Investigating hydrological drivers of nitrate export dynamics in two agricultural catchments in Germany using high-frequency data series

In this study near-continuous time series of nitrate, electrical conductivity, and discharge were used to identify the dominating hydrological mechanisms that control nitrate export dynamics in two agricultural catchments. The main goal was to assess relationships between contrasting event based as well as long-term nitrate transport behaviour and catchment hydrology. Data records were obtained from online probes that allow field based high-frequency analyses over long time periods. The catchments of the Ammer River (southwestern Germany) and the Weida River (eastern Germany) are similar with respect to size (~100 km²), morphology, and climate and are dominated by agricultural use. Main differences are the stronger urbanization and the occurrence of karstic rocks in the Ammer catchment. Nitrate concentrations are high in water of both streams and range mostly between 20 and 50 mg l^?1. Nitrate export in the Ammer catchment is dominated by baseflow and a minor second, diluting runoff component generated in urbanized areas. In contrast, nitrate dynamics of the Weida catchment is governed by the interplay of at least three runoff components, while the largest amount of nitrate is mobilized intermittently by a delayed fast component generated in the catchment’s soils during wet conditions. These interpretations, derived with one online probe at the outlet of each catchment, are well in line with the former modeling results. This study shows that high-resolution data obtained by online techniques offers a large potential to improve the conceptualization of dominating flow and transport processes at catchment scales at relatively low costs and effort.     

Multiple ways of producing intermediate and silicic rocks within Thingmúli and other Icelandic volcanoes

Major and trace element compositions of rocks and coexisting phenocrysts of the Thingmúli volcano suggest a revision of the existing models for the formation of intermediate and silicic melts in Iceland. The new data define two compositional tholeiitic trends with a significant gap between them. A high-iron trend (HFe) contains 6–14 wt% total FeO in silicic rocks with c. 1 wt% MgO, as well as sodic plagioclase and hedenbergite phenocrysts. A low-iron trend (LFe) contains 3–5 wt% FeO at c. 1 wt% MgO, which is typical of Iceland but higher than MORB compositions. The most evolved phenocrysts of the LFe trend do not reach iron-rich end members. The HFe trend is interpreted as a result of fractional crystallization; numerical modelling using the MELTS algorithm suggests that crystallization took place under redox conditions constrained to one-log unit below the fayalite-magnetite-quartz oxygen buffer (FMQ-1). The LFe trend is explained by a combination of mixing between rhyolite and ferrobasalt, assimilation of hydrated crust and fractional crystallization under higher redox conditions (FMQ). The two trends and the gap are best defined in a plot of Mg# versus SiO₂ that is useful to unravel petrogenetic processes. For example, intermediate and silicic rocks of the Holocene volcanic systems of spreading rifts (e.g. Krafla), propagating rifts (e.g. Hekla) and off-rifts (Öræfajökull) also fall into high- and low-iron fields and outline a gap similar to Thingmúli. The identification of two compositional trends in erupted intermediate and silicic volcanic products shows that processes in the deep roots of single volcanic systems are highly diverse and likely controlled by local variations in the thermal gradients and the extend of hydrothermal alteration. Generalizations about the relationship between the compositions of intermediate and silicic rocks and plate tectonic setting, therefore, should be avoided.     

The Agulhas Ridge, South Atlantic: The Peculiar Structure of a Fracture Zone

The Agulhas Ridge is a prominent topographic feature that parallels the Agulhas-Falkland Fracture Zone (AFFZ). Seismic reflection and wide angle/refraction data have led to the classification of this feature as a transverse ridge. Changes in spreading rate and direction associated with ridge jumps, combined with asymmetric spreading within the Agulhas Basin, modified the stress field across the fracture zone. Moreover, passing the Agulhas Ridge’s location between 80 and 69 Ma, the Bouvet and Shona Hotspots may have supplied excess material to this part of the AFFZ thus altering the ridge’s structure. The low crustal velocities and overthickened crust of the northern Agulhas Ridge segment indicate a possible continental affinity that suggests it may be formed by a small continental sliver, which was severed off the Maurice Ewing Bank during the opening of the South Atlantic. In early Oligocene times the Agulhas Ridge was tectono-magmatically reactivated, as documented by the presence of basement highs disturbing and disrupting the sedimentary column in the Cape Basin. We consider the Discovery Hotspot, which distributes plume material southwards across the AAFZ, as a source for the magmatic material.     

Late Holocene sea-level changes and isostasy in western Denmark

Cores and exposed cliff sections in salt marshes around Ho Bugt, a tidal embayment in the northernmost part of the Danish Wadden Sea, were subjected to ¹⁴C dating and litho- and biostratigraphical analyses to reconstruct paleoenvironmental changes and to establish a late Holocene relative sea-level history. Four stages in the late Holocene development of Ho Bugt can be identified: (1) groundwater-table rise and growth of basal peat (from at least 2300 BC to AD 0); (2) salt-marsh formation (0 to AD 250); (3) a freshening phase (AD 250 to AD 1600?), culminating in the drying out of the marshes and producing a distinct black horizon followed by an aeolian phase with sand deposition; and (4) renewed salt-marsh deposition (AD 1600? to present). From 16 calibrated AMS radiocarbon ages on fossil plant fragments and 4 calibrated conventional radiocarbon ages on peat, we reconstructed a local relative sea-level history that shows a steady sea-level rise of 4 m since 4000 cal yr BP. Contrary to suggestions made in the literature, the relative sea-level record of Ho Bugt does not contain a late Holocene highstand. Relative sea-level changes at Ho Bugt are controlled by glacio-isostatic subsidence and can be duplicated by a glacial isostatic adjustment model in which no water is added to the world's oceans after ca. 5000 cal yr BP.     

A scaled experiment for the verification of the SeaBed Logging method

SeaBed Logging (SBL) is an application of the marine controlled source electromagnetic (CSEM) method that is used to directly detect and characterize possible hydrocarbon-bearing prospects. Although the CSEM method has been used by academia for more than three decades, the application as a direct hydrocarbon indicator was first introduced about five years ago. The central idea of SBL is the guiding of electromagnetic energy in thin resistive layers within conductive sediments. Even if it has been well known for a long time that electromagnetic signals can propagate from a conductive region to another via resistive regions such as air or resistive parts of the lithosphere, the application to hydrocarbon exploration has not been developed until recently. This might be due to the uncertainty of getting any significant response from thin resistive layers such as hydrocarbon reservoirs since electromagnetic energy is highly attenuated in conductive sediments. Thus, during the early development phase of the SBL technique, a scaled laboratory experiment was performed to validate if a thin resistive layer (e.g. hydrocarbons) buried within conductive media (e.g. sediments) could be remotely detected by using electric dipoles as sources and receivers. Data from this experiment were compared to a forward modelling code for layered media, and the comparison showed good agreement between experimental and theoretical results. This suggested that thin resistive layers buried in conductive media are detectable due to the guiding of the electromagnetic field within the resistor. The successful results were vital for realizing the application of marine CSEM as a hydrocarbon exploration technique. We here present the results of the first scaled SBL experiment.     

Geology, magmatic affinity and geotectonic environment of some Caledonian ophiolites in Norway

Ophiolites within the Norwegian Caledonides were generated during at least two distinct periods, i.e. Tremadocian-Arenigian and Ashgillian. The older generation show a long-lived magmatic development (ca 500-470 Ma) with rocks that range from MORB, IAT, boninites, calc-alkaline to alkaline basalt in geochemical affinity. This development is compatible with generation in a subduction-influenced environment, and a plausible modern equivalent may be the ensimatic arc-basin evolution in the western Pacific.The metabasalts of the younger (Ashgill, 443±3 Ma) ophiolite occurrence are characterized by a dominance of N- to E-MORB compositions with subduction zone influence. The volvanics of the complex are intercalated with, and overlain by, continentally-derived sediments. Calc-alkaline as well as alkaline lavas and volcanic-lastics apparantly define late magmatic products. Associated with the youngest ophiolite is a sedimentary melange with olistoliths of mature island arc-derived volcanics, as well as clasts with MORB-IAT affinity, chert and sandstone, the latter probably derived from an accretionary prism. An Andaman Sea model appears most applicable to the youngest ophiolite/associated sediments assemblage.Contemporaneously with the renewed, Ashgillian spreading episode, widespread deposition of clastic sequences of Ashgillian age took place unconformably on the Lower Ordovician ophiolite complexes in fault controlled basins.     

On the variability of the Charnock constant and the functional dependence of the drag coefficient on wind speed: Part II-Observations

An analytical expression for the 10 m drag law in terms of the 10 m wind speed at the maximum in the 10 m drag coefficient, and the Charnock constant is presented, which is based on the results obtained from a model of the air-sea interface derived in Bye et al. (2010). This drag law is almost independent of wave age and over the mid-range of wind speeds (5?17 ms^?1) is very similar to the drag law based on observed data presented in Foreman and Emeis (2010). The linear fit of the observed data which incorporates a constant into the traditional definition of the drag coefficient is shown to arise to first-order as a consequence of the momentum exchange across the air-sea boundary layer brought about by wave generation and spray production which are explicitly represented in the theoretical model.