Geochemical and statistical approach to evaluate background concentrations of Cd,Cu, Pb and Zn (case study: Eastern Poland)

An attempt was made to evaluate background concentrations of Cd, Cu, Pb and Zn by means of geochemical and statistical approach. As many as 753 samples taken from 51 profiles located in Eastern Poland were analysed. For the estimation of geochemical background values, direct geochemical methods and a statistical analysis for the whole population of samples were applied. Average values of heavy metal concentration in loess sediments (bedrock) as well as in profiles not affected by human activity were measured. The iterative 2σ technique and calculated distribution function were chosen as statistical methods. The resulting values (background concentrations range) were as follows: Cd 0.5–0.9 mg kg⁻¹, Cu 5–16 mg kg⁻¹, Pb 12–26 mg kg⁻¹ and Zn 31–47 mg kg⁻¹. All the methods applied gave similar results. The highest deviation of the background was noted for Cu and the lowest for Zn. The lowest values of background were obtained for loess sediments and the highest in the case of the multiple 2σ method.     

Fractionation of heavy metals in bottom sediments using Tessier procedure

The study presents the results of Cu, Pb, Zn, Mn and Fe determination in the samples of bottom sediments collected from the Oder and Warta rivers. The sequential extraction of metals in the samples of bottom sediments was performed after introducing the modification of the extraction scheme suggested by Tessier et al. (Anal Chem 51(7):844–851, 1979). The extraction times of particular stages were optimised. The fifth stage was altered by introducing the new methods of performing extraction. The samples of bottom sediments submitted the following granulometric analyses: dry, wet and wet with (HMP) dispersing reagent. Seven granulometric fractions with the following grain sizes were isolated: >2.0, 2.0–1.0, 1.0–0.5, 0.5–0.25, 0.25–0.1, 0.1–0.063 and <0.063 mm. The sequential extraction of particular granulometric fractions was performed. The concentration of metals variability was analysed depending on the method of sample preparation for the chemical analysis, granulometric fraction of sediments subjected to the analysis, extraction conditions and the site of samples collection. The lack of linearity between the metal concentration and the size of granulometric fraction was observed. The highest concentrations of metals were observed in fractions >2.0, 2.0–1.0 and 0.1–0.063 and <0.063 mm while the lowest concentrations occurred in fractions 1.0–0.5, 0.5–0.25, and 0.25–0.1 mm. The atomic absorption spectrometry with flame atomisation (F-AAS) was used for the determination of the investigated elements.     

Reconstruction of anastomosing river course by means of geophysical and remote sensing surveys (the Middle Obra Valley,western Poland)

Intensive hydro technical works were conducted in the middle course of the Obra River (Poland) at the beginning of the nineteenth century. The ‘natural’ river course (functioning before the major construction works) was transformed into three artificial canals. Ground‐penetrating radar investigations, ground‐truthed with coring and remote sensing surveys, were conducted to reconstruct the course taken by the river prior to the hydro technical works. This work demonstrated that the Obra formerly had an anastomosing planform. Radiocarbon dating indicated that the earliest of the retraced channels were active before 9000 bp . The retraced river system was formed in a proglacial stream valley perpendicularly cut by remains of subglacial tunnels, now partly filled with lakes. The planform consisted of one or two major channels and a number of secondary channels formed by avulsions. During the last 2000 years, some of the avulsions may have been caused by anthropogenic interventions. The sequences of channel fill deposits indicate that particular channels changed from major to secondary ones. Sand deposits filling the bottom and middle parts of the channels point to an important role of upstream sediment supply causing in‐channel aggradation triggering the avulsions. Moreover, spatial variability in river patterns was found within the anastomosing system. Valley sections with meandering anabranches, anastomosing patterns with traces of a lateral migration and traces of a transition from meandering to anastomosing planform were distinguished.     

Geology,stratigraphy and palaeoenvironmental evolution of the Stephanorhinus kirchbergensis-bearing Quaternary palaeolake(s) of Gorzów Wielkopolski (NW Poland,Central Europe)

The sedimentary succession exposed in the Gorzów Wielkopolski area includes Eemian Interglacial (MIS 5e) or Early Weichselian (MIS 5d–e) deposits. The sedimentary sequence has been the object of intense interdisciplinary study, which has resulted in the identification of at least two palaeolake horizons. Both yielded fossil remains of large mammals, alongside pollen and plant macrofossils. All these proxies have been used to reconstruct the environmental conditions prevailing at the time of deposition, as well as to define the geological context and the biochronological position of the fauna. Optically stimulated luminescence dating of the glaciofluvial layers of the GS3 succession to 123.6 ± 10.1 (below the lower palaeolake) and 72.0 ± 5.2 ka (above the upper palaeolake) indicate that the site formed during the Middle–Late Pleistocene (MIS 6 – MIS 5). Radiocarbon-dating of the lacustrine organic matter revealed a tight cluster of Middle Pleniglacial Period (MIS 3) ages in the range of ~41–32 ka cal bp (Hengelo – Denekamp Interstadials). Holocene organic layers have also been found, with ¹⁴C ages within a range of 4330–4280 cal bp (Neolithic). Pollen and plant macrofossil records, together with sedimentological and geochemical data, confirm the dating to the Eemian Interglacial.     

Topographic and geologic controls on landslides induced by the 2015 Gorkha earthquake and its aftershocks: an example from the Trishuli Valley,central Nepal

The devastating Gorkha earthquake (M _w 7.8) on April 25, 2015 and its aftershocks triggered numerous landslides across the Lesser and Higher Himalayas of central Nepal. This study aims to characterize these landslides, based on the local topography and geology, and to develop data for landslide hazard zoning. This study focused on a mountainous catchment of the Trishuli River, where a digital elevation model was used to examine hilllslope and river profiles, aerial photos were used to identify 155 coherent landslides, and satellite images were used to map 912 earthquake-induced landslides. The topography of this area is mainly characterized by incised V-shaped inner gorges and steep (> 35°) SW-facing scarp slopes. Although most of the coherent landslides were not reactivated by the earthquakes, the Gogane landslide was affected by the earthquake and partly failed. A majority of the earthquake-induced landslides (91%) were new landslides, while the others were enlarged old landslides. The earthquake-induced landslides occurred mainly on the steep slopes of V-shaped inner gorges and scarp slopes, in gneiss and quartzite strata of the Lesser Himalayas, and they were primarily associated with fractured rock masses. This analysis provides a framework for zoning areas vulnerable to earthquake-induced landslides.     

The application of well logging and seismic modeling to assess the degree of gas saturation in Miocene strata (Carpathian Foredeep, Poland)

The presence of natural gas in the pore space of reservoir rocks results in a significant decrease in P-wave velocity. Even low gas saturation can generate seismic anomalies (DHI) and false image of gas accumulation of economic importance. This article presents an attempt to evaluate gas saturation from 2D seismic section in the Miocene sandstone strata in the south-eastern part of the Carpathian Foredeep. The ESTYMACJA program and the Biot-Gassmann model were used to study the dependence between elastic parameters and saturating fluids (water and gas) recorded in wells. Series of calculations was carried out using a method of fluid substitution for various gas saturation. The applicability of seismic data for evaluating gas saturation of reservoir beds was assessed with the use of 1D modelling (synthetic seismograms) and 2D modelling (theoretical seismic section) calculated for different gas saturation. The proposed methodology can be used to identify low and high gas-saturated zones and contour the reservoir.     

Microencruster-microbial-cement framework of the Upper Jurassic reef developed on the slope of the intra-Tethyan carbonate platform (Bulgaria)

The carbonate succession in the Lyalintsi section of the western Moesian Platform (western Bulgaria) displays a shallowing-upward trend. Growth of the Tithonian–Valanginian coral biostromes and low-relief bioherms was preceded by Oxfordian–Kimmeridgian sedimentation of fine-grained peloidal-bioclastic limestones and Saccocoma-bearing limestones on the homoclinal ramp and the carbonate platform slope. In the late Kimmeridgian, boundstones with very rare corals, but with easily recognisable biohermal morphology, were developed. The main components of this reef are encrusting microorganisms, microbial crusts and synsedimentary cements. Microencrusters Labes atramentosa, Crescentiella morronensis, Perturbatacrusta leini and Radiomura cautica, as well as thin crusts of calcified sponges (sclerosponges), are the main biotic components. Corals (almost exclusively microsolenids) are sparse, whereas photophilic microencrusters (e.g., “Lithocodium–Bacinella”), are absent, although they are common in the overlying shallow-water part of the Lyalintsi sequence. Microbialites and synsedimentary cements provided additional support for the reef framework. The framework, especially the biotic components, and the reefal facies position within the sedimentary succession, implies that the high-energy upper slope of the carbonate platform was the depositional setting of the microencruster-microbial-cement reef studied. Encrusting microorganisms, except for C. morronensis and sponges, are only known from the intra-Tethyan platforms. This study supports conclusion of studies of coeval Alpine reefs that the presence of the microencruster-microbial-cement framework provides insight into the palaeobathymetry, palaeogeography and tectonic configuration of the intra-Tethyan carbonate platforms.     

Origin and evolution of volatiles in the Central Europe late Variscan granitoids,using the example of the Strzegom-Sobótka Massif,SW Poland

Mineralogy and Petrology - The results of the new Electron Microprobe Analysis of apatite, hornblende and biotite crystals of the hornblende-biotite variety of the Strzegom-Sobótka granite...