Contamination of tsunami sediments in a coastal zone inundated by the 26 December 2004 tsunami in Thailand

Tsunami sediments deposited in a coastal zone of Thailand by the 26 December 2004 tsunami wave were sampled within 50 days after the event. All surface and ground waters in tsunami- inundated zone revealed significant salinity at that time. The tsunami sediments, composed mainly of fine to medium sand, contain significantly elevated contents of salts (Na⁺, K⁺, Ca⁺², Mg⁺², Cl and SO ₄ ⁻² ) in water-soluble fraction, and of Cd, Cu, Zn, Pb in the bioavailable fraction and As in the exchangeable fraction in relation to the reference sample. The origin of contaminants is marine, as well as litho- and anthropogenic. The salts and Pb, Zn and Cu reveal high correlation to each other and to the mean grain size (pore size and porosity). Serious environmental hazard exists in that region because, due to gentle morphology, there is a risk of migration of the contaminants into ground waters and food chain.     

Garnets from diamond deposits in China and in the Arkhangelsk diamondiferous province

The morphology and chemical composition of garnets from principal deposits in China and in the Arkhangelsk Province consisting of kimberlites of various mineral types have been examined. The morphology of garnets (300 specimens) from the V. Grib pipe was examined, in which crystal fragments and irregular grains predominate, and dissolution traces are common. Distribution of types of garnet coloration is typical of kimberlites: lilac-violet and red garnets of ultramafic rock association are preponderant, and the proportion of yellow-orange garnets is rather high, while brown garnets are very rare. The garnet preservation degree is very low, which is related to their high primary fracturing due to cataclasis. Grains with finely matted surfaces are preponderant (90%) reflecting their high corrosion alterations. The chemical composition was determined in 56 garnet speciments from the Grib pipe. Garnets from lherzolitic and eclogitic rock types were found and garnets from magnesium and ilmenite ultramafics are present; there are no garnets from eclogites, but garnets from diamondiferous rock associations occur. The investigations demonstrated that garnets from lherzolite rock association are preponderant in kimberlites from China, as well as from other regions, while garnets from the harzburgite-dunite and from diamondiferous rock associations are rare. Garnets belonging to the graphitepyrope depth facies were also found.     

Use of the temperature–vegetation dryness index for remote sensing grassland moisture conditions in the vicinity of a lignite open-cast mine

Anthropogenic activities, especially resulting in changes in the water conditions, usually disturb biological and agricultural functions of grasslands, leading to their degradation, often on large areas. Remote sensing observations of such changes in grassland ecosystems evoke a great interest, but they are still a difficult task, especially when performed on industrial and mining areas. This paper presents a new effective method of remote sensing of grassland moisture conditions based on temperature–vegetation dryness index (TVDI) calculated from free Landsat imagery, and employing the TVDI spatial variability estimated from a semivariance analysis. The practical applicability of the method is demonstrated on the example of monitoring of the extensive neighborhood of lignite open-cast mine within a period of a few years. Besides, the developed method was validated at the studied area, using in situ information. Thus, we demonstrated that TVDI may serve as an effective indicator of grassland moisture conditions, even in problematic areas.     

Timing of glacier advances and climate in the High Tatra Mountains (Western Carpathians) during the Last Glacial Maximum

During the Last Glacial Maximum (LGM), long valley glaciers developed on the northern and southern sides of the High Tatra Mountains, Poland and Slovakia. Chlorine-36 exposure dating of moraine boulders suggests two major phases of moraine stabilization, at 26–21 ka (LGM I — maximum) and at 18 ka (LGM II). The dates suggest a significantly earlier maximum advance on the southern side of the range. Reconstructing the geometry of four glaciers in the Sucha Woda, Pańszczyca, Mlynicka and Velicka valleys allowed determining their equilibrium-line altitudes (ELAs) at 1460, 1460, 1650 and 1700 m asl, respectively. Based on a positive degree-day model, the mass balance and climatic parameter anomaly (temperature and precipitation) has been constrained for LGM I advance. Modeling results indicate slightly different conditions between northern and southern slopes. The N–S ELA gradient finds confirmation in slightly higher temperature (at least 1 °C) or lower precipitation (15%) on the south-facing glaciers during LGM I. The precipitation distribution over the High Tatra Mountains indicates potentially different LGM atmospheric circulation than at the present day, with reduced northwesterly inflow and increased southerly and westerly inflows of moist air masses.     

Coronal Mass Ejections Associated with Slow Long Duration Flares

It is well known that there is a temporal relationship between coronal mass ejections (CMEs) and associated flares. The duration of the acceleration phase is related to the duration of the rise phase of a flare. We investigate CMEs associated with slow long duration events (LDEs), i.e. flares with the long rising phase. We determined the relationships between flares and CMEs and analyzed the CME kinematics in detail. The parameters of the flares (GOES flux, duration of the rising phase) show strong correlations with the CME parameters (velocity, acceleration during main acceleration phase, and duration of the CME acceleration phase). These correlations confirm the strong relation between slow LDEs and CMEs. We also analyzed the relation between the parameters of the CMEs, i.e. a velocity, an acceleration during the main acceleration phase, a duration of the acceleration phase, and a height of a CME at the end of the acceleration phase. The CMEs associated with the slow LDEs are characterized by high velocity during the propagation phase, with the median equal to 1423 km?s^?1. In half of the analyzed cases, the main acceleration was low (a<300 m?s^?2), which suggests that the high velocity is caused by the prolonged acceleration phase (the median for the duration of the acceleration phase is equal 90 minutes). The CMEs were accelerated up to several solar radii (with the median ≈?7 R _⊙), which is much higher than in typical impulsive CMEs. Therefore, slow LDEs may potentially precede extremely strong geomagnetic storms. The analysis of slow LDEs and associated CMEs may give important information for developing more accurate space-weather forecasts, especially for extreme events.     

Large spinel grains in a CM chondrite (Acfer 331): Implications for reconstructions of ancient meteorite fluxes

By dissolving 30–400 kg of marine limestone in HCl and HF acid, our group has previously recovered common relict chromite grains (approximately 63–250 μm) from ordinary chondritic micrometeorites that fell on ancient sea floors, up to 500 Myr old. Here, we evaluate if CM group carbonaceous chondritic material, which makes up an important fraction of the micrometeorite flux today, contains analogous grains that can be searched for in acid residues. We dissolved 8 g of CM2 meteorite Acfer 331 in HF, which yielded a characteristic assemblage of both transparent Mg‐Al‐ and opaque Cr‐spinels >28 μm. We find on average 4.6 and 130 Mg‐Al‐spinel grains per gram in the 63–250 and 28–63 μm size fractions, respectively. These grains are mostly pink or colorless, and often characterized by heterogeneous Cr‐content. Black, opaque Cr‐spinel grains are absent from the >63 μm fraction, but in the 28–63 μm fraction we find approximately 65 such grains per gram meteorite. The individual grains have a characteristic composition, with heterogeneous major element compositions (e.g., 44.4–61.7 wt% Cr₂O₃), but narrow ranges for maximum TiO₂ (0.6–1.6 wt%) and V₂O₃ (0.5–1.0 wt%) concentrations. The content of spinel grains in the 28–63 μm fraction of CM meteorites appears comparable at the order of magnitude level with the content of >63 μm sized chromite grains in fossil L‐chondrites from Ordovician limestone. Our approach of recovering meteoritic spinel from sediment may thus be extended to include CM meteorites, but the smaller size fraction of the acid residues should be searched.     

EPR and magnetism of the nanostructured natural carbonaceous material shungite

The X-band EPR and magnetic susceptibility in the temperature range 4.2–300 K study of the shungite-I, natural nanostructured material from the deposit of Shunga are reported. Obtained results allow us to assign the EPR signal to conduction electrons, estimate their number, N _P, and evaluate the Pauli paramagnetism contribution to shungite susceptibility. A small occupation (~5%) of the localized nonbonding π states in the zigzag edges of the open-ended graphene-like layers and/or on σ (sp ^2+x ) orbitals in the curved parts of the shungite globules has been also revealed. The observed temperature dependence of the EPR linewidth can be explained by the earlier considered interaction of conduction π electrons with local phonon modes associated with the vibration of peripheral carbon atoms of the open zigzag-type edges and with peripheral carbon atoms cross-linking different nanostructures. The relaxation time T ₂ and diffusion time T _D are found to have comparable values (2.84 × 10⁻⁸ and 1.73 × 10⁻⁸ s at 5.2 K, respectively), and similar dependence on temperature. The magnetic measurements have revealed the suppression of orbital diamagnetism due to small amount of large enough fragments of the graphene layers.