established and applied to fossil assemblages from a sequence from Fenyves-tető, Transylvania, Romania. The reconstructed water table shows a number of variations which have parallels with other palaeoclimatic records from Europe and the North Atlantic prominent phases of higher water tables are associated with the periods 8000–8300 cal BP, 3000–2500 cal BP and after 600 cal BP. We suggest that these were periods of particular intensification of westerly airflow which affected eastern Europe as well as western and central Europe.     

The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.     

Environmental and health risk assessment in abandoned mining area, Zlata Idka, Slovakia

The Zlata Idka village is a typical mountainous settlement. As a consequence of more than 500 years of mining activity, its environment has been extensively affected by pollution from potentially toxic elements. This paper presents the results of an environmental-geochemical and health research in the Zlata Idka village, Slovakia. Geochemical analysis indicates that arsenic (As) and antimony (Sb) are enriched in soils, groundwater, surface water and stream sediments. The average As and Sb contents are 892 mg/kg and 818 mg/kg in soils, 195 mg/kg and 249 mg/kg in stream sediments, 0.028 mg/l and 0.021 mg/l in groundwater and 0.024 mg/l and 0.034 mg/l in surface water. Arsenic and Sb concentrations exceed upper permissible limits in locally grown vegetables. Within the epidemiological research the As and Sb contents in human tissues and fluids have been observed (blood, urine, nails and hair) in approximately one third of the village’s population (120 respondents). The average As and Sb concentrations were 16.3 μg/l and 3.8 μg/l in blood, 15.8 μg/l and 18.8 μg/l in urine, 3,179 μg/kg and 1,140 μg/kg in nails and 379 μg/kg and 357 μg/kg in hair. These concentrations are comparatively much higher than the average population. Health risk calculations for the ingestion of soil, water, and vegetables indicates a very high carcinogenic risk (>1/1,000) for as content in soil and water. The hazard quotient [HQ=average daily dose (ADD)/reference dose (RfD)] calculation method indicates a HQ>1 for groundwater As and Sb concentrations.     

Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.     

Avalanche Risk During Backcountry Skiing – An Analysis of Risk Factors

Skier-triggered avalanches are the main cause of avalanche accidents in backcountry skiing. The risk of accidents during backcountry skiing was analysed statistically and related to factors such as elevation level, aspect, stability rating and the time of the year. The analysis is based on a database about terrain usage and avalanche accidents from a large heli-skiing operator in Canada, which makes it possible to study the conditional probability of accidents given the recorded pattern of terrain usage. This study shows that the historical risk of accidentally triggering an avalanche greater than size 1 depends highly on the stability rating, with the highest risk occurring during “poor” stability. The risk is greater at high elevations, and it is lower during the late season than earlier on. Skier risk does not depend as much on aspect as may be indicated from avalanche data alone. However, it is relatively high in the N–NE–E sector. These factors are not independent of each other and therefore analyses of combined factors were also performed. Questionnaires and interviews were used to gain knowledge about the terrain selection of professional mountain guides. These results indicate that when selecting terrain, guides first look at the overall shape and size of the terrain, but avalanche history of terrain and inclination are also important factors. Finally, remarks in avalanche reports were analysed, and common human factors identified.     

Effect of sampling and linkage on fault length and length–displacement relationship

The power-law exponent (n) in the equation: D=cL ⁿ , with D = maximum displacement and L = fault length, would be affected by deviations of fault trace length. (1) Assuming n=1, numerical simulations on the effect of sampling and linkage on fault length and length–displacement relationship are done in this paper. The results show that: (a) uniform relative deviations, which means all faults within a dataset have the same relative deviation, do not affect the value of n; (b) deviations of the fault length due to unresolved fault tip decrease the values of n and the deviations of n increase with the increasing length deviations; (c) fault linkage and observed dimensions either increase or decrease the value of n depending on the distribution of deviations within a dataset; (d) mixed deviations of the fault lengths are either negative or positive and cause the values of n to either decrease or increase; (e) a dataset combined from two or more datasets with different values of c and orders of magnitude also cause the values of n to deviate. (2) Data including 19 datasets and spanning more than eight orders of fault length magnitudes (10⁻²–10⁵ m) collected from the published literature indicate that the values of n range from 0.55 to 1.5, the average value being 1.0813, and the peak value of n _d (double regression) is 1.0–1.1. Based on above results from the simulations and published data, we propose that the relationship between the maximum displacement and fault length in a single tectonic environment with uniform mechanical properties is linear, and the value of n deviated from 1 is mainly caused by the sampling and linkage effects.     

Geometry and accuracy of reflecting points in bistatic satellite altimetry

The analysis of the time and space distribution of specular (reflecting) points in bistatic altimetry between GPS and CHAMP satellites or SAC-C (taken as examples) is extended from Wagner and Klokočník (2003 J. Geod 77: 128–138). We demonstrate a significantly higher number and density of reflecting points in bistatic altimetry in comparison with traditional monostatic altimetry. After an outline of our older accuracy assessment for the vertical position of the reflecting point, we add a new independent derivation and compare both approaches. We account for orbit errors of both the transmitters (GPS) and receiver (CHAMP) satellites, and the measurement (delay) error. We found that the accuracy of the vertical position of the reflecting point decreases only slowly with increasing off-nadir angle and that the orbit errors must be accounted for if decimeter and better accuracy is required. In this paper, we do not study errors such as state of the ocean, technical parameters of the receiving system, and atmospheric corrections.     

Daily Meteorological Observations in Cádiz – San Fernando. Analysis of the Documentary Sources and the Instrumental Data Content (1786–1996)

Meteorological observations in the city of Cádiz are acknowledged as having been made from the middle of the 18th century onwards although they were only recorded and preserved in documentary form from 1789 onwards. Data readings were taken at the new Naval Observatory in San Fernando, ten kilometres from Cádiz, from 1797 onwards. Continuous series for temperature and atmospheric pressure at a daily resolution have been compiled and constructed from 1817 until 1996. The data series is composed of thrice daily observations made at Cádiz (1821–1880) by local observers and hourly data from Naval Observatory at San Fernando (1870–1996).